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在此输入标题副标题IntroductionExperimentalResultsanddiscussionConclusionIntroductionChitin(poly-β-(1,4)-N-acetyl-d-glucosamine)isthesecondmostabundantnaturalbiopolymeraftercelluloseandabasicstructuralcomponentoffungiandyeastcellwalls,aswellasofnumerousinvertebrates.自然界中含量仅次于纤维素的一种天然高聚物Thechitin-basedscaffoldsrecentlyfoundbyourgroupsinmarinespongesarethree-dimensionalnetworksoftube-likeinterconnectedfiberswithadiameterofabout100μminthecaseofAplysinaaerophoba.支架是通过直径约100μm的管状纤维连接形成的三维网络Theadsorptionbehaviorwastestedinlifelikeconcentrationranges.Wefurtherattemptedtodesorbtheuranylinordertorecoverthespongechitinandmakeitreusable.Thekineticsoftheadsorptionprocesswereexaminedtodeterminethetimeneededfortheadsorption.Theinteractionmechanismsbetweenchitinanduranylwereexaminedwithsolid-stateNMR,infrared,Ramanaswellastime-resolvedlaserfluorescencespectroscopy.ExperimentalMarinespongeAplysinaaerophoba:collectedintheAdriaticSea(KotorBay,Montenegro)anddriedonair.NaOHplatelets:purchasedfromGrüssing(99%).Concentratedaceticacid:purchasedfromVWR(HPLCgrade).α-Chitin:purchasedfromCarlRothGmbH(depure).NaClO4·2H2O,NaOHandHCl:purchasedfromMerck(analyticalgrade).ConcentratedHNO3:purchasedfromCarlRothGmbH(analyticalgrade)anddistilledbeforeusage.A1000mg/lrhodiumsolution:purchasedfromMerck(ICP-MSstandard).UO2(ClO4)2:0.102MIonicstrength:0.5M(NaClO4)Resultsanddiscussion►Thespongechitiniscompletelyacetylatedwithinthelimitsofexperimentalerror.(甲基的相对强度为103%)►Theextractedfibersconsistofconcentricallyarrangedandlooselypackedtubularstructureswithhollowspacesinbetween.(由松散的同心排列的管状结构组成)►Chitinnetworksdriedwerethusnotusefulforadsorptionexperimentsanymore.Freeze-driedchitinmaintaineditsthreedimensionalshape.Thespecificsurfaceoffreeze-driedsampleswas4m2/g.However,uranyladsorptiondidnotyieldreproducibleresultsforfreeze-driedspongechitin.Thesurfaceareavaluemightbehigherinhydratedchitin.(水合甲壳素的比表面积值可能更高)►ThehydratedspongechitinfromA.aerophobastillcontainedapprox.90wt%water.Itislikelythatasignificantpartofthewaterisstoredinthespaceswithinthefibers.(水是存储在在纤维空间的一个重要组成部分)►Chitinnetworksfrommarinespongeswereshowntobepromisingmaterialsforthepurificationofwaterfromuraniumcontamination.►Spongechitineffectivelysorbsuranyl.►Insummary,A.Aerophobaspongechitinisamaterialwithfavorablepropertiesforwaterpurificationbybothindustryandconsumers.Conclusion
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