热化学方程式

热化学方程式热化学方程式................................................2B................................................................................................................................................2C................................................................................................................................................2H................................................................................................................................................2N................................................................................................................................................3P................................................................................................................................................3S................................................................................................................................................3二、热化学方程式BB2H6(g)+3O2(g)=B2O3(s)+3H2O(l)；△H=-2165kJ·mol-1CC(石墨，s)+O2(g)=CO2(g)；△H=-393.5kJ·mol-1C(金刚石，s)+O2(g)=CO2(g)；△H=-395.4kJ·mol-1C(金刚石，s)=C(石墨，s)；△H=-1.90kJ·mol-1．C(s)+H2O(g)=CO(g)+H2(g)；△H=+131.3kJ·mol-1C(s)+1/2O2(g)=CO(g)；△H=-110.5kJ·mol-1C(s)+O2(g)=CO2(g)；△H=-393.5kJ·mol-1CO(g)+1/2O2(g)==CO2(g)；△H=-283kJ·mol-1CaC2(s)+2H2O(l)=C2H2(g)+Ca(OH)2(s)；△H=-127kJ·mol-1CH4(g)+2O2(g)=CO2(g)+2H2O(l)；△H=-890.3kJ·mol-1C2H4(g)+3O2(g)=2CO2(g)+2H2O(l)；△H=-1411kJ·mol-1C2H2(g)+5/2O2(g)=2CO2(g)+H2O(l)；△H=-1300kJ·mol-1C3H8(g)+5O2(g)=3CO2(g)+4H2O(l)；△H=-2220.0kJ·mol-1C8H18(l)+25/2O2(g)=8CO2(g)+9H2O(l)；△H=-5518kJ·mol-1CH3OH(l)+3/2O2(g)=CO2(g)+2H2O(l)；△H=-725.8kJ·mol-1C2H5OH(l)+3O2(g)=2CO2(g)+3H2O(l)；△H=-1367kJ·mol-1C6H12O6(s)+6O2(g)=6CO2(g)+6H2O(l)；△H=-2800kJ·mol-1HH2(g)+Cl2(g)==2HCl(g)；△H=-184.6kJ·mol-12H2(g)+O2(g)=2H2O(g)；△H=-483.6mol·L-1H2(g)+1/2O2(g)=H2O(l)；△H=-241.8kJ·mol-12H2(g)+O2(g)=2H2O(l)；△H=-571.6kJ·mol-1H2(g)+1/2O2(g)=H2O(l)；△H=-285.8kJ·mol-12H2O(g)=2H2(g)+O2(g)；△H=+483.6kJ·mol-1H2O(g)=H2(g)+1/2O2(g)；△H=+241.8kJ·mol-12H2O(l)=2H2(g)+O2(g)；△H=+571.6kJ·mol-1H2O(l)=H2(g)+1/2O2(g)；△H=+285.8kJ·mol-1H2O(l)==H2O(g)；△H=+44kJ·mol-1H2O(g)==H2O(l)；△H=-44kJ·mol-1HCl(aq)+NaOH(aq)==NaCl(aq)+H2O(l)；△H=-57.3kJ·mol-1H+(aq)+OH-(aq)==H2O(l)；△H=-57.3kJ·mol-1NN2(g)+O2(g)=NO2(g)；△H=+180.7kJ·mol-1N2(g)+3H2(g)2NH3(g)；△H=-92.4kJ·mol-14NH3(g)+5O2(g)催化剂△4NO(g)+6H2O(g)；△H=-907kJ·mol-1．2NO(g)+O2(g)＝2NO2(g)；△H=-113kJ·mol-1．3NO2(g)+H2O(l)＝2HNO3(l)+NO(g)；△H=-136kJ·mol-1．N2H4(g)+O2(g)=N2(g)+2H2O(g)；△H=-534kJ·mol-1N2H4(l)+2H2O2(l)=N2(g)+4H2O(g)；△H=-641.6kJ·mol-12N2H4(g)+2NO2(g)=3N2(g)+4H2O(g)；△H=-1135.7kJ·mol-1．PP4(白磷，s)=4P(红磷，s)；△H=-66.8kJ·mol-1．SS(g)+O2(g)SO2(g)；△H=-297kJ·mol-1FeS2(s)+11/4O2(g)1/2Fe2O3(s)+2SO2(g)；△H=-853kJ·mol-1SO2(g)+1/2O2(g)SO3(g)；△H=-98.3kJ·mol-1SO3(g)+H2O(l)=H2SO4(l)；△H=-130.3kJ·mol-1三、有机反应方程式(一)、烷烃CH4+2O2CO2+2H2OCH4+2Cl2CH2Cl2+2HClCH4+3Cl2CHCl3+3HClCH4+4Cl2CCl4+4HClCH4C+2H2(二)、烯烃C2H4+3O22CO2+2H2OCH2＝CH2+Br2CH2BrCH2BrCH2＝CH2+H2OCH3CH2OHCH2＝CH2+H2CH3CH3CH2＝CH2+HClCH3CH2ClnCH2＝CH2CH3CH2OHCH2＝CH2↑+H2O(三)、炔烃CaC2+2H2OC2H2↑+Ca(OH)22C2H2+5O24CO2+2H2OCH≡CH+Br2CHBr＝CHBrCHBr＝CHBr+Br2CHBr2CHBr2CH≡CH+HClH2C＝CHClnH2C＝CHCl(四)、芳香烃2C6H6+15O212CO2+6H2O+Br2+HBr+HO－NO2+H2O+HO－SO3H+H2O+3H2+3HONO2+3H2O(五)、石油C16H34C8H18+C8H16(六)、卤代烃CH3CH2Br+H2OCH3CH2OH+HBrCH3CH2Br+NaOHCH2＝CH2+NaBr+H2O(七)、醇类CH2＝CH2+H2OCH3CH2OH2CH3CH2OH+2Na2CH3CH2ONa+H2↑2CH3CH2OH+O22CH3CHO+2H2O12Cu+O22CuO2CH3CH2OH+CuOCH3CHO+H2O+CuCH3CH2OHCH2＝CH2↑+H2OCH3CH2OHCH3CH2OCH2CH3+H2O(八)、酚类+NaOH+H2O+H2O+H3O++CO2+H2O+NaHCO3+3Br2↓+3HBr(九)、醛类CH3CHO+H2CH3CH2OH2CH3CHO+O22CH3COOHCH3CHO+2Ag(NH3)2OHCH3COONH4+2Ag↓+3NH3+H2OCH3CHO+2Cu(OH)2CH3COOH+Cu2O↓+2H2O(十)、羧酸CH3COOH+CH3CH2OHCH3COOCH2CH3+H2OHCOOH+CH3OHHCOOCH3+H2OCH3COOCH2CH3+H2OCH3COOH+CH3CH2OH(十一)、糖类C6H12O6+6O26CO2+6H2OC6H12O6(s)+6O2(g)=6CO2(g)+6H2O(l)；△H=-2800kJ·mol-1CH2OH(CHOH)4+H2CH2OH(CHOH)4CH2OHCH2OH(CHOH)4CHO+2Ag(NH3)2OHCH2OH(CHOH)4COONH4+2Ag↓+3NH3+H2OCH2OH(CHOH)4CHO+2Cu(OH)2CH2OH(CHOH)4COOH+Cu2O↓+2H2OC6H12O62CH3CH2OH+2CO2C6H12O62CH3CHOHCOOH+2CO2C12H22O11(蔗糖)+H2OC6H12O6(葡萄糖)+C6H12O6(果糖)C12H22O11(麦芽糖)+H2O2C6H12O6(葡萄糖)(C6H10O5)n(淀粉)+nH2OnC6H12O6(葡萄糖)(C6H10O5)n(纤维素)+nH2OnC6H12O6(葡萄糖)(十二)、油脂(十三)、氨基酸++H2O++H2O++H2O++H2O