Thermodynamic Properties as a Function of Temperat

thermodynamiCProPertiesasafunCtionoftemPeraturel.V.Gurvich,V.s.iorish,V.s.yungman,ando.V.dorofeevaThethermodynamicpropertiesC°p(T),S°(T),H°(T)-H°(Tr),-[G°(T)-H°(Tr)]/Tandformationproperties∆fH°(T),∆fG°(T),logKf°(T)aretabulatedasfunctionsoftemperatureintherange298.15to1500Kfor80substancesinthestandardstate.Theref-erencetemperature,Tr,isequalto298.15K.Thestandardstatepressureistakenas1bar(100,000Pa).ThetablesarepresentedintheJANAFThermochemicalTablesformat(Reference2).ThenumericaldataareextractedfromIVTANTHERMOdatabasesexceptforC2H4O,C3H6O,C6H6,C6H6O,C10H8,andCH5N,whicharebaseduponTRCTables.Seethereferencesforinformationonstandardstatesandotherdetails.references1.Gurvich,L.V.,Veyts,I.V.,andAlcock,C.B.,Eds.,ThermodynamicPropertiesofIndividualSubstances,4thed.,HemispherePublishingCorp.,NewYork,1989.2.Chase,M.W.,etal.,JANAFThermochemicalTables,3rded.,J.Phys.Chem.Ref.Data,14,Suppl.1,1985.No.FormulaNameState1ArArgong2BrBromineg3Br2Dibromineg4BrHHydrogenbromideg5CCarbon(graphite)cr6CCarbon(diamond)cr7C2Dicarbong8C3Tricarbong9COCarbonoxideg10CO2Carbondioxideg11CH4Methaneg12C2H2Acetyleneg13C2H4Ethyleneg14C2H6Ethaneg15C3H6Cyclopropaneg16C3H8Propaneg17C6H6Benzenel18C6H6Benzeneg19C10H8Naphthalenecr,l20C10H8Naphthaleneg21CH2OFormaldehydeg22CH4OMethanolg23C2H4OAcetaldehydeg24C2H6OEthanolg25C2H4O2Aceticacidg26C3H6OAcetoneg27C6H6OPhenolg28CF4Carbontetrafluorideg29CHF3Trifluoromethaneg30CClF3Chlorotrifluoromethaneg31CCl2F2Dichlorodifluoromethaneg32CHClF2Chlorodifluoromethaneg33CH5NMethylamineg34ClChlorineg35Cl2Dichlorineg36ClHHydrogenchlorideg37CuCoppercr,l38CuCopperg39CuOCopperoxidecr40Cu2ODicopperoxidecr41CuCl2Copperdichloridecr,lNo.FormulaNameState42CuCl2Copperdichlorideg43FFluorineg44F2Difluorineg45FHHydrogenfluorideg46GeGermaniumcr,l47GeGermaniumg48GeO2Germaniumdioxidecr,l49GeCl4Germaniumtetrachlorideg50HHydrogeng51H2Dihydrogeng52HOHydroxylg53H2OWaterl54H2OWaterg55IIodineg56I2Diiodinecr,l57I2Diiodineg58IHHydrogeniodideg59KPotassiumcr,l60KPotassiumg61K2ODipotassiumoxidecr,l62KOHPotassiumhydroxidecr,l63KOHPotassiumhydroxideg64KClPotassiumchloridecr,l65KClPotassiumchlorideg66N2Dinitrogeng67NONitricoxideg68NO2Nitrogendioxideg69NH3Ammoniag70OOxygeng71O2Dioxygeng72SSulfurcr,l73SSulfurg74S2Disulfurg75S8Octasulfurg76SO2Sulfurdioxideg77SiSiliconcr78SiSilicong79SiO2Silicondioxidecr80SiCl4SilicontetrachloridegOrder of listing of Tables5-43487_S05.indb433/14/062:39:00PMJ/K.molkJ/molT/KC°pS°–(G°–H° (Tr))/TH°–H° (Tr)∆fH°∆fG°log Kf1.ARGONAr(g)298.1520.786154.845154.8450.0000.0000.0000.00030020.786154.973154.8450.0380.0000.0000.00040020.786160.953155.6602.1170.0000.0000.00050020.786165.591157.2004.1960.0000.0000.00060020.786169.381158.9246.2740.0000.0000.00070020.786172.585160.6538.3530.0000.0000.00080020.786175.361162.32210.4310.0000.0000.00090020.786177.809163.90912.5100.0000.0000.000100020.786179.999165.41014.5890.0000.0000.000110020.786181.980166.82816.6670.0000.0000.000120020.786183.789168.16718.7460.0000.0000.000130020.786185.453169.43420.8240.0000.0000.000140020.786186.993170.63422.9030.0000.0000.000150020.786188.427171.77324.9820.0000.0000.0002.BROMINEBr(g)298.1520.786175.017175.0170.000111.87082.379–14.43230020.786175.146175.0180.038111.83882.196–14.31140020.787181.126175.8332.11796.67775.460–9.85450020.798185.765177.3734.19696.91070.129–7.32660020.833189.559179.0976.27797.13164.752–5.63770020.908192.776180.8278.36497.34859.338–4.42880021.027195.575182.49910.46197.56853.893–3.51990021.184198.061184.09312.57197.79648.420–2.810100021.365200.302185.60414.69898.03642.921–2.242110021.559202.347187.03416.84498.29137.397–1.776120021.752204.231188.39019.01098.56031.850–1.386130021.937205.980189.67621.19598.84426.279–1.056140022.107207.612190.90023.39799.14120.686–0.772150022.258209.142192.06525.61599.44915.072–0.5253.DIBROMINEBr2(g)298.1536.057245.467245.4670.00030.9103.105–0.54430036.074245.690245.4680.06730.8362.933–0.511332.2536.340249.387245.6711.235pressure=1bar40036.729256.169246.8923.7110.0000.0000.00050037.082264.406249.6007.4030.0000.0000.00060037.305271.188252.65011.1230.0000.0000.00070037.464276.951255.72014.8620.0000.0000.00080037.590281.962258.69418.6150.0000.0000.00090037.697286.396261.53022.3790.0000.0000.000100037.793290.373264.21926.1540.0000.0000.000110037.883293.979266.76329.9380.0000.0000.000120037.970297.279269.17033.7300.0000.0000.000130038.060300.322271.45137.5320.0000.0000.000140038.158303.146273.61541.3430.0000.0000.000150038.264305.782275.67345.1640.0000.0000.0004.HYDROGENBROMIDEHBr(g)298.1529.141198.697198.6970.000–36.290–53.3609.34830029.141198.878198.6980.054–36.333–53.4669.30940029.220207.269199.8422.971–52.109–55.9407.30550029.454213.811202.0055.903–52.484–56.8545.93960029.872219.216204.4368.868–52.844–57.6945.02370030.431223.861206.88611.882–53.168–58.4764.36380031.063227.965209.26914.957–53.446–59.2143.86690031.709231.661211.55518.095–53.677–59.9213.478100032.335235.035213.73721.298–53.864–60.6043.166110032.919238.145215.81624.561–54.012–61.2712.9095-44 Thermodynamic Properties as a Function of Tempera