等离子体技术在催化剂制备中的应用

代斌1,2宫为民1张秀玲1何仁1(1.大连理工大学等离子体化学实验室,大连116012;2.石河子大学,石河子832002):,,,:;;;:TQ426.6;O539:AApplicationsofplasmatechniquesinthecatalystpreparationDAIBin1,2,GONGWei-min1,ZHANGXiu-ling1,HERen1(1.PlasmaChemistryLaboratory,DalianUniversityofTechnology,Dalian116012,China;2.ShiheziUniversity,Shihezi832002,China)Abstract:Plasmaisanewtechnologyappliedinmanyfields.Theapplicationsofpreparingcatalystsarereviewed.Theapproachandtheinstallationaswellasrecentprogressofpreparingandregeneratingcatalystsofmetalandmetaloxidethroughplasmamethodareintroduced.Intheend,theprospectonthepreparingcatalystsbyplasmatechnologyisshowed.Keywords:plasmatechnology;catalyst;preparation;application:2001-06-08::,,1969,,,;,,1940,,,,2070,,,,[1],,,,,,[2,3],,[4],1111:,,,/,#13#2112Dec.2001200112ModernChemicalIndustry;,;;,/,112,,11211电弧等离子体法装置[5],CW10Vissokov,11212高频微波等离子体法装置1[6]TiN/TiO2,,(101666Pa),,图1微波等离子体反应装置11213电子回旋共振微波等离子法装置2(ECR)[7,8]TiO2/C-Al2O3Ni/C-Al2O31);2);3);4);5)ECR;6);7/8);9);10)图2ECR微波等离子体制备催化剂示意图2211Vissokov[9]Fe3O4,Fe2O3,FeO,Al2O3,K2O,CaO,SiO2,MgO,,Ar,N2,O2,50nmX:,(019%)HalversonCocke[10],,Ru/Al2O3Ru/Al2O3KhanFrey[11]LaMOx(MCo,Mn,Ni)LaNiOxLaCoOx,Dalai[12]Fe,75Fe/25Co,50Fe/50Co,25Fe/75CoCo()5BETXRD(X)SEM()EPMA(#14#2112),:BET,;350e,3FeCoO#Fe2O3;;X;FeCo,[13]Co-Fe,Fischer-Tropschn(H2)Bn(CO)=210,139Lm/s,275e,0169~1103MPa,CO9815%;0169~1103MPa,43%~50%,C540%,Serdyukov[14],,Rouleau[15]Ni,1@10-4~2@10-4,,,Kameyama[16],SiH4/CH4/Fe(CO)5Fe-S-iC,B-FeSi2;,A-Fe,Fe3Si,Fe5Si3,FeSi,B-SiCSi,5~50nmFischer-Tropsch:B-FeSi2,A-Fe,Fe3SiFe5Si3,COCao[17]SPS();Ohshima[18]Fe,Ni,CoMo(5~20nm),1-,N-iC[19],Al2O3,,CO,,[20][21],5A,,Sugiyama[22],E-,E-,Kiyokawa[23],,,,,Cha[24]PtNafion,,01043mg/cmPt10[6]n(N2)Bn(H2)=1B1/:1,3-#15#200112:[25]A-Al2O3Ni,:850e,9812%,9713%H29615%CO,15hECRTiO2/C-Al2O3Ni/C-Al2O3:,TiO2/C-Al2O3,,C280%,C-Al2O3,C23,1[7];,Ni/C-Al2O3C2,,Ni/C-Al2O3[8]212,,Bibby[26]Vissokov[27](/),2~5,10%N-iO-Al,G56A3~4,Ar/H2SiO2,ZrO2,MoO3V2O5/SiO2,V2O5/TiO2,SiO2Blecha[28]WO3/SiO2,,,,207080,;,,1.[M].:,19932,,.(I):[J].,2001,13(1):193,,.[J].,2000,20(7):134MagaliBoutonnetKizling,SvenGJ¾r¼s.AReviewoftheUseofPlasmaTechniquesinCatalystPreparationandCatalyticReactions[J].AppliedCatalysisA:General,1996,147(1):15VissokovGP,PirgovPS.ExperimentalStudiesonthePlasma-ChemicalSynthesisofaSatalystforNaturalGasReforming[J].AppliedCatalysisA:General,1998,168(2):2296,./[J].,1994,11(1):347,,.[J].,1999,16(5):5658,,.[J].(B),2001,31(2):1749PeevT,VissokovGP,Czako-NagyI,etal.MossbauerSpectraofUnreducedCatalystsforAmmoniaSynthesisObtainedinPlasma[J].AppliedCatalysis,1985,19(2):30110HalversonDE,CockeDL.RutheniumImpregnationofPlasma-GrownAluminaFilms[J].JVacSciTechnol:A,1989,7(1):4011KhanHR,FreayH.PlasmaSprayDepositionofLaMOx(M=Co,Mn,Ni)FilmsandtheInvestigationofStructure,MorphologyandtheCatalyticOxidationofCoandC3H8[J].JAlloysCompounds,1993,10:20912DalaiAjayK,BakhshiNarendraN,EsmailMNabil.CharacterizationStudiesofPlasma-SprayedCobaltandIronCatalysts[J].Industrial&EngineeringChemistryResearch,1992,31(6):1449(下转第18页)#16#2112YXM-92Phi-lADCA,Phi-lADCA-3000,N-5000N-5001,Betz,Chemlindn,Nako,Philips,Chevron,Intecat,YXM-92,,20%~30%10%~18%,H2/CH4115015,,0142,1151,[3],JK-01014~20Lg/g,,56188%39126%,H2/CH451332118,112,[4],,[5],,Gulf2070,Chevron,80IntercatCMP-112,,,,,[6],BetzDM-1152,,,,DM-1152,,,(上接第16页)13DalaiAjayK,BakhshiNarendraN,EsmailMNabil.ConversionofSyngastoHydrocarbonsinaTube-WallReactorUsingCo-FePlasma-SprayedCatalyst:ExperimentalandModelingStudies[J].FuelProcessingTechnology,1997,51(3):21914SerdyukovSI,SafohovMS,ChumakPS,etal.HydrogenationofBenzeneonaNickelCatalystPreparedbySprayinginArgonPlasma[J].Neftekhimiya,1992,1:1815RouleauL,BacaudR,BreysseM,etal.Plasma-ProducedDispersedandDisposableSupportedNickelCatalystforHydroconversionofHeavyOils(II):EvaluationoftheCatalyticActivityintheHydroconversionofaDeasphaltedVacuumResidue[J].AppliedCatalysisA:General,1993,104(2):14916KameyamaT,SakanakaK,ArakawaH,etal.PreparationofUltrafineFe-S-iCPowdersinaRadio-FrequencyThermalPlasmaandTheirCatalyticProperties[J].JournalofMaterialsScience,1993,28(17):463017CaoYA,ZhangXT,ChongLQ,etal.NovelTiO2FilmCatalys-tPreparation,PropertiesandResearchonitsPhotocatalyticOxidizedActivity[J].MaterialsResearchSocietySymposium-Proceedings,1997,497(1):7918OhshimaSatoshi,YumuraMotoo,UchidaKunio,etal.SynthesisofUltraFineMeta-lCarbonCompositeParticlesbyCarbonarc-PlasmaanditsCatalyticActivity[J].NihonEnerugiGakkaishi,1998,77(2):10419,,.[J].,1997,26(11):73620,,.CO[J].,1999,28(5):30121,,.5A[J].,1997,18(2):10622SugiyamaK,AnanG,ShimadaT,etal.CatalyticAbilityofPlasmaHea-tTreatedMetalOxidesonVapor-PhaseBeckmannRearrangement[J].SurfaceandCoatingsTechnology,1999,112(1):7623KiyokawaKazutoshi,MatsuokaHiroyuki,ItouAkihiko,etal.DecompositionofInorganicGasesinanAtmosphericPressureNon-EquilibriumPlasma[J].SurfaceandCoatingsTechnology,1999,112(1):2524ChaSY,LeeWM.PerformanceofProtonExchangeMembraneFuelCellElectrodesPreparedbyDirectDepositionofUltrathinPlatinumontheMembraneSurface[J].JournaloftheElectrochemicalSociety,1999,146(11):405525,,.Ni/A-Al2O3[J].,2000,