蜂蜜中羟甲基糠醛的研究进展

2011Vol.62No.1APICULTUREOFCHINA、、、。3/4、。85%～95%。、、、、、。、、、、、[1-3]。HMF、、。MailardHMF。HMF。HMF、、[4,5]。HMFHMF40mg。HMF。HMF10mg/kg。。HMFHMF、。1HMF。KubisHMF。HMF50℃63℃HMF。82℃HMF10[6]。Thrasyvoulou5。HMFHMF40mg/kg。50～60℃HMF。60℃535134373293490℃25821。*:,1969,,,,。E-mail:[e-mail]*/710069HMF。HMFHMF。HMF[]S896.1[]BAReviewof5-HydroxymethylfurfuralinHoneyLiuJingCaoWei*Researchcentreofbeeproduct/Departmentoffoodscienceandengineering,NorthwestUniversity,Xi’an710069,ChinaAbstract:HMF(5-hydroxymethylfurfural)isconsideredtobeanimportantqualityparameterforhoneyandhoneyproducts.ThispaperdemonstratestheformationofHMFofhoneyinthermalprocessingandpreservation,otherwise,theremovalofHMFinhoneyisalsoreviewed.Keywords:HoneythermalprocessingpreservationHMF[]0412-4367201101-0011-0311APICULTUREOFCHINA2011621[7]。Singh65℃HMF301295℃62[8]。HMF。HMF。HMF。80℃HMF[9]。2Kubis6℃12HMF18℃12HMF[6]。Sahinler9HMF6.25±0.15mg/kg16.40±0.25mg/kg[10]。HMF。Cavia60305HMF。HMF202.9%～8.0%HMF40mg/kg2522.9%～72.0%HMF。HMF[11]。BathHMF[12]。20[11]。3HMF。HMF[13]。HMFLH-1575%。、。HMF。pH、、、。LH-15pH4。LH-15HMF。。。LH-15。LH-15HMFLangmuirHMF[13]。HMF[14]。LSA-800BHMF。298K、308K、318KHMFLSA-800BFre－undlich。Freundlich0LSA-800BHMF。40kJ/molLSA-800BHMF。△G＜0△S＜0。[14]。HMF。、、、。HMF。4HMF。HMF。HMFHMF。。。HMF。HMF。[1].[J].,2003,54(1):38-39.[2].[J].,2004,3(17):62.[3],.[J].,2003,(6):5-6.[4]BruceWR,ArcherMC,CorpetDE.DietAberrantcryptfociandcolorectalcancer[J].MutatRes,1993,(290):111-118.[5]ZhangXM,ChangCC,StampD.Initiationandpromotionofcolonicaberrantcryptfociinratesby5-hydroxymethyl-2-furaldehyde（35122011Vol.62No.1APICULTUREOFCHINAinthermolyzedsucrose[J].Carcinogenesis,1993,(14):773-775.[6]KubisI,IngrI.Effectsinducingchangesinhydroxymethylfurfuralcontentinhoney[J].CzechJournalofAnimalScience,1998,43(8):379-775.[7]ThrasyvoulouA.HeatingtimesforGreekhoney[J].MelissokomikiEpitheorisi,1997,11(2):79-80.[8]SinghN,BathPK.QualityevaluationofdifferenttypesofIndianhoney[J].FoodChemistry,1997,58(1):129-133.[9],,.[J].,2006,36(2):253-256.[10]NuraySahinler.Effectsofheatingandstorageonhydroxymethyl-furfuralanddiastaseactivityofdifferentTurkishhoneys[J].JournalofApiculturalResearch,2007,46(1):34-39.[11]M.MarCavia,CristinaAlvarez,JoseF.Huidobro,MiguelA.Fer-nandez-Muino,M.TeresaSancho.Evolutionofhydroxymethylfurfuralcontentofhoneysfromdifferentclimates:Influenceofinducedgranu-lation[J].InternationalJournalofFoodSciencesandNutrition,2008,59(1):88-94.[12]ParminderKaurBath,NarpinderSingh.AcomparisonbetweenHelianthusannuusandEucalyptuslanceolatushoney[J].FoodChem-istry,1999,67:389-397.[13].[D]..2007.[14],,,.[J].,2006,22(11):254-256.mg/100g0703031701.300703041713.320703051701.3221(n=5)RSDg(mg)(mg)(mg)%%%10.540549.477818.1644103.8220.5722010.032918.6548103.0530.520369.12398.366817.6837102.31102.841.0940.491198.612517.0779101.1850.508058.908117.5971103.851ml10%1ml10ml。-500nmCB8.224～49.344μg/ml。Y=0.0130X-0.01791r=0.99958。3.25RSD0.25%。3.30、2、3、4、5hRSD1.16%5。3.451753.39mg/100gRSD0.86％。3.550.5g2.0917mg/ml4ml1。43“”2。55.1、。。5.2“GB/T20574-2006”《》2003“”[34]。5.3CO2、。5.4CO2。[1]..,2008,14:44-45.[2]2005[S]．,2005。[3]《》2003.,2003.[4]GB/T20574-2006.2006.!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!（1235