酒石酸拆分

PLEASESCROLLDOWNFORARTICLEThisarticlewasdownloadedby:[HuazhongUniversityofScienceandTechnology]On:26May2010Accessdetails:AccessDetails:[subscriptionnumber918088208]PublisherTaylor&FrancisInformaLtdRegisteredinEnglandandWalesRegisteredNumber:1072954Registeredoffice:MortimerHouse,37-41MortimerStreet,LondonW1T3JH,UKOrganicPreparationsandProceduresInternationalPublicationdetails,includinginstructionsforauthorsandsubscriptioninformation:~content=t902189982TARTARICACIDANDITSO-ACYLDERIVATIVES.PART2.APPLICATIONOFTARTARICACIDANDOFO-ACYLTARTARICACIDSANDANHYDRIDES.RESOLUTIONOFRACEMATESLudwikSynoradzkia;UrszulaBernaśa;PawelRuśkowskiaaLaboratoryofTechnologicalProcesses,FacultyofChemistry,WarsawUniversityofTechnology,Warsaw,POLANDTocitethisArticleSynoradzki,Ludwik,Bernaś,UrszulaandRuśkowski,Pawel(2008)'TARTARICACIDANDITSO-ACYLDERIVATIVES.PART2.APPLICATIONOFTARTARICACIDANDOFO-ACYLTARTARICACIDSANDANHYDRIDES.RESOLUTIONOFRACEMATES',OrganicPreparationsandProceduresInternational,40:2,163—200TolinktothisArticle:DOI:10.1080/00304940809458084URL::(2).163-200(2008)TARTARICACIDANDITS0-ACYLDERIVATIVES.PART2.APPLICATIONOFTARTARICACIDANDOF0-ACYLTARTARICACIDSANDANHYDRIDES.RESOLUTIONOFRACEMATESLudwikSynoradzki.*UrszulaBema5andPawdRuSkowskiLaboratoryofTechnologicalProcesses.FacultyofChemistryWarsawUniversityofTechnologyNoakowskiego3Street.00-664Warsaw.POWVDe-mail:[e-mail]1INTRODUCTION......................................................................................................................165I.RESOLVINGAGENT...........................................................................................................1671.ResolutionviaDiastereomericSaltFormation...................................................................167a)ResolvedCompounds.....................................................................................................168b)ResolvingAgent..............................................................................................................171c)ResolutionbyFormationandFractionalCrystallizationofDiastereomericSalts......173e)AlternativeMethodsofSeparationofDiastereomericSalts.........................................179d)SelectionoftheResolutionOptimalParameters...........................................................175f)IndustrialAspect.............................................................................................................1802.ResolutionviaDiastereomericComplexFormation..........................................................181a)ResolvedCompounds.....................................................................................................182b)ResolvingAgent..............................................................................................................184c)TechniquesofResolutionviaComplexFormation........................................................1863.ResolutionviaDiastereomericCompoundFormation.......................................................186I1.DERIVATIZATINGAGENT.............................................................................................187I.DerivatizationofAlcohols..................................................................................................1882.DerivatizationofAmines....................................................................................................188111.CHIRALMATERIALFORCHROMATOGRAPHY...................................................1881.ChiralAdditive....................................................................................................................189a)impregnatedSilicaPlates..............................................................................................189b)ChiralMobilePhaseAdditives......................................................................................189c)ChiralStationaryPhases................................................................................................1902.TemplatingAgent................................................................................................................19362008byOrganicPreparationsandProceduresInc.163DownloadedBy:[HuazhongUniversityofScience