苯乙烯生产技术及国内外市场前景_崔小明

专论综述,2005-06-25,15(3):53~59CHINAELASTOMERICS:2004-11-24:(1966-),,,,,,E-mail:[e-mail]崔小明,李明(,102500):介绍了苯乙烯的生产方法,分析了国内外苯乙烯的供需情况,提出了发展我国苯乙烯生产的建议:苯乙烯;生产;消费;市场分析:TQ241.2:A:1005-3174(2005)03-0053-07(SM),(PS)--(ABS)-(SAN)(SBR)(SBR)(SBS),,1,-1.1[1,2],90%1.1.1,DowFina/BadgerABBLummus/UOPBASF1.1.1.1ABBLummus/UOP800,:550~650;;(1.01)~(1.51)/,,40,670t/a1.1.1.2Fina/BadgerFina/Badger/Badger,800~950,,560~650,,(1.51)~(2.21),Fina/Badger,;30,ABBLummus1.1.1.3BASFBASF,,,,750,630,,585,,,(H2CH4CO2),,,Styromax-1Styromax-2Styromax-4Styromax-5;C-025HAC-035C-045;BASFS6-20S6-20SS6-28S6-30;DowD-0239E2060315335345355;XHDCGS,----1.1.2,,,(Styro-Plus)(styrenemonomeradvancedreactortechnology,Smart)1.1.2.1Styro-PlusUOP2080,,,,Sty-ro-Plus,34%,1.1.2.2Smart2090,UOP(Styro-Plus)LummusMonsantoUOPLummus/UOP,,,,,SmartLummus/UOP,,:,,,,,,,620~6450.03~0.13MPa(11)~(21),85%,92%~96%:(a),,,,80%;(b),,,;(c),;(d),,,,,;(e),5415,5,1.2-[3]-(PO/SM),Halcon,1973130~1600.3~0.5MPa,,17%,1104.05MPa,,2602.51,,10%LyondellShellRepsolPO/SM,,,,25%,50%,,,,,,,1.3[4]GTCGT-,(NGL)99.9%(),510-5,,,,30.0t/a1.5t/a1.4Dow(DSM),Dow-,1.8MPa100,,90%,4-(4-VCH)100%/,1,,0.6MPa400,VCH90%,90%,DSM,800.5MPa,95%,4-100%4-,3000.1MPa,4-,96%,1.5,22.1ABS,1999553,.2169.8t,20012359.8t,20022388.3t,20032463.1t,2300.0t,/742.7t/a,30.2%;640.1t/a,26.0%;119.5t/a,4.9%;960.8t,39.0%,,20063000t/a[5]2003112003/(ta-1)BP45.4-86.3Cos-Mar90.868.1Lyondell127.1Nova59.9Sterling77.2Westlake18.2Nova43.045.0Pemex15.0Innova25.050.0ElfAtochem72.055.0BP35.0BSLOlefinverbund28.060.056.5DowBenelux100.044.0RepsolQuimica50.06.0Dwory10.0Kaucuk17.046.027.0DenkiKagakuKogyo24.0IdemitsuKosan55.037.129.4/(ta-1)NihonOxirane38.419.023.2LG49.567.030.016.0YNCCSinobnet14.016.020.013.0TSMC118.0Ellba55.0Seraya32.020.0StyrindoMono34.020.026.0SaudiPetrochem45.0TabrizPetrochem10.02.220002099.2t,2001,,1.8%,2060.9t,20026.3%,2191.0t200320023.4%,2265.9t,/600.1t,26.5%;564.2t,24.9%;37.4t,1.7%;1064.2t,47.0%2006,2536.8t,,20021028.2t20061218.7t,4.3%ABS/SANSBR/SBR,2003:54%12%16%ABS/SAN9%SBR56155%,4%2[6]2/t2000200120022003200420052006/582.4540.2569.6600.1620.1635.7654.1561.2530.3556.3564.2583.1605.2623.734.835.136.837.438.339.440.3920.8955.31028.21064.21109.11160.61218.72099.22060.92190.92265.92350.62440.92536.833.12050,,5000t/a,200312,105t,8,72.9t/a,69.4%14.5t/a,13.8%;,14.0t,13.3%20033[7]32003/t/14.0Lummus/UOP+199814.5Lummus/UOP199710.0Lummus/UOP19968.0Fina/Badger19968.4Lummus/Monsanto19886.0Fina/Badger19966.0Lummus/Monsanto19886.0Fina/Badger199510.019996.019606.0199594.9,199525.58t,199856.30t,200076.38t,1995~200024.5%200289.56t,200113.8%,1997~200218.5%200394.82t,20025.87%,45.20t,47.67%;37.89t,39.96%,15.98t,16.85%,;,12.34t,13.01%;,10.40t,10.97%44/t20012002200310.6212.8415.9811.8211.8812.3410.4610.1710.408.129.507.344.978.878.106.896.957.836.776.527.026.466.772.722.465.056.364.925.165.031.571.862.6975.0685.5785.81573,.3.2ABS,199554.83t,2000191.42t,1995~200028.4%;2001200t,240.38t,2002269.19t,200112.0%,1997~200228.7%2003300t,360.27t,200233.83%5[7,8]5199519961997199819992000200120022003/t25.5826.0438.2556.3074.7676.3878.7089.5694.82/t30.5839.0944.0058.34102.69115.75160.79179.85266.06/t1.330.650.230.150.220.660.310.220.61/t54.8365.8076.3392.36177.23191.42240.38269.19360.27ABSAS2003:54.1%;16.4%ABS/SAN;3.1%/;6.9%;2.8%;16.7%66200220032005/t/%/t/%/t/%175.065.0195.054.1210.050.5ABS/SAN34.012.659.016.481.019.5/9.63.611.33.113.03.118.16.725.06.931.57.69.03.310.02.811.52.823.58.860.016.769.016.5269.2100.0360.3100.0416.0100.04(1),2463.1t/a,2265.9t/a,20063000t,2536.8t,,(2),105.0t/a,200394.82t,360.3t,266.06t,73.8%,ABSSBRSBS2005,416.0t,170.0t,,,(3),,,,,14.5t/a,,,,,,;,,,20.0t/a,,,5815,,30.0t/a,(4),,,/,,,CO2-,(5),,,,,,,:[1].[J].,2001,20(3):47~50.[2].[J].,2002,9(5):32~36.[3],,.[J].,2001,20(3):8~12.[4],.[J].,2004,(4):44~46.[5]Anno.Styrene[J].EuropearChemicalNews,2004,80(2096):13.[6].[J].,2003,(24):7~10.[7].[J].,2003,(33):6.[8],.[J].,2004,(8):A6~A7.ProductiontechnologyandmarketprospectofstyreneathomeandabroadCUIXiao-ming,LIMing(ResearchInstituteofBeijingYanshanPetrochemicalCo.Ltd.,SINOPEC,Beijing102500,China)Abstract:Theproductionmethodsofstyreneareintroduced.Thesupplyanddemandofstyreneathomeandabroadareanalysed.SuggestionsforthedevelopmentofstyreneinChinaareputforward.Keywords:styrene;production;consumption;marketanalysis,20031.212005(1.4~1.5)1,2010(1.6~1.8)1,,,200520%,201025%(关应)593,.