近年国内外毛细管气相色谱柱的进展和趋向

(1930-),,1953,1998(),1986,,:,,(,,,)180,1P3SCI(,;,;,;,)16,30(:,100081):O65:A:100020720(2009)032103220:,GC,,,GC,,5%,100%PEGOV217OV21701:;;,,,,,,[A1]Golay1958,1979DandeneauZerenner80,,,,(GasChromatography)[A2A5],GC:1.,2.GC,3.GC,GC11.1(IL)GC:[A1]GC60()GC,,GC(IL),,(RTILs),,,,[B1],,;,,,,30128320093ChineseJournalofAnalysisLaboratoryVol.28.No.32009-3,,,-70300400,,;,;;,1999,Armstrong[B2]199912232([BuMIm][PF6])([BuMIm][Cl]),,:;,1[BuMIm][PF6][Bu2MIm][Cl]1[BuMIm][PF6][BuMIm][Cl]McRynolds(100)[B2]Tab.1McReynoldsconstantof[BuMIm][PF6]and[BuMIm][Cl]columnsX3Y3Z3U3S3000000DB25276671936364[BuMIm][Cl]74437113245212216[BuMIm][PF6]107251178308244218OV2221601881912832532153X-(I);Y-(I);Z-22(I22);U-(I);S-(I);OV22265%,GC,21.280,,,[B18],[B19]GCVolkerSchu2rigGC[B20],,,,,GC2Tab.2ThereviewsandpapersonionicliquidsusedasGCstationaryphasespublishedinrecentyears1()B32B432B54()B65()B76()B87()B98()B109()B1110GC2MSB1211GCB1312B1413B1514B1615B172GC7090GC,10GC,,GC(Agilent),(Alltech),(Restek),SGE(Supelco),(Varian)(Zebron-Penomenex),2007200834GC,Agilent2008[C3],,,,GC,Agilent,540128320093ChineseJournalofAnalysisLaboratoryVol.28.No.32009-332007[C1]Tab.3Theparametersofnewchromatographycolumnsatthe2007PittsburghConferencePmPmm,PmGS2OxyPLOTAgilentPLOT100.25P10ASTMD7059PD4815PD5599InnertCapChiramixGLSciencesWCOT0.250.25P30,180P200Rxi25msGCPMSRestekWCOT5%295%0.15GCPMS,Rxi25SilMSRestekWCOT5%295%0.15GCPMS,-60360ZerbronMultiResidue21&2PenomenexWCOT0.21.0EPA808120,,320P340ZerbronZB21HTPenomenexWCOT100%0.10.250.18,0.25,0.32P15,20,30400P430ZerbronZB25HTInfernoPenomenexWCOT5%295%0.10.250.18,0.25,0.32P15,20,30400P43042008[C2]Tab.4Theparametersofnewchromatographycolumnsatthe2008pittsburghconferencePmPmm,Pm007217MSQuadrexWCOT011,0125,0150110153P10100,350P380,GCPMS00721MSQuadrexWCOT011,0125,015,1100110153P10100,350P380,GCPMSJ&WAgilentWCOT230118GCPMSMTX2BiodiesilTGRestekWCOT5%295%01160153P14,,430PrecixGCHamiltonWCOT40Rxi25SilMSRestekWCOT5%295%011,0125,015,110GCPMS,-60360,VB2FluoroVICIGigHarborWCOT0125,1100125,0153P30()VF2WaxmsVarianWCOT01121001150153P1060VactorFour,250P260ZerbronZB25MS1PenomenexWCOT5%295%01111001180132P1061,,ZerbronZB2XLBPenomenexWCOT0125,01501250132P15,30160,,,PCB50128320093ChineseJournalofAnalysisLaboratoryVol.28.No.32009-35Agilent[C3]Tab.5Agilentsnew,moredemanding,beronetestprobemixture11212120.53n20.544215n216171,2218n2191211032111n21RestekGC,RxiTM25msGC[C4],GC2MS,,VarianFactorFour[C5],VF25ms5%,95%,3251pA(30m,0.25mm,0.25m)VF25msVF21ms,VF21msVF25ms,,23(ZerbronMultiResidue21&2,MTX2BiodiesilTG,VB2Fluoro,ZerbronZB2XLB)3,3GC(),ElsevierJSepSci200720083.1200720086200720087165GC167620072008GCTab.6StatisticsofthegaschromatographiccolumnsusedinthepaperspublishedatChinesejournalofanalysislaboratorybetween2007200814225221,32222GCHP25(30m0.32mm0.25m)D1217GC2EI2MSDB25MS(30m0.25mm0.25m)D23DEIPGC2MSDB25MS(30m0.25mm0.25m)D34ECDDB2FFAP(30m0.32mm0.25m)D45GC2MSHP25MS(30m0.25mm0.25m)D56GC2MSHP25(30m0.25mm0.25m)D67GC2MSOV217(30m0.25mm0.5m)D78GC2MS8SPB21(Supelco)(30m0.25mm0.25m)D89GC22DM2FFAP()(30m0.32mm0.5m)D910INERTEARINERTEAR()(60m0.25mm0.4m)D1011PyGCSE230()(30m0.32mm)D1112SPE2NPDHP2608(30m0.53mm0.5m)D121322DB25MS(30m0.25mm0.25m)D1314HP25MS(30m0.25mm0.25m)D14155DB21701(30m0.53mm0.25m)D15167HP235(30m0.25mm0.25m)D161722DB25(30m0.25mm0.25m)D1718GC2MSHP25MS(30m0.25mm0.25m)D18192DB25(30m0.25mm0.25m)D19202GC2MS2SIMHP2VOC(50m0.32mm1.8m)D20212GC2MSOV21701(30m0.32mm0.25m)D21222GC2MSPONA(50m0.2mm0.5m)D2260128320093ChineseJournalofAnalysisLaboratoryVol.28.No.32009-36(ContinuedTab.6)232GC2MSHP25MS(30m0.25mm0.25m)D23248DB25(30m0.25mm0.25m)D2425HP25(30m0.32mm0.25m)D25262CP2SIL8(30m0.25mm0.25m)D26272DB235(30m0.25mm0.25m)D27282PEG20M(30m0.32mm0.5m)D2829DB2FFAP(30m0.25mm0.25m)D29302HP25MS(30m0.25mm0.25m)D3031HP2GC(30m0.53mm1.0m)D3132CPSil5CB(25m0.53mm)D3233GC2MS2SIMDB21(30m0.32mm1.0m)D3334GC2NCI2MSDB25MS(30m0.25mm0.25m)D34352CP2Wax52CB(30m0.32mm0.5m)D3536FFAP(22m0.25mm0.32m)(PE)D36372DB21701(30m0.32mm0.25m)D3738(2.1m3.2mmi.d.)D38392OV21701(50m0.25mm0.33m)D394022HP21(60m0.32mm1.0m)D40412213(a)HP25MS(30m0.25mm0.25m)D41422HP25(30m0.32mm0.25m)D42432HP21701(30m0.32mm0.25m)D43442PPE25MS(30m0.25mm2.65m)D44452HP25(30m0.53mm0.25m)D4546CH2Cl2CHCl3DB25MS(15m0.53mm0.32m)D4647HP25(30m0.32mm0.25m)D4748GC2MSPEG20M(30m0.25mm0.25m)D4849DB217MS(30m0.25mm0.25m)D495014HP25(30m0.32mm0.25m)D5051DB21MS(30m0.25mm0.25m)D5152GC2MSHP25MS(30m0.25mm0.25m)D5253HP25(30m0.25mm0.25m)D53542SE254(30m0.32mm0.32m)D5455OV2225(25m0.32mm)D55562HP25MS(30m0.25mm0.25m)D5657DMPPDB21701(30m0.25mm0.25m)D5758GC2MSPICP2MSHP25MS(30m0.25mm0.25m)D5859212HP25(30m0.32mm0.25m)D5960C18PAEsDB25(30m0.32mm0.25m)D6061216DB25(30m0.25mm1.0m)D6162HP25(30m)D62632DB25(30m0.25mm0.25m)D636422HP25(30m0.32mm0.25m)D6465HP25(30m0.25mm0.25m)D6570128320093ChineseJournalofAnalysisLaboratoryVol.28.No.32009-36(ContinuedTab.6)66+(10m0.25mm)D66672PE2Elite5MS(30m0.25mm0.25m)D6768CO22OV217(30m0.32mm0.25m)D6869HP21(30m0.53mm1.5m)D6970HP25(30m0.32mm0.25m)D7071D7172MDMAMDA2HP25(30m0.32mm0.25m)D727322HP25MS(30m0.25mm0.25m)D7374HP25MS(30m0.25mm0.25m)D74752HP25MS