杂多酸催化剂研究进展_王德胜

[e-mail]．*[e-mail]730000O643．32A1HeteropolyacidPolyoxometalate-．．．．12．．MO6MO4、、．．11∶12Keggin．XM12O40n－X=PSiGeM=WMoPW12O403－SiW12O404-PMo12O403-1a22∶18Dawson．X2M18O62n－X=MoWM=PAsKeggin．1b3．cd．4．efγ-Kegginsandwich．1Fig．1Structureofheteropolyanions1．．2．．3．“”．4．、、、．264Vol．26No．420128JOURNALOFMOLECULARCATALYSISCHINAAug．20125．．．2070．．2、、、3．．．．、B、、H3PW12O40PW12＞H4PW11VO40＞H3PMo12O40PMo12～H4SiW12O40SiW12＞H4PMo11VO40～H4SiMo12O40SiMo12＞＞HClHNO3．MoWV．Misonosurface-typebulk-typeIandII2．POM．．I．IIeII+．IIIPOM．．2Fig．2Modelofsruface-typeandbulk-typeIandII2．1．、4．Radbil56-．Sil-va7．8、14-9．10DRIFTS．．2．2、、．KegginDawson．．B．．SiO211121314ZrO21516177634．Dias18H3PW12O40NbOH2n+H3-nPW12O40n-3H3PW12O40B．19MOF．Cu3BTC2MOF．POM/Cu3BTC2．、．MOF．3aCu3BTC2bH3PW12O40Fig．3athetunnelstructureofCu3BTC2bImmobilizedH3PW12O40inthetunnelJohanA．Martens20HPW/Cu3BTC2HPW/Cu3BTC2．HPW/Cu3BTC2Y．．．21、Keggin．110℃．．4Fig．4POMmodifiedILscatalyst．1422－28．Zieba29MxH3-xPW12O40M=KorCsx=22．5and3．K2K2．30/PyBS3PW12O40．2．3、、Friedel-Crafts．SnO2H3PW12O4031、3233Friedel-Crafts863265Fig．5HPAsaltscatalyzedesterexchangereaction34．Nikunj35γ-Al2O3pw12Friedel-Crafts．36．α-37－394041．2．4BrnstedL．Ferreira42SiO297%．Castanheiro42-．H3PW12O40＞H4SiW12O40＞H4PMo12O40＞H4SiMo12O40．98%．6Fig．6ImobilizedheteropolyacidcatalyzedacetalizationAkihiro43γ-SiW10O32H2O22l-O24-Knovenagel96%6LewisH+Brnsted．7γ-SiW10O32H2O22l-O24-KnovenagelFig．7γ-SiW10O32H2O22l-O24-catalyzedKnovenagelreaction．4420∶1dr99%ee．．/．8Fig．8ChiralityammoniumsaltofPOM4598%99．9%．．．9Fig．9POMammoniumsaltcatalyzedPrinsreaction2．5Emma46γ-SiW10O36Cu2N326-97%TON100000．．TON．4713-48Hosomi-Sakurai4950．963410γ-SiW10O36Cu2N326-Fig．10γ-SiW10O36Cu2N326-catalyzedcyclopropanationreaction3Keggin．．、、、．．．．．3．1C-H．MirkhaniSchiffFeCu5152．．Mizuno53．．Neumann54－57．Mostafa58Daw-sonα2-K8HP2V3W15O62．．Cavaleiro59SandwichM4H2O2PW9O342M=CoMnandFe．FeTON．3．260－64．Mizuno65gamma-SiW10O368-99%99%．66．．-．11Fig．11SynthesisofPOM/ILnanosphereGhamati67．98%．3．368－71．Neu-07326man72sandwichPdⅡPd-POMPdCl20．5Q12WZn3H2O2ZnW9O342．．．．．Mizuno73γ-KegginZnacac2sandwich．．．12ZnsandwichFig．12ZncoordinatedSandwichtypyPOM3．4Corma74Heck．60．．13Fig．13POM/LDHcatalyzedhydroxylreaction75H3PW12O401-．．．．．14a．bFig．14asynthesisofnanowireboxdationofsulfurtosulphone76．K6PW9V3O40·4H2O1734．．15K6PW9V3O40·4H2OFig．15K6PW9V3O40·4H2O/PyridineN-oxidesystem77787980．4、．1．．2．、．．3．．1KozhevnikovIV．Catalysisbyheteropolyacidsandmulti-componentpolyoxometalatesinliquid-phasereactionsJ．ChemicalReviews1998981171－1982WeinstockIA．Homogeneous-phaseelectron-transferre-actionsofpolyoxometalatesJ．ChemicalReviews1998981113－1703CormaA．Inorganicsolidacidsandtheiruseinacid-cata-lyzedhydrocarbonreactionsJ．ChemicalReviews1995953559－6144MisonoM．Heterogeneouscatalysisbyheteropolycom-poundsofmolybdenumandtungstenJ．CatalysisRe-views-ScienceandEngineering1987292－3269－3215Radbil＇ABetal．CamphenehydrationcatalyzedbyheteropolyacidsJ．RussianJournalofAppliedChemis-try2000732253－2566Radbil＇ABetal．Acid-catalyzedalkoxylationandhy-drationofcampheneJ．RussianJournalofOrganicChemistry200036111618－16227daSilvaKAKozhevnikovIVGusevskayaEV．Hy-drationandacetoxylationofcamphenecatalyzedbyheteropolyacidJ．JournalofMolecularCatalysisa-Chemical20031921－2129－1348AlhanashAKozhevnikovaEFKozhevnikovIV．Gas-phasedehydrationofglyceroltoacroleincatalysedbycae-siumheteropolysaltJ．AppliedCatalysisa-General2010378111－189OnoY．Heteropolyacidcatalysis-auniqueblendofacid-baseandredoxpropertiesJ．PerspectCatal1992431－46410ChengLMYeXP．ADRIFTSStudyofCatalyzedDe-hydrationofAlcoholsbyAlumina-supportedHeteropolyAcidJ．CatalysisLetters20091301－2100－10711YamamotoYetal．DirectadditionofaceticacidtoethylenetoformethylacetateinthepresenceofH4SiW12O40/SiO2J．AppliedCatalysisa-General20083441－255－6012SopaAetal．Ethanetoaceticacidoxidationoversup-portedheteropolyacidsJ．AppliedCatalysisa-General20052851－2119－12513KostovaNGetal．MechanochemicalapproachforpreparationofMo-containingbeta-zeoliteJ．JournalofPhysicsandChemistryofSolids2007685－61169－117214BrahmkhatriVPatelA．12-Tungstophosphoricacidan-choredtoSBA-15Anefficientenvironmentallybenignreusablecatalystsforbiodieselproductionbyesterifica-tionoffreefattyacids．AppliedCatalysisa-General20114031－2161－17215SakthivelRKemnitzE．AcetylationofanisoleonTPA/ZrO2．IndianJournalofChemicalTechnology200815136－4016Bravo-SuarezJJPaez-MozoEAOyamaST．Interca-lationofdecamolybdodicobaltateIIIanioninlayereddoublehydroxidesJ．ChemistryofMaterials20041671214－122517AmirinejadMetal．Cesiumhydrogensaltofheteropoly-acids/Nafionnanocompositemembranesforprotonex-changemembranefuelcellsJ．JournalofMembraneScience20113771-289－9818DiasJAetal．Preparationandcharacterizationof27326H3PW12O40supportedonniobiaJ．MicroporousandMesoporousMaterials20101321－2103－11119SunCYetal．Highlystablecrystallinecatalystsbasedonamicroporousmetal＆#x2212organicframeworkandpolyoxometalatesJ．JournaloftheAmericanChemicalSociety200913151883－188820MartensJAetal．ConvenientsynthesisofCu3BTC2encapsulatedKegginheteropolyacidnanoma-terial