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一、什么是玻璃纤维I.Whatisfiberglass?1.材料分类MaterialCategory2.产品品种Productcategory3.主要性能Mainproperties4.主要产品Mainproducts1、材料分类Materialcategory—Steel钢铁—Metal金属—Nonferrousmetals有色金属—Organicmaterials有机材料Materials—Fiberglass玻璃纤维材料FRP/Highperformancecomposites—NonmetalSpecialglass/deep-processedglass非金属—InorganicSpecialceramicmaterialsArtificialcrystal无机材料SyntheticmicaLasercrystal—Specialcementingmaterial2、产品品种Productcategory—Medium-Alkalifiberglass(C)中碱—ContinuousfiberglassAlkali-freefiberglass(E)无碱连续玻璃纤维—High-Alkalifiberglass(A)高碱Staplefiberglass&glasswool玻璃棉Fiberglass玻璃纤维—High-strengthfiberglass(S)高强High-modulusfiberglass(M)高模量High-silicafiberglass高硅氧—SpecialfiberglassAlkali&corrosionresistantfiberglass抗碱特种玻璃纤维Opticalcommunicationfiberglass光通信—Light-guidefiberglass光导3、玻璃材料Glass-makingmaterialsa)中碱玻璃原料C-glassrawmaterials中碱玻璃球C-glassmarble中碱玻璃粉料C-glassbatch中碱废丝C-glassrecycledwastefiberb)无碱玻璃原料E-glassrawmaterials无碱玻璃球E-glassmarble无碱玻璃粉料E-glassbatch无碱废丝E-glassrecycledwasterfiber3.1中碱玻璃粉料C-glassRawmaterialsa)石英砂Quartzsand:SiO2b)钠长石Albite:AL2O3、Na2Oc)白云石Dolomite:CaOMgOd)石灰石Limestone:CaOe)莹石Fluorspar:CaF2f)纯碱Sodaash:Na2CO3g)硝酸钠Sodiumnitrate:NaNO3h)无水硫酸钠Anhydroussodiumsulfate:Na2SO4i)氧化铈Ceria:CeO23.2无碱玻璃粉料E-Glassrawmaterialsa)高岭土/叶腊石Clay/Pyrophyllite:AL2O3、SiO2b)硼钙石Colemanite:B2O3、CaOc)石灰石Limestone:CaOd)莹石Fluorspar:CaF2、SiO2、CaCO3e)石英砂Quartzsand:SiO2f)纯碱Sodaash:Na2CO3g)无水硫酸钠Anhydroussodiumsulfate:Na2SO43.3玻璃成分Glasscomposition3.3成分与作用Componentsandtheirfunctions氧化硅SiO2:物质基础、骨架Basisandmatrix氧化铝Al2O3:降析晶和膨胀系数,提高稳定性和强度toreducerecrystallizationandexpansioncoefficientandincreasestabilityandstrength氧化钙氧化镁:降低高温时粘度,促进熔化、澄清、提高拉丝速度CaO/MgO:Toreduceviscosityathightemperatureandpromotemelting,refiningandincreasewindingspeed.氧化硼B2O氧化铁Fe2O3碱金属;助熔,提高流动性Na2O/K2O;Toaidmeltingandincreasefluidity4、主要产品Mainproducts合股无捻粗纱直接无捻粗纱短切原丝无捻粗纱布缝编短切毡短切原丝毡缝编复合毡细纱4.1主要产品——合股无捻粗纱Mainproducts–Assembledrovinga)喷射SprayupRoving(SP)b)缠绕Filamentwindingroving(FW)c)拉挤Pultrusion(PL)d)SMCroving(RovingforSMC)e)HOBAS管道RovingforHOBASpipes(HS)f)膨体Texturedroving(BY)g)透明板材Panelroving(TS)h)热塑性增强Rovingforthermoplastics(RP)i)RovingforGMT(GMT)4.2主要产品——直接无捻粗纱Mainproducts-directrovinga)缠绕Filamentwindingroving(FW)b)拉挤Pultrusionroving(PL)c)织布Rovingforwovenroving(WR)4.3主要产品——短切原丝Mainproducts–Choppedstrandsa)团状模塑料Bulkmoldingcompound(BM)b)热塑性增强Thermoplasticreinforcement(TP)c)湿法短切Wetchop(WS)d)增强水泥Reinforcedcement(RC)4.4主要产品——布毡Mainproducts–fabric&mata)无捻粗纱布Wovenroving——EWRb)缝编短切毡Stitchedchoppedstrandmat——EMKc)短切原丝毡Choppedstrandmat——EMCd)缝编复合毡Stitchedcombomat——EMK(0,90)4.5主要产品——其它Mainproducts-Others细纱Continuousfilamentyarn一般指单纤维直径9微米以下的玻璃纤维纱,包括G75纱、D450纱、E225纱等,织成7628布、2116布、1080布等。主要用于电子行业,增强覆铜板基板,部份为工业用布。二、玻璃纤维行业的历史II.Historyoffiberglassindustry1.国际发展Internationaldevelopment2.国内发展Domesticdevelopment3.市场竞争Marketcompetition4.行业现状Industrycurrentstatus1、国际发展Internationaldevelopment2000多年前,古埃及手工拉制玻纤做装饰材料;Over2000yearsago,Egyptiansmanuallymadefiberglassasornamentmaterial20世纪30年代,美国发明了铂坩埚拉制工艺技术;Inthe1930s,Americansinventedthetechnologyofproducingfiberglasswithplatinumcrucibles1938年美国成立OWENSCORNING,具有工业性规模,用于绝缘材料;In1938OwensCorningCowasestablishedinUSAwhichhadaindustrialscaleoffiberglassproductionforinsulationapplication.二战后工业普及,成立了圣哥本(法)、皮尔金顿(英)、日东纺(日)等;AfterWorldWarII,theindustrialproductionoffiberglassbecamepopularandSt.Gobain(France),Pilkington(GreatBritain),Nittobo(Japan)startedtoproducefiberglass.1959~1960年,OWENSCORNING和PPG公司相继建成了玻璃纤维池窑。In1959and1960,OwensCorningandPPGbuiltfiberglassfurnaces.2、国内发展Domesticdevelopment20世纪50年代后期,我国玻璃纤维工业诞生,采用陶土坩埚法和镍铬合金孔板法生产;Inlate1950s,thefiberglassindustrystartedinChinaandthefiberglassthenwasproducedwithclaycruciblesandnickel-chromealloynozzleplates20世纪60年代中期,研制成功代铂坩埚法生产工艺;Inthemiddleof1960s,theplatinum-substitutecrucibleprocesswasinvented20世纪90年代初,池窑法开始在中国普及。Inthe1990s,thefiberglassfurnacesbecamepopularinChina3、市场竞争Marketcompetitors国际竞争对手——欧文斯.康宁(美)、PPG(美)、圣哥本(法)Internationalcompetitors–OwensCorning,PPG,St.Gobain国内竞争对手——巨石、泰山、重庆Domesticcompetitors:Jushi,Taishanfiberglass,CPIC4、行业现状Industrycurrentstatus奠基于上世纪30年代末,已成独立工业体系。Theindustryestablisheditselfin1930sandhasformedintoanindependentindustrysystem.目前有数千个品种与规格、5万多种用途,成为现代工业材料家族中重要的一员。Atpresenttherearethousandsofproducttypesandspecificationsandover50,000applicationsandfiberglasshasbecomeanimportantmemberinthemodernindustrialmaterialfamily.三、玻璃纤维有什么用处?III.Whatisfiberglassfor?1.交通运输Transportation2.建筑建材Construction3.电气工业Electrical4.机械工业Engineering5.石油化工Petroleum&chemical6.休闲文化Leisureandsports7.国防科技Defence四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?一、代铂炉生产工艺四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?二、波歇炉生产工艺四、玻璃纤维怎么做出来的?IV.Howisfiberglassproduced?配料Batch熔化Melting拉丝Fiberforming烘干Drying络纱Roving织布Weaving制毡Matproduction捻线Twisting短切Chopping三、单元窑生产工艺
本文标题:玻璃纤维概述――材料分类
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