矿物材料在有机废水处理中的应用

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(2006)02-0046-071,2,1(1.,610225;2.,650093):,,.:;;:XT03:AApplicationofMineralsinOrganicWasteWaterTreatmentYANGYi2jin1LIZhi2zhang2LIUJian2ying1(1.Dept.ofEnviron.ChengDuUniversityofInformationTechnologyChengdu610041;2.KunmingUniversityofScienceandTechnologyKunming650093)Abstract:Naturalmineralsormodificationofmineralsanditsapplicationinpurificationoforganicwastewaterisapopularresearchsubjectofwastewatertreatmentbecauseofitsbetteradsorption.Inthispaper,theapplicationsofmineralmaterialsinorganicwastewatertreatmentaresummarizedandtheapplicationprospectispredicted.Keywords:Mineralmaterials;Organicwastewater;Application1,,,,,,,,,.2,,,,,.,64:(1965-),,,,.:E-mail:[e-mail];13688409811.:2006-04-21SichuanNonferrousMetals20066©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[1]WinnieMatthes[2]3-3-DipaD[3]GoyneKW[4]SiO2Al2O3-BanatFA[5],,S.Gi2tipour[6],,IVGlazunova[7],C.Breen[8],G.JockChurchman[9],Steven[10]1,2,4-Sung[11]:2-,3-,4-:3-4-2-Emmanuelle[12]4-2,5-Theopharis[13]Al2O32,4-2,4,6-,26.3%75.6%95.2%SPalOR[14],,91.5%73.25%Gonzlez-Pradas[15]-CeZr,--YHHsu[16]HDTMA2,4-,Saeid[17],75%87%89%89%.,[18](4),485%[19]:,COD[20](TMA)(HDTMA)[21],225mg/g266mg/l437mg/l[22],X-3B[2326]()()(TMAB),,-,[2731],(STB)(AZB)COD(CTMAB)CTMAB,[32],COD90%70%[33],--,:,COD742:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[34].3,,40,,(Si,Al)O4,,(400800m2/g),,,.[3536]13X,:,10min,;,93%;,100%,;13XSSCODCr.JorgensenTC[37],,,10g/LNaCl,,,LeeHS[38]4000mg/l,,,[39]pH9CODcr3500mg/L,1900,CODcr450960mg/L,23.RazeeS[40]4h,,,4-,4-,2-,4-,2-,2--4-45%64%,(CDs),-CD65%74%[41]---,,.[42]-,,[43]O3--GAC,,O3--GAC,CODMnUV25430%48%80%95%40%70%50%80%70%95%30%50%[44],0.52.0mm,,,[45],,NH3-NNO2-NMn90.4%93.4%95%30%72%77%.CHCl3TCE(),MTBE(),,84:2©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[46](SiO2/Al2O3)MTBECHCl3TCE,MTBECHCl3TCE812[47]Bouf2fardSC[48]HDTMA(),,DHA()Li[49]HDTMA,Li[50]HDTMA(PCE),,CO2,MeshkoV[51].4MgAlSi,SiO2,Al2O3Fe2O3MgO,,,-OH.[52]:,CODcrBOD5PO43-,[53],92%,,,[54],[55]3,,,,TiO2/,67.2%,TiO2TiO2/.5[56]:,,80%,6%,,[57],,92%.JianLuoJ[58](OMS-2,,),,T300,,CO2H2O,,,,LiuXR[59]F3B,pH,,XiaoChen[60](Cu2+,Zn2+,Ni2+,Co2+,Al3+Mg2+)(OMS-2)2-,(89%100%),(6%)CO2XRD,,M-OMS-2:(KMn8O16)v(MnOy(1y2))v(Mn3O4)v(MnO),942:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[61]-,,CO2H2O,MnOMn3O4.6,,,:(1),;(2),;(3);(4),,,,,,.:(1),,,,(2),(),,(3),,,,,;,,,,(4),,;,(5),,(6),,,,,.1SellaTriantafyllou,EiriniChristodoulou,ParaskeviNeou.SyngounaremovalofNickelandCobaltfromaqueousbyNa-activitedbentonite[J].ClayandClayminerals,1999,47(5):567-572.2WinnieMatthes,GuentherKahr.SorptionoforganiccompoundsbyAlandZr-hydroxyintercalatedandpil2laredbentonite[J].ClaysandClayMinerals,2000,48(6):593-602.3DipaGhosh,KrishnaG.Bhattacharyya.AppliedClaySci2ence,2002,(20):295-300.4GoyneKW,ChoroverJ,KubickiJD,etal.Sorptionoftheantibioticofloxacintomesoporousandmonporousalumi2naandsilica.JournalofColloidandInterfaceScience,2005,283(1):160-170.5BanatFA,BashirAB,AshehAS,etal.Adsorptionofphenolbybentonite[J].EnvironmentalPollution,2000,27(6):391-398.6GitipourSaeid,BowersMarkT,BodocsiAndrew.Theuseofmodifiedbentoniteforremovalofaromaticorganicsfromcontaminatedsoil[J].JournalofColloidandInter2faceScience,1997,196(2):191-198.7IVGlazunova,YuYaFilonenko,AVBondarenko.Pro2ducingahighlyeffectiveadsorbentfromnaturalalu2mosilicarebymodificationwithorganosiloxanes[J].CokeandChemistry,2004,(1):33-35.8BreenC,WatsonR.Polycation-exchangedclaysassor205:2©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[J].JournalofColloidandIn2terfaceScience,1998,208(2):422-429.9ChurchmanGJock.Formationofcomplexesbetweenbentoniteanddifferentcationicpolyelectrolytesandteiruseassorbentsfornon-ionicandanionicpollutants[J].AplliedClayScience,2002,21(34):177-189.10StevenKDentel,AhmadIJamrahandDonaldL.Sparks.Sorptionandcosorptionof1,2,4-trichlorobenzeneandtannicacidbyorgano-clay[J].WaterResourse,1998,32(12):3689-3697.11SungCKwonandDongISong.Adsorptionofphenolandnitrophenolisomersontomontmorillonitemodifiedwithhexadecyltrimethylammoniumcation[J].Separa2tionScienceandTechnology,1998,33(13):1981-1998.12EmmanuelleMontarges,AgnesMoreau,LaurentJMi2chot.RemovingoforganictoxicantsfromwaterbyAl13-pluronicmodifiedclay[J].AppliedClayScience,1998,13:165-185.13TheopharisGDanis,TriantafyllosA.Albanis,DimitriosEPetrakisandPhilipJPomonis.Removalofchlorinatedphenolsfromaqueoussolutionsbyadsorptiononaluminapillaredclaysandmesoporousaluminaaluminumphos2phates[J].WaterResourse,1998,32(2):295-302.14PalOR,VanjaraAK.Removalofmalathionandbu2tachlorfromaqueoussolutionbyclaysandorganaclays[J].SeparationandPurificationTechnology,2001,24(11):107-11