沸石催化剂在炼油和石油化工中的应用

:2002-11-27:,,,(,201208):,:;;;;:TE624.9;TQ424.25:A:1008-1143(2003)06-0019-06LatestadvancesinapplicationofzeolitesinoilrefiningandpetrochemicalindustryYANGXue2ping(SINOPECShanghaiResearchInstituteofPetrochemicalTechnology,Shanghai201208,China)Abstract:Latestadvancesindevelopmentandapplicationofzeolitesinrefineryandpetrochemicalin2dustrywerereviewed,includingtheirapplicationincatalyticcracking,hydrocracking,isomerization,alkylation,andproductionofpetrochemicalssuchasethylbenzene,cumene,LABandcaprolactam.Itwaspointedoutthatzeoliteswillfindwideruseaspoisonlessandenvironmentally2benigncatalysts.Keywords:zeolite;catalyst;refinery;petrochemicals;environmentally2benigncatalystCLCnumber:TE624.9;TQ424.25Documentcode:AArticleID:1008-1143(2003)06-0019-061960WeisePB,1962X,,2070,ZSM25,[1],,,,,,[2]SAPO()MCM222,,,1[3]11.11990(),,CO20036116INDUSTRIALCATALYSISJune2003Vol.11No.6,0105%20%40,,,1Table1Mainzeolitesandrelatedprocessesinrefineryandpetrochemicalindustry2060REY/REXMobil(Selectforming)MobilC5C6(Hysomer)Shell2070ZSM25(MTDP)MobilMobil(MLDW)MobilH2Y(Unicracking)Union2080ZSM25Mobil/BadgerMobilH2USY(R2HYC)ShellGa2ZSM25(Cyclar)UOP/BPPt/K/L(Aromax)Chevron(Tatray)Toray/UOPUSYLummus/UOP/Unocal2090SAPO211(Iso2Dewaxing)Chevron(32DDM)DowEniChemMgAPSO232(Q2Max)UOPMCM222(EBMax)Mobil/Badger(MWI)MobilMCM222Mobil/BadgerREYREXYX;Y;Y1.1.12060,,XY,80Y(USY),,,,[4-5],,;P/Al2O3;USYRON()70ZSM25USYRE2USY,(FCC),,90Si/AlZSM25[6]Si/Al450ZSM25ZSM25(Si/Al55),,,RON,ZSM25,1.1.2,()Mo2NiMo2Co,20200361982Fe2USYR2HYC,USYUSY,TiAl,Ti/HUSY,Mo,Mo/Ti/USY,,,[3],,,USY,,ShellNi/Mo/Al2O3USY(),IFPHytailExxonMobilOctgainIntevep/UOPISALOctgainISALFCC,OctgainZSM25,,;ISAL,,3010-6,C+5,ISAL[7]1.1.3,,,AlCl3,,ShellHysomerUOPIsosiv,PtH,TotalIsomerizationProcess(TIP)2090,MTBE,ShellSKIP[3]Sd2ChemieCEPSAKBRHYSOPARCKSHYSOPARPt,,[8],AxensAkzoNobelATIS22L,,[9]1.1.4C3C4C5,,,B,[10],,UOPAlkylene,Pt2KCl2AlCl3/Al2O3;Topse&KelloggFBA(FixedBedAlkyla2tion),SiO2[11]ABBLummusAkzoNobelAlkyClean,5090,RON96Fortum,[12]1.2,Beckmann,,,1.2.1BF3/Al2O3AlCl3ZSM25Y[13]20036:21Mobil/BadgerMCM222TRANS24EBMax,1995MCM2221210,,[14]MCM222ZSM25,/,EBMax,80%[15]MCM256MCM222,MCM256C,,MCM222,MCM256,ABBLummus/UOPEBOne1990,EBZEBZ26009917%99195%[16]UOP(diphenylethane)[17]CDTECH,AlCl3,2080Mobil/BadgerMCM2221996MCM256,2[18]Table2ComparisonofisopropylbenzenesynthesisprocessesusingdifferentcatalystsMCM222MCM256/112121113/%981082119514/h-11132151010/333/%8418584125841981113071091312021060122112811809145015311808144015265%35%Al2O32,MCM256MCM222,MCM256,UOPUSY,Q2MaxAlPO4231Mg(010030102mol)MgAPSO231,1996JLMQ2Max66kt/a,()99195%[19]UOP2000QZ22000,()99197%,99197%Enichem,Enichem,Al2Si2B,,,CDTECHYCDCumene;Dow(Si/Al70)Dow3DDM,1.2.2(LAB)LAB,C10C14,AlCl3HF1995,UOPPetresaDETAL,,Si/Al=191,1%6%8201[20],98%,85%,90%,ExxonMobilLABMOBCAT3LAB3,MOBCAT2232,(),[3]1.2.3,,ZSM25;,(TS21)H2O2NH3;Beck2mann22200363LABTable3ComparisonofpropertiesoflaboratoryLABproductsoverdifferentcatalystsMOBCATAlCl3HFDETALw/%94889395w22/%503015182530w2,32/%804935452530w/%0105610101510101010Enichem19951996,,O2H2O[21]Beck2mann,MFI,,350,200h,9916%,9517%,9919%[22]1.2.4,;,EnichemBASFDow(TS21)H2O2,,,,[23]BASF2006ArcoPtTS21,[24];DegussaUOPTS21,1.2.5,[25],H2SO4,2,,USYREHYOrbit2300Lanet235USYREHYZSM25Comet2400,,[26],MFIC3C4DCC6,2159Mt/a,720kt/a[27]MFI,RONGORY,,4704,27135%,RON9012[4,28],39013974FC2163912ZHC201FC214ZHC204,,RISOC5/C6180kt/a,,C56614%,C68113%[29],,HAT,MAX201;20036:23,7;;AB296;,TS21,,321,,ITQ21MCM241,/,:[1],.4:[M].:,1993.[2],,[J].,2001,1(1):3-7.[3].[J].,2002,44(4):282-286.[4],.[J].,2002,10(11):1-6.[5]TanabeKozo,HolderickWF.Industrialapplicationofsol2idacid2basecatalysts[J].AppliedCatalysisA:General,1999,181:399-434.[6]BuchananJS.ThechemistryofolefinsproductionbyZSM25additiontocatalyticcrackingunits[J].CatalysisToday,2000,55:207-212.[7].2ISAL[J].,2000,(45):12-13.[8].[J].,2000,(46):11-13.[9][J].EuropeanChemicalNews,2002,77:2027.[10]YooKyesang,SmirniotisPG.TheinfluenceofSi/Alra2tiosofsynthesizedbetazeolitesforthealkylationofisobu2tanewith22butene[J].AppliedCatalysisA:General,2002,227:171-179.[11],.[J].,2002,31(9):759-763.[12].[J].,2002,(31):16.[13],.MCM222[J].,2000,29(3):110-116.[14],.[J].,2000,42(7):537.[15].[J].,2000,(27):15-16.[16].EBOne[J].,1999,(35):15.[17]GajdaGregoryJ.Minimizingdiphenylethaneformationinalkylationofbenzenebyethylenecatalyzedbyzeolitebeta[P].US:6153806.2000.[18]ChengJaneC,etal.Processforpreparingshortchainalkylaromaticcompounds[P].US:5453554.1995.[19].[J].,1999,24(34):43-45,48.[20]KocalJosephA.Detergentalkylationprocessusingafluo2ridedsilica2alumina[P].US:5196574.1993.[21],.:21[J].,2000,29(3):113-116.[22].[J].,2002,25(2):38-41.[23].[J].,2001,(18):3-6.[24]GreyRogerA.Aqueousepoxidationprocessusingmodi2fiedtitaniumzeolite[P].US:6194591.2001.[25],,.[C].,:1998.312-313.[26].21[J].,1998,28(6):1-6.[27],.[M].:,2002.[28],,.GOR2C[J].,2002,7(1):23-27,22.[29]RISOC5/C6[J].,2002,(2):62-64.N2420036