最新橡胶工艺原理

():TQ330.1:E:100024408(2002)0420054206:15”À(1999)12:11.1()1.2,,,,(Tg)Tg2050,,1-2,,,,(PU)(TPE),,1.3,?,,,,,,,,,;,,22.1,,(),,,4520021-2106Nöm2,,,,,,,,,,2.22-1,,,,,,,,,52.1.1()2.1.22-1NRIR_CH2CCH3CHCH2b21,42100%21,429298%BR_CH2CHCHCH2b21,429298%21,423238%1,22VBR_CH2CHbCHCH2CR_CH2CClCHCH2b21,428790%IIR_CH2Cb_CH2CH3CH3CCH3CHCH2b%SBR_CH2CHCHCH2b_CH2CHbNBR_CH2CHCHCH2b_CH2CHbCN55294EPMEPDM(52222%)CSM_CH2CH2b_CH2CHb_CH2SO2ClCHbCl2543%1.01.4%COECO_CH2CHCH2ClOb_CH2CHCH2ClOb_CH2CH2ObACMANM_CH2CHb_CH2COORCHbX_CH2CHb_CH2COORCHbCNXROT_RSxbRC2H4OCH2OC2H4VMQFVMQ_SiCH3CH3Ob_SiCH3CHCH2Ob_SiCH3CH2CH2CF3Ob_SiCH3CHCH2ObFKMFEPM_CF2CH2b_CFCF3CF2b_CF2CF2CHCH3CH2b2AUEU_ROCONHRNHCOObR(AU)R(EU)a.,,(2-1)(2-5):Ikd2R(2.1)R+Mk1R-M(2.2)(P):P+MkpP(2.3):2PktP2P(2.4):P+AktrP+A(2.5),IMAP;R;P;k,,,652002,,,,,,(),,,,,(C),,1.6,0.5,0.8,50C,0.4,0.04,(0.016),,21,4221,41,23,4,b.,,,,,,,,,(CH2=CHR),(R),,%,,,c.,,,,,21,42,,,,,,,,,22(SBS)22(SIS)SBS(2-6)(2-10)SBSBS,(2-11)S2BßLiÝ(2-12)RßLiÝ+CH2CHRCH2CHßLi݁(2.6)RCH2CHßLiÝ+nCH2CHR(CH2CH)nCH2CHßLi݁(2.7)(SßLiÝ)SßLiÝ+nCH2=CHCH=CH275294S(CH2CH=CHCH2)n-1CH2CH=CHCH2ßLiÝ(2.8)(S-BßLiÝ)SBßLiÝ+nCH2CHSB(CH2CH)n-1CH2CHßLi݁(2.9)(S-B-SßLiÝ)SBSßLiÝ+ROHSBSH+ROLi(2.10)2SBßLiÝ+XRXSBRBS+2LiX(2.11)nCH2CHCHCH2+LiÝßRßLiÝLiÝßBRBßLiÝ(2.12)SBR()E2SBR,S2SBR,S2SBRS2SBR,,222S2SBRE2SBR2-2S-SBRE-SBRS2SBRE2SBRd.,2ÉËÌÎ,(A2),,Al(C2H5)32TiCl3,(2-13),,TiÝ,,,,,,(2.13),2,(EPM)(Tg),,,,EPM,,(EPDM),VCl4AlR2Cl(R)EPMEPDM,,e.,,AABBAB(2-14)(2-15)(c)nAA+nBB_AA-BBh+2nC(2.14)nAB_ABh+nC(2.15),(41)852002a13mm,mm;Ut,,mmn=8.8105ND,nt,:TP=NDtn(5),TP,at,a(5),,3.33.5a,5a,TP[T](6)[T]5a,:,,(),P2201-8-80P2201-3-85,,,,[][1]..[J],1998,3,c.16,17.[2]..[J],1999,6,c.8,9.(58),,,,,,2.3.22.2.3,,a.,(-120C),,(2-16),_CH2CH2bk+SO2Cl2_CH2bl_CHbm-_CHh+SO2+HClClSO2Cl(2.16),,4060C0.63.0%,,,,,b.,(2-17)0100%,,,()14294():TQ330.1:E:100024408(2002)05200502092.32-2,,2-32-2(a)-;(b)-;(c)-2-3,,,,,,,,2.3.1a.(),,,,,,,2-32-4(S8)(Sx),052002©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.Ý2-5,,,2-6,2-3h,,ö,Ac2Sx2Ac,,Acö(CV)(semi2EV)(EV)2-4,2-42-52-4CVsemi-EVEVCVsemi2EVEV,phr2.33.51.01.70.40.8,phr1.20.42.51.25.02.0ö0.10.60.72.52.512,%955020,%55080,%(70C22h),%30201015295()©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.ö,,,ö()N2(CTP),,6,,,,,b.,(2-18)(2-20),,,ROOR2RO(218)RO+P-HROH+P(219)2PP-P(2-20)2PP(-H)+P(+H)(2-21)N,N2,,2A2,,2,,,c.ab,,,,,222(a)2-2(b),,2-2(c),,,,,,d.,,2.3.2a.(TPE),TPE:252002©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(1),,;(2),;(3),;(4),TPE,55-16TPETPE()()(37007800A),,TPE2-7ABA22(SBS)(SPU)2-7TPETPE(a)-ABA:SBS,PS,PB;(b)-:SPU,2-8SBS,(PS)(PB)Tg,-,TgÉ,PBPSËSBSPBPSTPEÊÉ,PS,PB,,,TPE,TPE,TPEPS,2-9,,TPE2-8SBS,SPU,()SPU2-10SPU,2-11,,35295()©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),TPEb.TPE,TPE,,,TPE,TPE,,2.4,,,,,,2.4.1(CB),95%(10-9)2-12,,,,,1,32,,,,,,,,2-122.4.2,,,,,,,,ö,,55295()©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(OR)3SiOR,R,,R,(3-)(TESPT)2-13,,2-13TESPT2.4.3,,22(RFL)(7)2.4.4,,,Tg,,,,C=C,,(HNBR)(NBR),,NBR2HNBR(2-14PdöSiO2VËRhC1(PPh3)3VË652002©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(BR),1,421,22,,,,,(Tg),,,,12,1,22,2.5,,2.5.12.2.3,(MMA)MMAMG(),,,(mesogen),,,,,,,2.5.2(),,,LmLm,,,2.5.3,,,,,,,,2.6,,,75295()©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(PH)POOHPPOOH,P2-15,PPOO,,,,,,2.6.2pphm(1pphm=110-8löl)2-15,,,,,6()200211,,,20021111:1.,(),,,,,,,,,,2.,,,,,,3.111214,,,4.2002111113,10(1111),1015:[phone];:(010)62261173852002©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.():TQ330.1:E:100024408(2002)062005120733.1,,,,,,,3.23.2.1,10%,(),,(),,,,,,,,,,,:,;,,,,,(),,,,,,,150100,3.2.2f3-1,,,L0,;,,,,,3-1(,15296()©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.),,,,(),,,,V1öV,P,,T,(1öV),(),,,,,,,,(1öV),dW,,PdV,fdL,dV,(),,3.33.3.1,,,()3.3.23-2(a)nb0,n0,bibj()r(=bi,i=1,2,),rrrr2(=n0b20),:3-2(a);(b)r=r21ö2=n1ö20b0(3-1)(3-1),rn01ö2,,n0b0n0,n010000,n1ö20(10000)1ö2=100,,100,3-2(b)(,),r2=2n0b20,r:r=(2n0b20)1ö2=n1ö20b(3-2),,H,b0b,,HC-C,(b),()(),r,fST:f=-T(5Sö5r)=(3kTör2)r(3-3)(3-3),fr,,,v(),L0,252002©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),,yzKy=Kz(=1öKx1ö2),KxKyKzxyz,TG(K)xRe(),Re=föL20=[5$Gö5(KL0)]öL20:3-3()Re=(TkTöV0)(K-1öK2)=TeRT(K-1öK2)(3-4),V0(L30),Re(engineeringstress),TöV0,NA,()Te=TöNAV0(3-4),E(K-1),:E(DReöDK)K-1=3TeRT(3-5)(3-5),ETTeQMc(),Te=QöMc,,,,,Te:Te=Qö[Mc{1-2(McöM)}](3-6),M3.43.4.1,Yn0b0(n0b01ö31ö2),,,,RLf(x)µcothx-1öxLf:R=(TeRTö3)n1ö20[Lf-1(Kön01ö2-K-2ö3Lf-1(1öK1ö2n01ö2)](3-7)(3