环境友好型无铅低温封接玻璃最新进展

(100024),,,,,:TQ171:A:1003-1987(2007)06-0017-07[1],,,[2],,,,,30%80%,10%12%,10m,,[3],,,2008,,,200671,,[5],,CRTPDP,,,,,,1,,,7120076195,18,As2O3Bi2O3V2O5SnOP2O5PbO,F-O2-2[6],1V2O52P2O5=(711815)10-6/,400600SnO2P2O5CRTPDPVFD=(8191013)10-6/,410490ZnO2P2O5CRTPDPVFD=(8101110)10-6/,390470R2O2Al2O32B2O32SiO2PDP=71510-6/,580R2O2SrO2BaO2SiO2=(9171010)10-6/B2O32SiO2RO2R2O2SiO2=(91259145)10-6/RO2WO32P2O5=(510915)10-6/RO2B2O32Bi2O3=(8101118)10-6/430650111V2O5V2O52B2O32ZnO,,V2O5,,V2O5,V2O52P2O52Tl2O32TeO22R2O[7],V2O5P2O5,,400500,(70130)10-7/,(Tl2O3)(Te),V2O52P2O52Sb2O3[8],400500,,Sb3+,,,,,V2O52Sb2O32As2O32TeO2,,2010-6/,112SnOSnPbIV,Sn2+Pb2+,SnO,Sn2+,Sn2+4,SnSnO2ZnO2P2O5[9213]430500,500103Pas;(1040m),,,,ZrSiO4,,,,SnO2ZnO2P2O5:,201501015cm1010cm,40kVmm-1,,,50%(),SnO,SnO2,,,,8120076195,BeallUSP5,122,484R2O2ZnO2P2O5,475,,,113Bi2O3(Bi2O3),()2000272473P2O52ZnO2Bi2O32CuO,500550,,2211[14]21111,,,,MgOAl2O3SiO2B2O3,,211122P2O5,Li2O2ZnO2SiO2TiO2ZrO2HfO2V2O5Nb2O5Ta2O5Cr2O3MoO3NiOCuO,,Na2O2CaO2P2O5Na2O2BaO2P2O5Na2O2Al2O32P2O5Li2O2BaO2P2O5ZnO2B2O32P2O5TiO2Al2O3,,2Li2ONa2OK2OZnOB2O3Al2O3SiO2P2O523146219021572177661351195[15]2216456177110619131MgO[16]28145315131123136601371119[17]1911046150419022150MgO+4190TiO2+2110ZrO2[18]2917510120571472158TiO2[19]916811077819310132F23118131239193521920174ZrO2151945412221169CoO+8115TiO2181235213319183MnO2+9161TiO218116112820123591201113MoO3[20]1714951151713741225215611212100Cr2O31714951151713741225215611212100Ta2O52017021604317832192CdO1819572139Sb2O3+8166Tl2O3[21]21375014629148410441539112MgO[22]9120076195:(1),,(2),,,,,,(3),,,,(4),(5),,212,,,300,,,,[2],,,,,,,,,3311,,,,80,,,,,312,,,,,,,,,,0220076195,,,,,,[2]4411,,,,1818+2BiSnZn,,[23226];,,;,,,,,,412,,,,,,,,,,,,413,,,41311,,,41312,(-),,122007619541313,41314,,[2]41315//HarukiNiida[27,28]Me2SiCl2:SnCl2:H3PO3(x=015115),/,,Tg1540,200-,,,,,,,5,;,[1],1Na2O2Al2O32B2O3[J]11200523,331[2],1[J]1120058198,40421[3],1[J]112005111[4]SomervailleL1Measuringleadinman1GlassTech[J]11993,134(3):94951[5]1,[J]1123131[6],1[J]112006341,52[7][P]152854901[8]1[P]1CN200310103592111[9]NIPPON[P]1US20020193031[10]R1Morena1PhosphateglassesasalternativestoPb2basedsealingfrits[J]1JNon2CrystSolids,2000,263&264:38223871[11]R1M1[P]CNpatent9510397411,19952112221[12]Ide,Akira1Lead2freesealingglassforignitionplugs[J]1JPPatent2004018335,20042012221[13]Ide,Akira1Lead2freesealingglassandsealingcompo2sitionscontainingsamefordisplaypanels[P]1JPPa2tent2004035316,20042022051[14]1[J]112002121612,431[15]AndrewsAI1PorcelainEnamels:thepreparation,ap2plicationandpropertiesofenamels12ndEdh1GarrardPress,Champaign,ILL,19611[16]McMillanPW,PhilipsSV,PartkidgeG1JMaterSci,1996,1:2691[17]HammetterWF,LoehmanRE1JAmerCeramSoc,1987,70:5771[18]MetcalfeBL,DonaldIW1SilicatesIndustries,1991,526:991[19]CorningGlassWorks1BritPat829447119601[20]DonaldIW1JMaterSci,1987,22:26611[21]1[P]182295531,19961[22]ChenZX,McMillanPW1JMaterSci,1985,20:342812220076195[23]1[P]1CNPat,14532322003211205[24]DingJY,ShihPY,YungSW,etal1Theproper2tiesandstructureofSn2Ca2P2O2Fglasses[J]1MaterChemPhys,2003,82:61[25]ClintonJM,CoCoffeenWW1LowmeltingglassesinthesystemB2O32ZnO2CaO2P2O5[J]1CeramicBull,1984,63(11):1401[26]DayanandC,BhiksshamaishG,TyagarajuVJ,etal1Review:Structureinvestigationsofphosphateglasses:adetailinfraredstudyofthex(PbO)2(12x)P2O5vitreoussystem[J]1JMaterSci,1996,31:1945[27]HarukiNiida,MasahideTakahashi,Preparationandstructureoforganic2inorganichybridprecurorsfornewtypelow2meltingglasses[J]1J1Non2CrystSolids,2002,306:292-2991[28]HarukiNiida,MasahideTakahashi,Preparationandstructureoforganic2inorganichybridlow2meltingphos2phateglassesfromphosphonicacidH3PO3[J]1JMaterialsResearch,2003,18(5):1081-1086TheLatestDevelopmentofGreenLowTemperatureLead2FreeSealingGlassChangjiuLi,YourongHuang,ZhuCui,XipingGao(ChinaBuildingMaterialAcademy,Beijing,100024)Abstract:Thepaperintroducedthedangeroflead2containingmaterialtomankindandenvironmentbriefly,pointedoutthedevelopmentnecessityofleadfreelowtemperaturesealingglass,reviewedtheapplicationanddevelopmentofleadfreelowtemperaturesealingglass,andrecommendedvana2diumsystem,phosphateandbismuthatesystem1Itisemphasizedthatthepriorityresearchshouldcon2sistoffundamentaltheory,newtheoryofglassformation,sinteringandmeltingtheoryandnewpreparationtechnology1Keywords:leadfree,lowtemperaturesealingglass,fundamentaltheoryresearch,glassforma2tiontheory,sinteringandmeltingtheory(13)SiO22PbO2K2O,,,,,,400,,11565,,,;,,,,3D,,[1]RaedtIP,Janssensk1VeekmanJ1etal1TransanalysisfordistinguishingbetweenVenetianandfacon2de2Veniseglassvesselsof16thand17thcentury[J]1JanalSpec2trom2001,16:101210171[2],11[J]12007,41[3],1[M]1:,20061[4]DurmasRH1Extractionofleadfromcrystalware1J1AmerCerSoc11995,74(5):702771[5]WangWei,LuLizhang1Properationandpropertiesofcrystalglasswithoutleadcontent1JWuhanUnivTech[J]1999,14:31[6]AhmadAA1InhibitionofPb2leachingfromleadcrystalglassbycoatingwithfilmspreparedbysol2gelmethod1Jsol2gelSciTech,1998113[123]:75327561ThePast,PresentandFutureofCrydtalGlassWangChengyu,TaoYing(DalianPolytechnicUniversity,Dalian,116034)A