有机化学(下)复习题——完成反应式答案

1有机化学II总复习（一）——完成反应式解答H+2C2H5CHCOOHOHOOOOC2H5C2H5HOOCCH=CHCHCOOHCOOHOOOCOOHHOOCOHOOCOCOOHCOOHOC6H5COONa+CH2CHCH2BrC6H5COOCH2CH=CH2+CO2NaCH2BrBrCH2OCBrO+CH3CH2CH2COOHBr2POH-H2OCH3CH2CHCOOHBrCH3CH2CHCOOHOHCOOHClHHPb(OAc)4,I2CCl4RONaClHHIOOOC2H5OHH+C2H5OHOOOC2H5OHOC2H5OOOC2H5COClO2NHNNaOHH2O+NCOO2N+CH3NH2CH3OOCH3ONHCH3OHC2H5OHOCH3CH3OC2H5ONaCH3CH3OOHOC2H5NOHLiAlH4H2ONH2H3O+LiAlH4(1)(2)OOCH2OHCH2OHH2,Pd/BaSO4硫喹啉ClCOClCHOClC2H5OHH+CH3CH=CHCH2CH2COC2H5ONaCH3CH=CHCH2CH2CH2OHH+(CH2)12COOCH3COOCH3Na二甲苯(CH2)10OOHCOOC2H5COCl(CH3CH2)2CdCOOC2H5COCH2CH3CH3CH2COCl(CH3)2CuLietherCH3CH2COCH3+OOC2H5MgBrH+/H2O乙醚HOCH2CH2CH2CH2CC2H5OHC2H5H+/H2OCNC6H5MgBrCONaOC2H5CH2COCH2CH3COOC2H5OOCH3+COOC2H5OCH3COOC2H5C2H5ONaCOCH2COOC2H5OH+COOC2H5COOC2H5C2H5ONaOH-2H2OOOH5C2OOCOOCOOC2H5+CH3CH2NO2CH2=CHCOCH3NaOCH3CH3CHCH2CH2CCH3NO2O+OCOOC2H5COOC2H5C6H6NaHOCOCOOC2H5+CH2CN(C2H5O)2COC2H5ONa甲苯CHCOOC2H5CN3+H+NaHCH3OHCOOC2H5etherCH3OCHOCH3CH2CH2COOC2H5LDA,THFCH3CH2ICH3CH2CHCOOC2H5Li+CH3CH2CHCOOC2H5CH2CH3C2H5ONaNCCH2COOC2H5CH3COCH=CHPhNCCHCOOC2H5CHCH2COCH3CH3COCH3(1)(2)CHOOH+ClCH2CO2C2H5NaOC2H5OH/H2OH+/CH3OCH3OCOOC2H5CH3CHOOClCH2COOC2H5KOC(CH3)3tBuOH+OCOOC2H5+CHOBrCH2COOC2H5Zn/C6H6H+1.2.OH-/H2OH+/1.2.CH=CHCOOHC2H5OC(CH2)4COC2H5OONaOC2H5(1)(2)NaOC2H5BrC2H5(1)(2)OH-/H2OH+CO2C2H5OCO2C2H5OC2H5OC2H5+H3O+NHO对甲苯磺酸甲苯ClCH2CH=CH2(1)(2)NOCH2CH=CH2NHOOKOH(s)PhCH2BrH2OOH-N-K+OONOOCH2CH2NH2H3CHNH2PhCCOBr2/OHH3CHPhCNH2NHOOBr2/OHNH2COO-BrNO2Zn/OHH+NHNHBrBrBrBrH2NNH24C6H5CONH2P2O5C6H5CNCH3OHNaN3CH2CClOCH2N=C=OCH2NHCOOCH3CO2HSOCl2CH2N2Ag2OH2OCCHN2OCH2COOHH2O(1)(2)CH2NHCOCH3O2NH2/PtLiAlH4CH2NHCOCH3H2NCH2NHCH2CH3H2NH2/PtOCH3CH2NH2+压力，NHCH2CH3NHCH3HHOHCHO/H+NCH3OmannichreactionOHCH2NH2HNO2OHClNH2OHNaNO2O。CH3COOCHCH2CH(CH3)2C(CH3)3500CC=CH(CH3)3CHCH(CH3)2。500CCH3BrHDCH3CH2HCCCH3COOCH3DOCCH3OHCH3CH2HCCC=CCH3CH2CH3HDCH3CH2CH2CHN(CH3)3OHCH3CH3CH2CH2CH=CH2N(CH3)3OHCH3CH3+CH3CH3。N(CH3)2CH2CH3CH3H2O2200CN(CH3)2CH2CH3O-CH3+CH2CH3CH35NHCH3CH3IAg2OH2O过量NCH3CH3CH3+OH-NCH3CH3CH3++NClNCH3ClHONaOHH2OClHON=NCH3CH3C2H5CH3OCH3CH3OCH3CH3C2H5CO2CH3CO2CH3..HCO2CH3CH3O2C()()HHCO2CH3CO2CH3CH3C2H5++C2H5CH3CH3+CH2N2CH3OCOCCCOOCH3+NNCOOCH3COOCH3++ONCH2=CHCOOCH3NOCH3OOCHOOC2H5HOOC2H5OC2H5OCH=CH2CH2+OCH3CH3CCCH3OOCCOOCH3CH3OCOOCH3COOCH3CH36+SHCHOHCl/ZnCl2SCH2Cl+COOHSBr2CH3CO2H25CoCOOHSBrSH2SO425C。SSO3H+NNCH3IHNNHCH3I-+(1)(2)NCH3CH3NaNH2PhCOClNCH2COphCH3NH2SO4HNO3NNO2NNO2+H3O+CH3NC6H5LiOCHONCH=CHONCH2CHOOLiClClNCH3ONaCH3OH,ClNOCH3NCH3RLiCH2=CHCNNCH2LiNCH2CH2CH2CNC2H5ONaNH2NNaNO2,HClCuBrCH2(COOC2H5)2H3+OBrNCH2COOHNOCHONCCH2COOC2H5CH3COONH4OCH=CCNCOOC2H5+NCH3CCH3ONaNH2NCH=CCH37+HHOHOHCH2OHCH2OHOPhNHNH23HAcHHOHOHCH=NNHphCH2OHNNHphOCH3OCH2OCH3OCH3CH3OCH3OOCH2OCH3OCH3CH3OOH3O++OHCH2OCH3OCH3CH3OOOHCH2OCH3OCH3CH3OCH3OOHO+HHOHOHCH2OHCH2OHOAg(NH3)2+COO-HHOHOHCH2OHHHOOHHCOO-HHOHOHCH2OHCHOHOOHOHCH2OHHHHHHOOOOCHOCH2OHHHHOHOHOHOHOHCH2OHONaBH4CH3COCH3HCl