轴手性化合物立体构型的便捷判断法

[]2010-01-20[](1978-),,,,,轴手性化合物立体构型的便捷判断法李刚(,455002)[],[];;[]G642[]A[]1671-5330(2010)02-0077-03,,,,,,[1,2],:;;,,;,,,R,S:11,3-(1)::,;C2(1),,a,bc,d;,ClH,abcd.d,a,b,c,R,C1(),,c,da,b;,ClH,cdab.b,c,d,a,R,,1,,,,,1:1,5--1,2,3,4-S7720102,2,6[3,3](2)2C1,C2,,C1(2),,a,bc,d,CH3H,abcd;d,a,b,c,S,(2),,c,da,b,CH3H,cdab.b,c,d,a,S3,4-(3),C1,C2,,C1(3),,a,bc,d;,CH3H,COOHH,abcd.d,a,b,c,R,C2(3),,c,da,bcdab.b,c,d,a,R2:2,R32,2--6,6-(4),,C1,C2,,C1,C2CBrCC;lC1(4),,a,bc,d,CBrCC,labcd.d,a,b,c,S,(4),,cdab.b,c,d,a,S43:4,R7820104,BINOL(5),C1,C2,,C1,C2COCCC2(5),,a,bc,d,COCCabcd.d,a,b,c,S,C1(5),cdab.b,c,d,a,S54:,BINAPS,,,,,,,[][1]R.[M].,.:,2006.45-48.[2],,.[J].,2007,(22):52.[3].[J].(),2000,(6):88.AConvenientMethodtoJudgeConfigurationofChiralAxisCompoundsLIGang(CollegeofChemistryandChemicalEngineering,AnyangNormalUniversity,Anyang455002,China)Abstract:Basedonseveralyears,experienceofteachingandstudyofconfigurationofchiralaxiscompounds,weadvanceaconvenientmethodtojudgeconfigurationofchiralaxiscompounds,whichteachersexpedientlyteachandstudentseasilylearn.Keywords:ChiralAxisCompounds;Configuration;MethodtoJudge[:D]792: