土壤有机污染物非理想吸附研究的理论与方法

2002,11(2):144~[e-mail]19642001-12-0811500402Amherst010003,USASOMSOM1H-13C-NMRSOMtransitionSOMX131.3A1008-181X200202-0144-08SOMSOMSOMSOM3-FreemanCheung1981Chiou1989Karickhoff1984SOMMayer1999SOMSOM3-Chien1997SOMChiou1989Karickhoff1984SOMXing1996XingPignatello1997Huang1451997XiaBall1999Xing1996XingPignatello1997McGinley1993Kan1998XiaPignatello2001MillerPedit1992Kan1998HuangWeber1997Mark1993TgSOMLucht1987Larsen1995Milewska-Duda1993Milewska-DudaDuda1994Irvine1984SOM/SOMDSCLeBoeufWeber1997200045~73TgsDSCSchaumannAntelmann2000SOMTg7977Gustafsson1997Karapanagioti2000Kleineidam1999Buiel1999XiaBall1999Kleineidam1999Karapanagioti2000ChiouKile1998Chiou2000-TgXiaPignatello2001CHCl3SOMSOMLyonRhodes1993SgLuchtPeppas1987MarzecKisielow1983LyonRhodes199119931995LyonRhodesPahokee20014611220025PerkinElmerTMA750nm–170+500HAChang1997Shian-cheeWuXiaPignatello1,3--2-2,4-SOM1,2-1,3-–NO2,-CN,-OCH3,-C(=O)-H–C(=O)-OCH3-HAHAsHAHARuntFitzgerald1997Hedvig1977BidstrupDay1994β-β-transitionssidegroupsα-α-transitionsα'-βαα'α-4~5nm102Walther1998sinusoidalvoltagef()()wewee′′-′=iw()we′w()we′′wi1-()we′f()we′Tgf=~1Hz()we′′w1/tt()we′′T1=×twfT~1HzTgf(Mackinnon1994)TSC(Teyssedre1997)T1T250CTSCMackinnon1994(Butler147Cameron2000)HAs-HA-HA()we′()we′′TgHAH+TgAl3+Ca2+-HAHATg1H13CNMRSOMHAHA(T2HT2C)Axelson1985CookLangford1998T2HFID90°7μsFIDGaussianLorentzianJurkiewicz1982Yokono1978T2HLorentzianT2HSOMGaussianLorentzianBarton1984Jurkiewicz1982Yokono1978T2C/CP/MASHahn-180º180ºXing1999CPtt180ºttT2Cln2tT2C(Axelson1985)180°(Xing1999)T2CT2H305080SOMT2CT2HT2HHACa2+Al3+SOMXing1994Xing1997Chin1997SOMHAsWeberHuangWeber1997Johnson1999SOMHAXingPignatello19971998SOMHA1Johnson19992O-Stevenson19943NaOClCStevenson1994Christman19894/CAlmendros199414811220025FTIRXing1996200μg/mLNaN3HgCl20.01MCaCl230-70%log30GCLC-3Chen2000XiaPignatello2001CaCl2XiaPignatello2001FreundlichChen1999Carmo2000XingPignatello1997FreundlichNsFreundlichNdYuanXing2001-Kd=qe/CeC2αC2maxKdSOMSOMSOMH-vanderWaalsStevenson1994Varadachari1991SOMLee1998Murphy1990Laor1998HAHAsMurphy1994-3-HASOMTg()300TgsAl3+HAHAHAsHAsCa2+Al3+Pb2+Fe3+-HAs3α-FeOOH)0()0()(22max22==-=CKCKCCKddd14911213GarbariniLion198560KOHFe(NO3)3Laor1998Spark1997Ca2+Al3+5Ca2+11Al3+AgNO3Varadachari1997Laor1998Ca2+Al3+Varadachari19911997Spark1997HAsHA-HAVaradachari19972000-Murphy19901994HANaOHHClpH7.0HA120152hHApH7.02h4HATOC-HAOCHAHANaOHpH5~7AlCl3CaCl2Pb(NO3)2,Fe(NO3)3pH-HAprogrammabledualsyringepumpFe3+-HA-HAAl3+-HAHASOM[1]CHIENY-Y,KIME-G,BLEAMWF.1997.Paramagneticrelaxationofatrazinesolubilizedbyhumicmicellarsolutions[J].EnvironmentalScienceandTechnology,31,3204-3208.[2]SCHWARZENBACHRP,GSCHWENDPM,IMBODENDM.1993.EnvironmentalOrganicChemistry[M].NewYork,NY:JohnWiley&Sons.[3]CHINY-P,AIKENGR,.DANIELSENKM.1997.Bindingpyrenetoaquaticandcommercialhumicsubstances:Theroleofmolecularweightandaromaticity[J].EnvironSciTechnol,31:1630-1635.[4]CHIOUCT.1989.Theoreticalconsiderationsofthepartitionuptakeofnonionicorganiccompoundsbysoilorganicmatter[A].In:SawhneyBL,BrownK,eds.ReactionsandMovementofOrganicChemicalsinSoil[C].1-29.Madison,WI:SoilScienceSocietyofAmerica,Spec.Publ.[5]CHIOUCT,KILEDE.1998.DeviationsfromSorptionLinearityonSoilsofPolarandNonpolarOrganicCompoundsatLowRelativeConcentrations[J].EnvironmentalScienceandTechnology,32,338-343.[6]CHIOUCT,KILEDE,RUTHERFORDDW,SHENGG,BOYDSA.2000.Sorptionofselectedorganiccompoundsfromwatertoapeatsoilanditshumic-acidandhuminfractions:potentialsourcesofthesorptionnonlinearity[J].EnvironmentalScienceandTechnology,34,1254-1258.[7]FREEMANDH,CHEUNGLS.1981.AGelPartitionModelforOrganicDesorptionfromaPondSediment[J].Science,214,790-792.[8]GUSTAFSSONÖ,HAGHSETAF,CHANC,MACFARLANEJ,GSCHWENDPM.1997.Quantificationofthedilutesedimentarysootphase:implicationsforPAHspeciationandbioavailability[J].EnvironmentalScienceandTechnology,31,203-209.[9]HUANGW,YOUNGT,SCHLAUTMANMA,YUH,WEBERWJ,JR.1997.Adistributedreactivitymodelforsorptionbysoilsandsediments.9.Generalisothermnonlinearityandapplicabilityofthedualreactivedomainmodel[J].EnvironmentalScienceandTechnology,31,1703-1710.[10]IRVINEGM.1984.Theglasstransitionsofligninandhemicelluloseandtheirmeasurementbydifferentialthermalanalysis[J].TappiJ,67,118-121.[11]KAMIYAY,HIROSET,MIZOGUCHIK,NAITOY.1986.Gravimetricstudyofhigh-pressuresorptionofgasesinpolymers[J].JournalofPolymerSciencePartB-PolymerPhysics,24,1525-1539.15011220025[12]KAMIYAY,HIROSET,MISOGUCHIK,TERADAK.1988a.Sorptivedilationofpoly(vinylbenzoate)andpoly(vinylbutyral)bycarbondioxide.JournalofPolymerSciencePartB-PolymerPhysics,26,1409-1424.[13]KAMIYAY,HIROSET,NAITOY,MIZOGUCHIK.1988b.Sorptivedilationofpolysulfoneandpoly(ethyleneterephthalate)filmsbyhigh-pressurecarbondioxide[J].JournalofPolymerSciencePartB-PolymerPhysics,26,159-177.[14]KAMIYAY,MISOGUCHIK,HIROSET,NAITOY.1989.Sorptionanddilationinpoly(ethylmethacrylate)-carbondioxidesystem[J].JournalofPolymerSciencePartB-PolymerPhysics,27,879-892.[15]KAMIYAY,NAITOY,HIROSET.1990.Sorptionandpartialmolarvolumeofgasesin