苯酚钾的合成及应用

121113(1.,111003;2.,1110033.,111003),,:2009-08-10:,,:(2004D072)(Potassiumphenoxide),,,()201,2;;,3;420,,57,,816,,,,1,1.1,,,,,,,:2C6H5OH+2K2C6H5OK+H2(3060),,,,,,,,,,,,50.6%63.3%17Eisenbraun18,,,0.91.20.050.5(),0.510,,,20,,1.2(THF),(),,:C6H5OH+KHC6H5OK+H2,,1.3,1420101.©1994-2013ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:C6H5OH+KOHC6H5OK+H2O,,,,,,,,,,,,,110,100,84.1,86.5%,13.5%,,,,,1.3.13,(),,10,110,1.5h,,,,,5,,20(),,,(),,,,,,(),,1.3.22140%50%,,1000.5h,130140,,1.4,,:C6H5OH+ROKC6H5OK+ROH,,,,1.53.0L/mol,,,,Gavril22,143g/L719mL(1.47mol),,138g(1.47mol)1400mL,,1200mol8010075min,120,110111,,,,190g,98%2(),2.12.1.12.1.223THF(10.410.5mol/L),LiHNaHKH,(),,,24ADVANCESINFINEPETROCHEMICALS111©1994-2013ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.()25,3.21-,,103.3,2-(4-),,,,,,4-,2-,83.4,50,10,,,93.54--2-B,,,2,5-4--2-,4--2-113.612,13,(CTC)CTC,,3.7,,264,,,,,,,1HarryB.MechanismoftheBrominationofPhenolinAqueousSo2lution.JChemSoc,1924,125:9079082RikiHoriuchi.InducedReactionBull.ChemSocJapan,1935,10:3143183HonovskiBR.SomeTransformationofRicinoleicandOleicAcids..ActionofMonopotassiumAnilideandPotassiumPheno2lateuponDibromohydroxystearicandDibromostearicAcids.JAmChemSoc,1914,36(5):102810354HansMeyerZ.TheSynthesisofHydrogenBenzoicAcid.AnalChem,1924,64:72815DavieS,GlyndwrJ,MoiseyP.PlainBearingMaterial.US3420101.©1994-2013ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(3):1821858,..,1998,28(3):24259,,..,1999,(3):313410IliyanaV,Berlinova,AissaAmzil,etal.AmphiphilicGraftCopol2ymersasPhase2transferCatalystsinaSolid2liquidSystem.Jour2nalofMacromoleculesScience,PartA,1996,33(9):1239124711,,.4--2-.,1995,6:555712,,..(),1988,(1):798413,,..,1997,15(3):20420814,,..,1996,13(5):333615WangYifeng,ChanKwokP.Ring-openingPolymerizationofMacrocyclicArylEtherKetoneOligomersContainingthe1,2-dibezoylbenzeneMoiety.JournalofPolymerScience,PartA:Poly2merChem,1996,34(3):37538516JanatpourM,ShaferSJ.ProcessforMakingDiarylCarbonates.US4697034.198517,..(),1980,(4):394218EisenbraunAA.ProcessforMakingAlkaliMetalAryloxides.US4691057.198719LyschkaU,EmmelU.MethodforthePreparationofAlkaliMetalAlcoholates.DD241252.197520.():[].:,200221,..,2008,37(4):38839222GavrilaL,PatrascusC,VasiliuMN.PreparationofAlkaliMetalPhenoxides.RO107949.199423KamalZ,AslnafE.IntonationofMonovalentCationswithSalicyl2aldehyde:EvidenceforExcited-stateIon-pairDissociation.JournalofSolutionChemistry,1983,12(9):62162924,,..,1998,26(3):454825,,..,2008,16(10):4726Hall,JamesE.InitiatorSystemsforPolymerizationof1,3-DienesorCopolymersContaining1,3-Dienes.US4647635.1987SynthesisandApplicationofPotassiumPhenoxideShenGuoliang1SangShuning2LiYinping1ZhangBing1XuTiejun1ChenYuannan3(1.SchoolofPetrochemicalEngineering,ShenyangUniversityofTechnology,Liaoyang111003;2.LiaoyangCompany,ChinaPetroleumGroupEngineeringDesignCo.Ltd.,Liaoyang111003;3.LibraryofLiaoyangCampus,ShenyangUniversityofTechnology,Liaoyang111003)AbstractThemethodsforsynthesizingpotassiumphenoxidewerespecificallyintroduced.Theanalyticalap2proachesofpotassiumphenoxidewerereviewedbriefly.Theapplicationsofpotassiumphenoxideintheorganicsynthesiswerediscussedbriefly.KeyWordspotassiumphenoxide,alkalimetalphenoxide,synthesis,application,catalystChoren2009119,ChorenChoren,2010ChorenFreiberg,,15kt/aBiofuels-news,2009-11-0944ADVANCESINFINEPETROCHEMICALS111©1994-2013ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.