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MSDSMaterialSaftyDataSheet第一部分化学品及企业标识Section1Chemicalproductsandcompanyidentifications化学品中文名称:硫酸Chemicalproductschinesename:liusuan国家应急电话:0532-5811759Nationalemergencyphone:0532-5811759第二部分成分/组成信息Section2Compositionandinformationoningredients纯品√混合物×Singlesubstance√Mixture×有害成分浓度CASNo.硫酸98%7664-93-9HazardousingratiateconcentrationCASNo.Sulfuric98%7664-93-9第三部分危险性概述Section3hazardsidentificationHazardstype:8.1typeCorrosivespresentingacidicproperties侵入途径:吸入、食入Pathways:Inhalation,Ingestion健康危害:对皮肤、粘膜等组织有强烈的刺激和腐蚀作用。蒸气或雾可引起结膜炎、结膜水肿、角膜混浊,以致失明;引起呼吸道刺激,重者发生呼吸困难和肺水肿;高浓度引起喉痉挛或声门水肿而窒息死亡。口服后引起消化道烧伤以致溃疡形成;严重者可能有胃穿孔、腹膜炎、肾损害、休克等。皮肤灼伤轻者出现红斑、重者形成溃疡,愈后癍痕收缩影响功能。溅入眼内可造成灼伤,甚至角膜穿孔、全眼炎以至失明。慢性影响:牙齿酸蚀症、慢性支气管炎、肺气肿和肺硬化。Healtheffect:Thisproductmayproducesevereirritationandcorrosiontoskinandmucousmembranesandothertissue.Vaporormistmaycauseconjunctivitis,chemosis,cornealopacityandlosesight.maycauseirritationofrespiratorytract,evencausedifficultyinbreathingandlungedema.Maycauselaryngospasm,glottisedema,lossofbreatheanddeathwhenhighconcentrationispresent.Swallowingwillresultinburnstoalimentarycanalandproduceulcerations,andeveninthedangerofperforationstomach,peritonitisandindamagetokidney,shock,etc.slightburnstoskincauseerythemaandsevereburnsproduceulcerations.Scarscontractafterhealingupandaffectfunction.Incaseofeyecontactmaycauseburns,cornealperforation,panophthalmitisandlossofsight.慢性影响:牙齿酸蚀症、慢性支气管炎、肺气肿和肺硬化。PotentialChronicHealthEffects:teetherosion,chronicbronchitis,emphysemaandpneumosclerosi环境危害:对环境有危害,对水体和土壤可造成污染。Environmentaleffect:Itisharmfultoenvironmentandmaypollutewatersandsoil燃爆危险:本品助燃,具强腐蚀性、强刺激性,可致人体灼伤。Combustionhazard:Thisproducthelpstocombustandisseverecorrosiveandirritant,maycauseburnstohumanbody第四部分:急救措施Section4Firstaidsmeasurement皮肤接触:立即脱去污染的衣着,用大量流动清水冲洗至少15分钟。就医。SkinContact:Immediatelyremovecontaminatedclothingandshoes.flushskinwithplentyofrunningwaterforatleast15minutes,Getmedicalattentionimmediately.眼睛接触:立即提起眼睑,用大量流动清水或生理盐水彻底冲洗至少15分钟。就医。EyeContact:Immediatelyfiledpalpebral,withplentyofliquidwaterorsalinethoroughlyflushedatleast15minutes.Thenconsultadoctor.吸入:迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难,给输氧。如呼吸停止,立即进行人工呼吸。就医。Inhalation:Escapetofreshair.KeepRespiratoryTractUnobstructed,Ifbreathingisdifficult,giveoxygen.Ifnotbreathing,giveartificialrespiration.Getmedicalattentionimmediately.食入:用水漱口,给饮牛奶或蛋清。就医。Ingestion:RinsemouthwithwaterGivemilkandeggwhite,callaphysician第五部分:消防措施Section5:FireFightingMeasures危险特性:遇水大量放热,可发生沸溅。与易燃物(如苯)和可燃物(如糖、纤维素等)接触会发生剧烈反应,甚至引起燃烧。遇电石、高氯酸盐、雷酸盐、硝酸盐、苦味酸盐、金属粉末等猛烈反应,发生爆炸或燃烧。有强烈的腐蚀性和吸水性。Hazardproperties:Contactwithwatergeneratesplentyofheat,andcausesplashing.Reactviolentlywitheasilycombustiblematerial(asbenzene),ombustiblematerial(asSugar,cellulose,etc.).andevenresultincombustion.Reactviolentlywithcalciumcarbide,perchlorate,fulminate,nitrate,picrate,metalpowder,etc.andcausecombustionorexplosion.Stronglycorrosiveandwaterabsorbent.有害燃烧产物:氧化硫ExplosionHazards:sulfuroxide灭火方法:消防人员必须穿全身耐酸碱消防服。灭火剂:雾状水、二氧化碳、砂土。避免水流冲击物品,以免遇水会放出大量热量发生喷溅而灼伤皮肤。Extinguishingmeasurement:Firefightermustwearacidandalkaliproofclothing.Exstinguisher:Vaporificwater,carbondioxideandsandysoil.Avoidwaterflowstriketheproductopreventshinburnsbecauseofplentyofheatproducedincontactwithwater.第六部分:泄漏应急处理Section6:AccidentalReleaseMeasures应急处理:迅速撤离泄漏污染区人员至安全区,并进行隔离,严格限制出入。建议应急处理人员戴自给正压式呼吸器,穿防酸碱工作服。从上风处进入现场。尽可能切断泄漏源。防止流入下水道、排洪沟等限制性空间。小量泄漏:将地面洒上苏打灰,然后用大量水冲洗,洗水稀释后放入废水系统。大量泄漏:构筑围堤或挖坑收容。喷雾状水冷却和稀释蒸汽、保护现场人员、把泄漏物稀释成不燃物。用泵转移至槽车或专用收集器内,回收或运至废物处理场所处置。Removepeopleawayfromareaofspilltosafearea,isolatethemandstrictlyrestrictaccess.SuggestthatemergencyProcessingpersonnelwearSelf-containedbreathingapparatusandAnti-acid&alkaliworkclothing,entersitefromthewindwardside.Cutoffsourceofspills.Prevententryintosewers,basementsorconfinedareasSmallspill:Sprinklethesodaashontheground,thenflushwithplentyofwaterandpourintowastewatersystemafterdilutedwithwater.Largespill:Buildcausewayanddigaholetocontaintheleakage.Usewaterspraytocoolandreducevapors.Protectpersononsite,dilutetheleakagetobeinflammablematerial.Transfertotankcaroraspecialcollectorwithpump.Recoverorremovetowastetreatmentplantsfordisposal.第七部分:操作处置与储存Section7:HandlingandStorage操作注意事项:密闭操作,注意通风。操作尽可能机械化、自动化。操作人员必须经过专门培训,严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具(全面罩),穿橡胶耐酸碱服,戴橡胶耐酸碱手套。远离火种、热源,工作场所严禁吸烟。防止蒸气泄漏到工作场所空气中。避免与还原剂、碱类、醇类、碱金属接触。搬运时要轻装轻卸,防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。稀释或制备溶液时,应把酸加入水中,避免沸腾和飞溅。HandlingPrecautions:Keepinasealedareaandcareforventilation.Handlingshouldbemechanicalandautomaticaspossibleasitcan.Operatorsshouldobtainspecialtraining,andfollowclosetooperationprocedures.Suggestthatoperatorsshouldwearself-supportingfiltermask(fullfacetask),anti-acidandalkalirubberclothingandgloves.Keepawayfromsourcesofignition.Keepawayfromheat.NosmokinginWork-station.PreventvaporsneakingintoairintheWork-station.Keepawayfromreducingagents,alkalis,alcoholsandalkalimetal.Handlewithcare,andavoiddamagetopackageandcontainer.Preparematchingtypeandamountoffirefightingequipmentandaccidentalreleaseequipments.Hazardousresidualmayremaininemptycont
本文标题:硫酸MSDS中英文互译
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