生物质热化学转化制备生物燃料及化学品

:200733(973)(No.2004CB719704)33e2mail:[e-mail]333(100080),,,P3P:TK6;TQ517:A:10052281X(2007)07P821190208Bio2FuelandChemicalsbyThermochemicalTreatingofBiomassWangZeLinWeigangSongWenli33YaoJianzhongLuChangboDuLin(InstituteofProcessEngineering,ChineseAcademyofSciences,Beijing100080,China)AbstractBiomassisakindofsourceofrenewableandenvironmentallybenignenergy.Recently,moreandmoreattentionshavebeenfocusedonitsresearchanddevelopmentwithalargeamountofliteratures.Inthispaper,thetechniquesonthebio2fuelandchemicalsbythermochemicaltreatingofbiomassaresummarized,supplemented,andbrieflycommented,onthebasisofthereportedreviewsandnewlypublishedpapers.Thecontentsofthecatalyticupgradingofthebio2oil,theaqueous2phasereformingforalkanesandthesupercriticalwaterPhydrothermaltreatmentforchemicalsareintroducedemphatically.Keywordsbiomass;bio2fuels;chemicals;catalyticupgrading;aqueous2phasereforming;supercriticalwaterPhydrothermaltreatments,,CO2,[13],,[417],,,,,,,P31,,,,197P820078PROGRESSINCHEMISTRYVol.19No.7P8Aug.,2007©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[18],,(230250),,,,,,,[19]:F2T;[8]103104K/s0151s(500),,[5,7],,200400525MPa2min[8],HTU(hydrothermalupgrading),,,,,HTU,CO2,HPC112,:,;,9917%,,10%;[7,13],,H2,,,11211H2CO,,,H2OCO2,[13],,Co2Mo/Co2Mo/Al2O3Ni2Mo/Al2O3Co2Mo2PPAl2O3[13,2022]11212,,,,H2,,,ZSM25,,Adjaye[23,24]5(HZSM25H2mordeniteH2YSilicaliteSilica2alumina)HZSM25,(coke);H2Y(tar),;Silica2alumina(char);HZSM25H2mordenite,H2YSilica2aluminaSilicaliteWilliams[25],55045050055060019117P8©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[26]HZSM25,HZSM25,,,,,Adam[27]Py2GCPMS4SiPAl20MCM2414K1,K2K3,CuK4,,;;,,K1K2Triantafyllidis[28],500(MSU2SBEA)beta,,Al2MCM241,,,,Ates[29]DHC232HC2K113Q500750,,500;750,,,,C11C31,,,,,,Nokkosmaki[30],ZnO,8024h,55%,ZnO129%,ZnO,ZnO,,insituinbedInsitu,,;inbedInsitu,,,[28]2Huber[14,3132]Metzger[33]C1C15,(),,211C1C6[14,32]5wt%,538K5716bar,PtPAl2O3H2C1C6HCl,pH,H2SiO2PAl2O3,,(5%),[14,32],498538K291119©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[14,32]CC2H2CO2H2,P()PCC,COCO2NiRu212C7C15,CC,1[32]Fig.1Reactionpathwaysfortheproductionofalkanesfromsorbitolovercatalystswithmetalandacidiccomponents[32]P,[14,31],,HMFHMFCCCO2[31]Fig.2Reactionpathwaysfortheconversionofbiomass2derivedglucoseintoliquidalkanes[31]39117P8©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(HMTHFA)222(THF2A)CC,PHMF,,PP,C7C15,2,,[31]:(1);(2);(3)H2;(4)PtPSiO22Al2O3P,,,,3[34],,P,P,,,[16]311PHawaiiAntal[35],45s4min190230(),,(60%)(10%),,Ando[36],,(10MPa),,312,[37]Sasaki[38],3204002533MPa0102016s,,20,60,313P25MPa01051010s,350,,;350,;400[37]P,:(1),,,;(2),,(retro2aldolcondensation)52,3[16]314P2,[16][3941]Okuda[16],2491119©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[16]Fig.3Proposedreactionmechanismofmicrocrystallinecelluloseinsupercriticalwater[16]0136:015(wt),THF,1h,,22(422)2422(BMP),80wt%Saisu[40],,,,,,,4,P3:,59117P8©1994-2007ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),,,,,,(15%),H2,,,P,,,,,,,,,,,[1]BridgwaterAV.ChemicalEngineeringJournal,2003,91(2P3):87102[2](MinNZ).(ProgressinChemistry),2006,18(2P3):131141[3](TanTW),(WangF).(ModernChemicalIndustry),2006,26(4):69,11[4]BridgwaterAV,MeierD,RadleinD.OrganicGeochemistry,1999,30(12):14791493[5]BridgwaterAV,PeacockeGVC.RenewableandSustainableEnergyReviews,2000,4(1):173[6](GuoXY),(YanYJ),(RenZW).(ActaEnergiaeSolarisSinica),2003,(2):206212[7](GuoY),(WangY),(WeiF),(JinY).(Chem.Indu.Eng.Prog.),2001,(8):1317[8](JiangHT),(LiHQ),(ZhangY).(Chem.Indus.Eng.Prog.),2006,13(1):813[9](LiuSF),(WangSY),(BaiXS).(ForestryLabourSafety),2006,(1):2933[10](YangCY),(LuCB),(LXS),(YaoJZ),(LinWG).(ModernChem.Indu.),2006,(4):1014,16[11](ZhuXF),(ZhengJL),(GuoQX),(ZhuQS).(EngineeringScience),2005,(9):8388[12](WangMJ),(TanTW),(ZhuWD).(ScienceTechnologyIndustryofChina),2006,(2):8084[13](ZhangQ),(ChangJ),(WangTJ),(XuY).(PetrochemicalTechnology),2006,(5):493498[14]HuberGW,DumesicJA.CatalysisToday,2006,111(1P2):119132[15]MohanD,PittmanCU,SteelePH.EnergyFuels,2006,20(3):848889[16]MatsumuraY,SasakiM,OkudaK,TakamiS,OharaS,UmetsuM,AdschiriT.CombustionScienceandTechnology,2006,178:509536[17]HuberGW,IborraS,CormaA.ChemicalReviews,2006,106(9):40444098[18](LuoP),(LiuZ).(Chemistry&IndustryofForestProducts),2006,(2):99104[19](WeiHM),(ZhaoH).(ContemporaryChemicalIndustry),2006(4):246249,269[20]ZhangSP,YanYJ,LiTC,RenZW.BioresourceTechnology,2005,96(5):545550[21]ElliottDC,NeuenschwanderGG.DevelopmentsinThermochemicalBiomassConversion.London:BlackieAcadenic,1997.611621[22]SenolOI,ViljavaTR,KrauseAOI.CatalysisToday,2005,100(3P4):331335[23]AdjayeJD,BakhshiNN.FuelProcessingTechnology,1995,45(3):161183[24]AdjayeJD,BakhshiNN.FuelProcessingTechnology,1995,45(3):1