高压脉冲液相放电废水处理技术的研究进展

1,213(1.230022;2.200092;3.311300),,,DevelopmentofStudyontheTechnologyofAqueousHighvoltageElectricalDischargeWastewaterTreatmentZHUShuguang1,2DINGYuanyuan1SONGZezheng3(1.Dept.ofEnvironmentalEngineering,AnhuiInstituteofArchitectureandIndustryHefei230022)AbstractThispaperreviewsthedevelopmentofhighvoltageaqueousdischargetechnology,summarizingtheprinciplesandresearchorienta2tion,suchashighvoltageelectricalsource,physicaleffects,reactors,pollutants,degradationmechanisms,andsoon,andproblemsexistedinthistechnologyandtheprospectsareputforward.Keywordspulsedhighvoltagedischargeplasmaliquiddischargetechnology,,,,,,,,,,,,1,(),,(103105A)(102103J/cm3),(104105K),,,(75185nm)[1],,,310GPa,(102103m/s),,10-410-2s,,,,[2],,,,,2,:;;;;2.1,,,:[35],[69][10,11][12](),[4,5]72006324April2006IndustrialSafetyandEnvironmentalProtection,MasudaHosokawa,,[13]LawlessYamamoto,,,,,,[14],Yan[15]2.0kW,,100kV,2050ns,100200ns,11000pps,0.53.0J,65%85%,Mok[16]10kW,140kV,3.3kA,205200pps,3109100kV,2040kA,;(100300pps),;,,,:2.2,,,,1MPa,0.1GPa,1635kK,[17],,[18],:,,,,[19],[20],4.1F,10kV,7mm,1.5km/s,0.3m1.55MPa0.55MPa,30s49MPa,4mm180m/s[21][22],,,,[23],312.5J,50kA,5104K,(10200nm),Lisitsyn[24],2.3,[2529][30,31][32][33]183:(coronadischarge);(streamdischarge);(sparkdischarge)()[28]2.4,22Clementsetal[25],,80%Mizunoetal[34]NaCl4()Sharmaetal[35]Willberetal[31]TNT:1min,200(47kJ),99%Grymonpreetal[36],,1Sunetal[37],,,Sugiartoetal[32]B,,95%[38][39]TNTTNT,[29,4044],,[4549],pH,,,()2.5,,33Clementsetal[25],,,,,Masayukietal[26]HOHSunetal[27]OHOH,50mL/L,1080s/cm,(OHH);80s/cm,,Dwyeretal[50]10s/cmSharmaetal[35,51]Fe2+Fenton,,Onoetal[52],;,Joshietal[53],,Fe2+Fenton,Langetal[30];,,,,,,3,,,,,:(1),,/(2),,,(3)9,,,1,..,1997(2):13162RobinsonJW,HamM,BalasterAW.Ultravioletradiationfromelectricaldischargeinwater.JApplphys,1973,44:723WillbergDM,langPS.Degradationof4chlorophenol,3,4dichloroaniline,and2,4,6trinitrotolueneinanelectrohydraulicdis2chargereactor.EnvironSciTechnol,1966,30:252625344,,.ns.,2000,26(1):14155,,,..,1999,25(2):44466,,.10kW.,1999(3):1171217,,..,1999,39(6):7367408MassimoR,YanK.Evaluationofpulsevoltagegenerators.IEEE,1993,143414419LawlessPA,YamamotoT,PoteatS,etal.Characteristicofafastrisetimepowersupplyforapulseplasmareactor.IndustryApplicationsSocietyAn2nualMeeting.ConferenceRecordoftheIEEE,1993,1875188110..:,199211...,1993.11112LiJ,WuY,WangNH.Industrialscaleexperimentsofdesulfurationofcoalfluegasusingapulsedcoronadischargeplasma.IEEETransactionsonPlasmaScience,2003,31(3):33333713MasudaS.Pulseenergizationsystemofelectrostaticprecipitatorforretrofittingapplication.IEEETransonIndAppl,1988,24(4):70871614LawlessPA,YamamotoT,ShofranS,etal.Characteristicsofafastrisetimepowersupplyforapulsedplasmareactorforchemicalvaporde2struction.IEEETransOnIndustryApp,1996,32(6):1257126515YanK,Heesch,NairSA,etal.Atriggeredsparkgapswitchforhighrepetitionratehighvoltagepulsegeneration.JournalofElectrostatics,2003,57:293316MokYS.Efficientenergydeliveryconditionfrompulsegenerationcircuittocoronadischargereactor.PlasmaChemistryandPlasmaProcessing,2000,20(3):35336417,,,..,2000,28:858718,..,2000(8):31031619,,,..,2001(15):10311020,..,2002,51:1549155321,,,..,2001,21:28228622,,..,2002,51:1768177223LuXP,PanY,LiuKF,rtal.Earlystageofpulseddischargeinwater.ChinPhysIett,2001,18:1493149524LisitsynLV,NomiyamaH,KatsukiS,rtal.Thermalprocessesinastreamerdischargeinwater.IEEETransactiononDielectricsandElec2tricalInsulation,1999,6(3):35135625ClenmentsJS.Preliminaryinvestigationofprebreakdownphenomenaandchemicalreactionsusingapulsedhighvoltagedischargeinwater.IEEETransactiononIndustryApplications,1987,IA23(2):22423426SatoM,OhgiyamaT,ClementsJS.FormationofchemicalspeciesandtheireffectsonmicroorganismsusingapulsedhighvoltagedischargeinWater.IEEETransactiononIndustryApplications,1996,32(1):10611227SunB,SatoM.Useofapulsedhighvoltagedischargeforremovaloforganiccompoundsinaqueoussolution.JphysD:applphys,1999,32:1908191528SugiartoAT,SatoM.Pulsedplasmaprocessingoforganiccompoundsinaqueoussolution.ThinSolidFilms,2001(386):29529929WenYZ,JiangXZ.Pulsedcornadischargeinducedreactionsoface2tophenoneinwater.PlasmaChemistryandProcessing,2001,21(3):34535430LangPS,WillbergDM.Oxidativedegradationof2,4,6trinitrotoluenebyozoneinanelectrohydraulicdischargereactor.EnvironSciTechnol,1998,32:3142314831WillbergDM,LangPS.Degradationof4chlorophenol,3,4dichloroaniline,and2,4,6trinitrotolueneinanelectrohydraulicdis2chargereactor.EnvironSciTechnol,1996,30:2526253432SugiartoAT,OhshimaT,SatoM.Advancedoxidationprocessesusingpulsedstreamercoronadischargeinwater.ThinSolidFilms,2002(407):17417833LukesP,AppletonAT,LockeBR.Hydrogenperoxideandozoneforma2tioninhybridgasliquidelectricaldischargereactors.IEEETransac2tionsonIndustryApplications,2004,40(1):606734MizunoA,HoriYJ,Destructionoflivingcellsbypulsedhighvoltageapplication.IEEETransIndAppl,1998,24:38739435SharmaAK,lockeBR,ArceP,etal.Apreliminarystudyofpulsedstreamercoronadischargefordegrationofphenolinaqueoussolution.HazardousWaste&HazardousMaterial,1993,10(2):20921936GrymonpreDR,FinneyWC,LockeBR.