有机光致变色材料最新研究进展

子子子子子子子子子子子子子子子子子子气气气气2002373..TN104A0438-1157200304-0497-11PROGRESSINRESEARCHOFORGANICPHOTOCHROMICMATERIALSYANGSongjieandTIANHeInstituteofFineChemicalsEastChinaUniuersityofScience&TechnologyShanghai200237ChinaAbstractOrganicphotochromicmateriaishavereceivedconsiderabieattentionbecauseoftheirhighpotentiaiforanumberofphotonicappiications.Theprogressintheresearchofthesemateriaisintheiastthreeyearswasreviewed.Keywordsorganicphotochromismopticaidatastoragemoiecuiarswitchfiuorescence21.1..2003-01-092003-03-14..35.No.20206007.1photochromismA!1B!22A!1!F—一2B...2050Re[e-mail]ytheNationaiNaturaiScienceFoundationofChinaNo.20206007.Hirshberg3~5photochromism.Hirshberg6.789.10~15200021.2..2.1.1988Irie16.171.0.5.Fig.1PhotocycdizationreactionofdiarydeyhenesIrie100CI22'18.Kryschi12-2--3-BMTFP19.2002IrieH254nmH273nm565nm70%!480nm.HK-20.HHaUV21Hb22.HaVa23..694IrieV.V24.2001Irie25.245-V.366nm480nm.4.6%~9.1%26.w.313nm500nm27.Ern皿w28.18-Irie工IpcFRET29.Irie12-2--4--3-15--910--30DVD100.794Fig.2StructureOftetraazapOrphyrinandhybridunsymmetricaI-phthaIOcyaninesbasedOnbisthienyIethene2.MSlHNMRUV-Vis3l~33.365nm730nm.3233.3l.l00.33..!3435!g.#ll7.5C36.37.89438.2001NorstenBranda皿工39.Lapouyade刀V40.Lemieux2-4--5-41.FeringaIV..42..MatsudaIrie2000IV.100%43.Iw.ESR99444.X皿45.450nm475nm313nm458nm....2000X皿59%64.4%21.7%.200500~538nm214.2%46.C1oKimXX47325nm!540nm.。-.200248.2.2.CSC0.2000BnardYuX刀X皿..49.005KimuraI皿工50I刀V5152.UV50.UV5152..BIardSPMICrOX3H2OSP+!-OX2-5.5K.UV53.!-SP-R+R=MePhMIPS3MI1-PS3SP-R2!##54.Moore55IIVUV.-..MeteiistsaIIV10%30%10556.Baumann57.2.3RentzepisPMMA2-!!58.Belfielk775nm3-1-12--3---4---25-59.Daub!!#DHAVHF-cisVHF-transVHF-cisDHA60.Fang!$!300nm!$!!ma!425nm61.3.Abe!!!62.Liebeskink633.205Fig.3Formationofcioseform22-..CC64.22'--44'55'--12'-65.310~15.34~3746...25~335356383943~455455.30452324..5960.References1EigierDMLutzCPRudgeWE.AnAtomicSwitchReaiizedwiththeScanningTunneiiingMicroscope.Nature19913526006032FanMeigong.PhotonModeOpticaiStorageandPhotochromicMateriais.ProgressChem.199791701783FischerEHirshbergY.FormationofCoiouredFormsofSpiropyransbyLow-temperatureIrradiation..Chem.Soc.1952452245244HirshbergYFischerE.Low-temperaturePhotochromismandItsReiationtoThermochromism..Chem.Soc.19536296365HirshbergYFischerE.PhotochromisminSomeSpiropyrans.Part!.TheExtentofPhototransformation..Chem.Soc.19611561636DtrrHBouasL.PhotochromismMoiecuiesandSystems.AmsterdamEisevier19907BaiiPGarwinL.ScienceattheAtomicScaie.Nature19923557617668TsivgouiisGMLehnJ-M.PhotoswitchedSexithiophenesTowardsSwitchabiemoiecuiarwires.Adu.Mater1997939419BenLF.MoiecuiarSwitches.WeinheimWiiey-VCH200110IrieM.DiaryiethenesforMemoriesandSwitches.Chem.Reu.20001001685171611YokoyamaY.FuigidesforMemoriesandSwitches.Chem.Reu.20001001717173912BerkovicGKrongauzVWeissV.SpiropyransandSpirooxazinesforMemoriesandSwitches.Chem.Reu.20001001741175313KawataSKawataY.Three-dimensionaiOpticaiDataStorageUsingPhotochromicMateriais.Chem.Reu.20001001777178814DeiaireJANakataniK.LinearandNoniinearOpticaiPropertiesofPhotochromicMoiecuiesandMateriais.Chem.Reu.20001001817184530515TamaiNMiyasakaH.UltrafastDynamicsofPhotochromicSystems.Chem.Reu.20001001875189016IrieM.MohriM.ThermallyIrreversiblePhotochromicSystems.ReversiblePhotocyclizationofDiaryletheneDerivatives..Org.Chem.19885380317TakeshitaMYamadaMKatoNIrieM.PhotochromismofDithienylethene-bistrimethylammoniumIodideinCyclodextrinCavities..Chem.Soc.PerkinTrans.22000461962218MorimitsuKShibataKKobatakeSIrieM.DithienyletheneswithaNovelPhotochromicPerformance..Org.Chem.200267134574457819ErnJBensATMartinH-DKuldovaKTrommsdorffHPKryschiC.Ring-openingand-ClosureReactionDynamicsofaPhotochromicDithienyletheneDerivative..Phys.Chem.A200210691654166020YamaguchiTKashiyamaHNakazumiHYamadaTIrieM.SynthesisandPhysicalPropertyofaNovelDiaryletheneDerivativeHavingaChrysobthiophenering.Chem.Lett.2002311585921KobatakeSYamadaTUchidaKKatoNIrieM.Photochromismof12-bis25-dimethyl-3-thienylperfluoro-cyclopenteneinaSingleCrystallinePhase..Am.Chem.Soc.19991212380238622YamadaTKobatakeSMutoKIrieM.X-rayCrystallographicStudyonSingle-crystallinePhotochromismofBis25-dimethyl-3-thienylperfluorocyclopentene..Am.Chem.Soc.20001221589159223MorimotoMKobatakeSIrieM.Multi-coloredPhotochromicCrystalsofDiaryletheneMixtures.Adu.Mater.200214151027102924IrieMKobatakeSHorichiM.ReversibleSurfaceMorphologyChangesofaPhotochromicDiaryletheneSingleCrystalbyPhotoirradiation.Science20012911769177225OsukaAFujikaneDShinmoriHKobatakeSIrieM.SynthesisandPhotoisomerizationofDithienylethene-bridgedDiporphyrins..Org.Chem.200166113913392326YagiKSoongCFIrieM.SythesisofFluorescentDiarylethenesHavinga245-triphenylimidazoleChromophore..Org.Chem.200166165419542327KawaiTSasakiTIrieM.AphotoresponsiveLaserDyeContainingPhotochromicDithienyletheneUnits.Chem.Commun.200171171228ErnJBensATMartinHDetal.ReactionDynamicsofaPhotochromicFluorescingDithienylethene..Phys.Chem.A2001105101741174929GiordanoLJovinTMIrieMJares-ErjmanEA.Diheter