最新橡胶工艺原理(九)

():TQ330.1:E:167128232(2003)06200462055.3.2Ma.(EPMEPDM),(EPM)1955Natta,,,22,(EPDM),EPDM,,,,,(1)EPMEPDMEPMEPDMVOCl3VCl4(V)AlEt2ClAl2Et3Cl3Al2EPM(Ti)80,,,EPDM,52(ENB),(DCPD)1,42(HD)DCPD,ENBDCPD,HD(2)EPMEPDM,,,EPMEPDM,,,,,1550mol%,20mol%,30mol%,,,,,,(ML1+4,100C)10300,100150,,,,,ENBEPDM5-205-20ENBEPDMEPMEPDMMwöMn25,,510,,EPDM,,642003ENBHDDCPDENBEPDM,,530(V)EPDM,,DCPD,(3)EPMEPDMEPDM,,EPDM,,,,EPDM,0.860.87,EPDM,,EPDM,,,EPM,,,,EPM,,EPM,b.(ACM)(ACM),,1948ACM,ACM,,,,(1)ACMACM,,75C,(2)ACMACM5-21ACM,,,ACM(EA)(BA)(MEA),,-15CACM,100%EA,,(),,BA,ACM,,MEA()-25C-30CACMEA2BAEA2BA2MEA,()-35C-40CMEA2BA5-21ACMACM,1-5%,ACM,22ACM,ACM,ACM(3)ACMACM,,150C74316()180C,80C100CACM,,,,ACMO,,,,ACM,(4)(AEM),1974AEM,,,,,,,AEM,;,;,AEM,20C100C,40CAEM,22AEMOc.(FKM),50(VDF),Viton,,,(1),,100C,(2)5-22225-22(HFP)(TFE),230C,,,,,,-20C,,,,85%2,,C-HC-F,,,,,,22,842003C-HC-F,,316C14d,70%,,,10%,,,Od.(CSM)(-120C),,CSM(,),1951CSM,,(1)CSMCSM,(SO2Cl2),(2)CSMCSM5-232,CSM,(LHDPE)CSM,35%,35%CSM,,,CSM2542%(SO2Cl),,1%,CSM(HDPE)CSM,(LDPE)CSM,(CH2CH2)i(CH2CHSO2Cl)m(CH2CHCl)n5-23CSM(3)CSMCSM,,;,,,,,;;,,CSM;,;;,CSM5.3.3Oa.(CO,ECO,GCO,GECO)1965,,(ECH)(EO)(AGE)ECH(CO)ECH-EO(ECO)AGE-ECH(GCO)AGE-EO-ECH(1),(2)COECOGCOGECO,94316(),,,,,CO;ECO,-40CECO,COECO,GCOGECO,,,,,,5-24(CH2CHCH2ClO)m(CH2CH2O)n5-24(ECO)GECO,,ECO,,5.3.4Qa.(VMQ,PVMQ,FVMQ)CC,(SiO),(1)(2)5-25,SiO101ömol,CC(83ömol3),,CC0%,SiO50%,CH,,Si,,-120C,,,(-60C250C),,,,,,31=4.1868kJ(SiCH3CH3O)m(SiCH3CH=CH2O)n5-25(VMQ)(MQ),,,(VMQ),0.030.3mol%,,,,,(PMQ)(PVMQ),510mol%,,-90C,(FVMQ)052003,,,,(),,,,,1002000,,,,,,,100C(VMQ),,(LIM)(3),,O,,()[:](8)()A687072736362,KNöm576559675359(E=150%),100.186.148.769.75(Qv),8m0.470.250.0470.04273533520%1.210.880.1240.094732019792d0.960.670.0980.0811330665,,[][1]StudebakerM.R.,BeattyJ.R.[J].Elastomer2ics.1977.V.109.N10.P.4147;1977.V.109.N11.P.2532.[2]GesslerA.M.,HessW.M.,MedaliaA.L.[J].Plast.Rubber.1978.V.3N3.P.109120;1978.V.3.N4.P.141156.[3]DevineyM.A.[J].Rubber,Plast.Age.1968.V.49.N13.P.9698;[J].Adv.Coll.Int.Sci.1969.N2.P.237259.[4]MarchP.A.,VoetA.[J].Carbon.1971.V.9.N6.P.797802.[5]..[J]....1980.T.53.1.C.174177.[6]..,,[J].,2001,3,.1418.[:]15316()