世界导电塑料工业化进展

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(,213164):(),,:;;;:TQ32418:A:1005-5770(2008)04-0001-05ProgressinIndustrializationofWorldwideConductivePlasticsQIYa2guang(ChangzhouVocationalSchoolofLightIndustry,Changzhou213164,China)Abstract:Rapidprogresswasmadeintheindustrializationandlarge2scaleproductionofnovelconductivead2ditives,(suchascarbonnano2tube,nano2graphiteplatelet,conductivepotassiumtitanatewhisker,etc.),highperformanceconductiveplasticsforspecialapplication,masterbatchtechnology,alloytechnologycontaininginher2entconductivepolymerandionicconductivepolymer,etc,andsomepioneerproducttrademarksofinternationallyfamouscompanieswereenumeratedinthispaper,whichcouldbereferencefortheexploitationofnewconductiveplasticsproducts.Keywords:ConductivePlastics;ConductiveAdditive;InherentConductivePolymer;IonicConductivePolymer,,,,(ESD)(),,,(EMI)(RFI),,(EMI)(EMC),,,()EMI/RFICE,,(BCC)[1],2006200510%,7t7175t,,,,1,,,,111(),136420084CHINAPLASTICSINDUSTRYX:,,1955,,qiyaguang@czili1edu1cn©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(ICP),Eeonomer[2]Eeonomer(360),,,ICP,,,,,ICPEeonomer,,[3],,112,,,,[4],,,1/10,,(L/D1000),,:;;;,,,,,,HyperionCatalysisInternationalBayerArkemaNanocyl,,:HyperionFIBRIL;BayerBaytubes2C150P;ArkemaGraphistrengthC100;NanocylNanocyl7000,200465t,1144,2010,30,60%,,20082009,[5],PremixPolyOneGE/LNPRTP[6]113(K2OnTiO2),,,DENTALL(TISMO),013017m,1020m,TISMO,,DENTALL,,,:DENTAL[7]114,,,30%,,,,,,,22008©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(MSU)Drzal[8],(nanoGraphite)nanoGraphite510nm,2%2%5%,,,S|11/kg,Drzal[9]2,,211CE,CE,,,Atex89/686/EEC,,(2004/108/EC)(2004/104/EC),,,RTPAtex(94/9/EC)EN50014EN50018,,RTP100SeriesPPRTP2500PC/ABS[10];Cabot,CabelecXS4865,ATEX95andATEX137,,,2305kg1012g/10min,[11]LNPFaradexDS21003FRHi,2060dBEMI,,212,TechmerLehvossCompounds(TLC)PPSPA6,Electrafil[12](ABS),,,,EMI/RFI60dB,UL94V20(ElectrfilABS21200/SD/FR)Premix[13]Pre2Elec122031,GEPPO/PA,NorylGTX674PCPPO/PA-[14],RTP(1004300),ArkemaSAEJ1645,,1112,[15]:RilsanPA11M2BESNBlkP212CTLRilsanPA12AESNBlkP212CTL,107cmRTP,,,,PBTPPAPEEK[16],,ZBT3364:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(PPS)[17];Bac2,Electro2Phen,ElectroPhen[18],,500S/cmBac23BCC,,(ICP)2011,ICP2400t,,(IDP)311(ICP),ICP,ICPICP,ICP,ICPICPICP,ICP[19]BayerMate2rialScience,Ormecon,PanipolICPPanipolICP,PanipolGE/LNPNoveonRTPPremix,RTPPremixPanipol,PanipolPanipolPanipo,PEPPPSPVCPMMASEBS:(),;,PanipolICP,PanipolCX,3:CXHCXMCXLRTPpanipolICP,ICP100PPICP100HIPPICP400HIPSICP700HDPEICP700ALDPEICP,106109,ICPICP,Premix,ICP,PRE2ELECESD5500,,,EOS/ESDS201201999IEC613402521PRE2ELECESD5500108,,,ESD[20]312(),(IDP)Ion2phasEArkemaNoveonRTP2001Ion2phasE,[21-22]IDP,IonPhaseIPE(IPN),,,,,,PEPP;PSHIPSABSABS/PCASAPMMAPA;TPETPEETPU;SBSSEBS,1091011,,,:ArkemaPebaxMH1657/MV1074,,109101242008©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[23]RTPPermaStatIDP,PMMAABSPCPC/ABSPOMPA[24]4Cabot,,,,ICPIDP411(SSF)80,SSF,,,SSF,,,,,,(EMI)SSF,[25]3N[26],3NEMI2Shield,EMI2Shield,ABSEVANYLONPCPEPAPBTPETPPSPPO,412,,,,,Zyvex(Kentera),,[27],Nanocyl,,PlastiCyl,HyperionPremixNanosperse413,,,,,PanipolIonphasE,PanipolPanipolDXHPanipolDXM,PPPPPS[28],,,,,5,,BCC,2011,11t,7%,1517%,,,[1]MELVINS.ElectroactivePolymers[R].Wellesley:BCCre2search,2006.[2]PlasticsTechnologyGroup.NewConductiveAdditivesGiveBetterESDControl[J].PlastTechnol,2006,52(6):35.[3]SAMIRK.Coatedconductivecarriers:US,7223475[P].2007-05-29.[4]OLIVIERD.CarbonNanotubes:CommercialApplicationsandTrendsinPolymer[J/OL].[2007-02-01].(73)5364:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(5)[5]TIMH.NanotubesfortheCompositesMarket[R].London:CientificaLtd,2005.[6]LILLIM.CarbonNanotubesLotsofPotential2IfthePriceisRight[J/OL].[2007207201].[7]IIZUKAM.Basebodyforphotosensitivedrumandphotosensitivedrum:US,6936389[P].2005-08-30.[8]PAPUM.NNEC07PresentationAbstracts[EB/OL].[2007-11-14].[9]DRZALLT.Expandedgraphiteandproductsproducedthere2from:US,20060231792[P].2006-10-19.[10]EuropeanPlasticsNewsGroup.ElectricalCompoundsforAtexcompliance[J].EurPlastNews,2006,33(1):26.[11]BritishPlastics&RubberGroup.Newconductivecompoundhashighimpactstrength[J].BrPlastRubber,2006(1):20.[12]TLCwebmaster.NewFRABSforStaticDissipation[EB/OL].[2007-10-01].[13]PlasticsEngineeringGroup.Conductive,Static2DissipativePolyacetalCompounds[J].PlastEng,2006,62(2):10.[14]PlasticsTechnologyGroup.ConductivePPO/NylonHandlesPowderCoating[J].PlastTechnol,2007,53(1):25.[15]ModernPlasticsEditorialStaff.GMbetsonnon2conductivefuelpumps[J/OL].[2007-02-15].[16]BritishPlastics&RubberGroup.RTPextendslongfibrecapa2bilities[J].BrPlastRubber,