光催化太阳能转换及环境净化材料的现状和发展趋势

83∗234567(1.2100932.1000803.3500024.1000845.3000716.1000837.,305-0047)2004-06-131955COE1101021TK513TB39A1001-97312004-0083-061/EDCs50SARS200326172003330,50020058420043515020004%400750nm43%1Fig1Solarspectrun(Nature,414pp625,2001)(0.6%)0.03%12321972FujishimaHonda(2)123TiO24%2Fig2VariousapplicationsofphotocatalysisTiO285TiO22001TiO2-xNyScience293,pp269-271,200120029CTiO2(Science,297,pp2243,2002)TiO2NC2001(Nature,414pp625,2001)TiO2(In1-xNixTaO4),3LewisZouetaldescribeastepalongonewaytowardsthisHolyGrailofinorganicphotochemistry(Nature414,pp589,2001)Science3Fig3Visible-light-drivenphotocatalysisAVO4(A=In,Ga,)(In2O3)m(BaO)nAgInW2O8,MN1/3Nb2/3O3(M=Ca,Sr,andBaN=Ni,Co,In,Cr)(650nm)H2S(4)J.Phys.Chem.B107pp61,2003;107,pp4936,2003;107,pp14265,2003BB4Fig4Degradationofcontaminationbyvisible-light-drivenphotocatalysisTiO2B(J.Am.Chem.Soc.126pp47822004)NCTiO2,B-TiTiO2Ni2O3Angew.Chem.Int.Ed.,2001,40,3041-Angew.Chem.Int.Ed.,42,pp1029,2003Science(296,pp1106,2002)200286200435RuRu-PtJ.Am.Chem.Soc.126,pp3060-3061,2004J.Mater.Res.,16,pp254420011998TiO2TiO2,SARS/5312,3,,87/1212--34(400800nm)[1]FujishimaA,HondaK.[J].Nature,1972,238:37.[2]ZouZ,YeJ,etal.[J].J.Phys.Chem.B.,2002,106:517.[3]YeJ,ZouZ,etal.[J].Chem.Phys.Lett,2002,356:221.[4]YeJ,ZouZ,etal.[J].J.ofPhotochem.andPhotobio.A:Chem,2002,148:65.[5]ZouZ,YeJ,etal.[J].Chem.Phys.Lett,2001,343:303.[6]ZouZ,YeJ,etal.[J].Nature,2001,414:625.[7]ZouZ,YeJ,etal.[J].J.Phys.andChem.B,2002,106:13098.[8]YinJ,ZouZ,YeJ.[J].J.Phys.Chem.B.,2003,107:61.[9]YinJ,ZouZ,YeJ.[J].Chem.Phys.Letters,2003,378:24.[10]WangD,ZouZ,YeJ.[J].Chem.Phys.Letters,2003,373:191.[11]YinJ,ZouZ,YeJ,etal.[J].Chem.B.,2003,107:4936.[12]TangJ,ZouZ,YeJ.[J].Chem.Phys.Lett,2003,382:175.[13]ChenJ,TaoZ.L,LiS.L.FabricationofRuandRu-basedfunctionalizednanotubes[J].J.Am.Chem.Soc,2004,126:3060-3061.[14]ChenJ,LiS.L,TaoZ.L,etal.Titaniumdisulfidenanotubesashydrogenstoragematerials[J].J.Am.Chem.Soc.,2003,125:5284-5285.[15]ChenJ,TaoZ.L,LiS.L.Lithiumintercalationinopen-endedTiS2nanotubes[J].Angew.Chem.Int.Ed.,2003,42:2147-2151.[16]HirotsuguKikuchi,MasayukiYokoda,YoshiakiHisakado,etal.Polymer-StabilizedLiquidCrystalBluePhase[J].NatureMaterials,2002,1:pp64.[17]HuaiYang,HirotsuguKikuchiandTisatoKajiyama,Study88200435onThermal-addressingCharacteristicsof(PolymerNetwork/LiquidCrystals/ChiralDopant)Composite[J].Chem.Lett.,2003,32:256.[18]HuaiYang,KenjiMishima,KiyoshiMatsuyama,etal.ThermallyBandwidth-controllableReflectivePolarizesfrom(PolymerNetwork/LiquidCrystal/ChiralDopant)Composites,Appl.Phys.Lett.,2003,82:2407.[19]ZhaoW,MaW,ChenC,etal.EfficientdegradationoftoxicpollutantswithNi2O3/TiO2-xBxundervisibleirradiation[J].J.Am.Chem.Soc.,2004,126:4782-4783.[20]MaWanhong,LiJing,TaoXia,etal.EfficientDegradationofOrganicPollutantsUsingDioxygenActivatedbyResin-ExchangedIron(II)BipyridineunderVisibleIrradiation[J].Angew.Chem.Int.Ed.Engl.,2003,42:1029.[21]MaWanhong,HuangYingping,LiJing,etal.AnEfficientApproachforPhotodegradationofOrganicPollutantbyImmobilizedIronIonsatNeutralpHs[J].Chem.Comm.,2003,1582-1583.[22]TaoXia,MaWanhong,ZhangTianyong,etal.EfficientOxidativeDegradationofOrganicPollutantsinthePresenceofIronTetrasulfophthalayanineunderVisibleIrradiation[J].Angew.Chem.Int.Ed.,2001,40:3014-3016.[23]YuJimmyC.,WangXinchen,FuXianzhi.Pore-WallChemistryandPhotocatalyticActivityofMesoporousTitaniaMolecularSieveFilms[J].Chem.Mater.,2004,16:1523-1530.[24]ZhangWen,WangXuxu,FuXianzhi.MagneticFieldEffectonPhotocatalyticDegradationofBenzeneoverPt/TiO2[J].Chem.Commun,2003,2196-2197.[25]FuXianzhi,ZeltnerW.A,AndersonM.A.ApplicationsinPhotocatalyticPurificationofAir,inSemiconductorNanoclusters:Physical,Chemical,andCatalyticAspects(P.V.Kamat,D.Meisel,Eds.)[J].Stud.Surf.Sci.Catal.,1997,1030:445-461.[26]S.YamazakiNishida,FuXianzhi,AndersonM.A.CatalyticHydrolysisofDichlorodifluoromethane(CFC-12)onSol-Gel-DerivedTitaniaUnmodifiedandModifiedwithH2SO4[J].J.Catal.,1997,168:482-490.[27]FuXianzhi,ClarkL.A,YangQ.EnhancedPhotocatalyticPerformanceofTitania-basedBinaryMetalOxides:TiO2/SiO2andTiO2/ZrO2[J].Environ.Sci.Technol.,1996,30:647-653.[28]ZhuWanpeng,YangZhihua,WangLi.ApplicationofFerrous-hydrogenperoxidefortreatmentofDSD-acidmanufacturingprocesswastewater[J].WaterResearch,2001,35:2087.[29]ZhuWanpeng,BinYuejing,LiZhonghe,etal.ApplicationofcatalyticwetairoxidationfointhetreatmentofH-acidmanufacturingprocesswastewater[J].WaterResearch,2002,36:1947.[30][30]LiLaisheng,ZhuWanpeng,ZhangPengyi,etal.Photocatalyticoxidationandozonationofcatecholovercarbon-black-modifiednano-TiO2thinfilmssupportedonAlsheet[J].WaterResearch,2003,37:3546.DevelopmentonsolarenergyconversionandenvironmentalapplicationsofphotocatalysisZOUZhi-gang,ZHAOJin-cai2,FUXian-zhi3,ZHANGPeng-yi4,CHENJun5,ZHUHong-min6,YEJin-hua7(1.EcomaterialsandRenewableEnergyResearchCenter(ERERC),NanjingUniversity,Nanjing210093,China;2.InstituteofChemisty,ChineseAcademyofSciencesBeijing100080,China;3.FuzhouUniversity,Fuzhou350002,China4.TsinghuaUniversity,Beijing100084,China;5.NankaiUniversity,Tianjin300071,China6.UniversityofScienceandTechno