氢化丁腈橡胶技术进展及市场现状

25820094GansuScienceandTechnologyVol.25No.8Apr.2009,(,730060):,,:;;:TQ333.7(HNBR),(NBR)NBR,,HNBRHNBRNBR,,,,,,,1HNBRHNBR3:NBRNBR-1.1HNBRNBRNBR,,,,,NBR,,-CN(Pd)(Rh)Pd/C,,95.6%,,HNBR,SiO2Pd/SiO2,NBR,NBR,,3:[Pd(OAc)2]3,,,,,;NBR,,,,;PhCl(PPh3)3,95%,HNBR8l%,,[1]1.2HNBRNBRNBRHNBR2,WilkinsonNBRWilkinson()SinghaWilkinsonNBR,75,12h,60%HNBR,,,WilkinsonNBR,,,,,,,,Cu2+1984WideManHNBR,NBRHNBRGoodYearParKerHNBR,():NBR,100;CuSO45H2O,01008;,0.15;,,1516;H2O,216.66:NBRCuSO45H2O,4550,,7hH2O,,1hHNBR:,,;,;,;,,;HNBR:,,NBR,Oline,JSRNBR,HNBR,,,[2,3]1.3--(=0.04,=0.8),,,,HNBR,,:HNBRHNBR(PZMA),(ZSC)5060MPa,[4,5]2HNBRHNBRBayer1982BayerTherban,Therbanl7071907,34%38%,Therbanl707s,1907s2207(Zeon)1970HNBR,1978,1980,19844,Zetpol;19955300t/aPolysar2070HNBR,1985,198811Orange,1600t/a,Tornac1991,BayerPolysar,BayerTherban,3000t/aHNBR1992,NBR;,HNBR1999,,:LH-9901,LH-9902,HNBR2.2t/a,Bayer(1.0t/a),Zeon(1.2t/a),,,[6],Rh-Ru,98%,,,,NBR,NBR,,HNBR,95%,,,,HNBR,,HNBR[7],HNBR81%,,148:3HNBR[8],2001,HNBRNBR20%,HNBRNBR2007HNBR1.9t,20102.2tHNBR,,Z2010Z2020HNBRNBRCR,HNBR,,,HNBR,,,HNBR2832,HNBR2426,,,,2007100t,2010,4HNBRHNBR,,,HNBRHN2BR,,Zeon60MPaHNBR-ZSCHNBR,HNBRHNBR,,HNBRV,CR40,2HNBR;NBR/CR,HN2BR/CSMHNBR(PVCPE)(EPDM),HNBR5HNBRHNBR,,,,70t,HNBR,HNBR,,,HNBR,,:[1].[J].,2002,49(9).[2].[J].,1999(3):325.[3].[J].,2000,27(1).[4].[J].,2000,47(3).[5].[J].,1995,42(6).[6].[J].,2000,47(3).[7],.[J].,2002,18(5).[8].[J].,2002,17(3).[9].[J].,2000,47(2).2425