科莱恩阻燃剂介绍

24.11.2006PublicDevelopmentFlameRetardantsATPGDr.S.HöroldPhosphinates,theFlameRetardantsforPolymersinElectronicsSlide2PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionFRPolymersintheE&EIndustry–Demandingrequirements„Materialproperties(selection)–smallparts,thinwall,lowdensity–SurfaceMountTechnology–leadfreesoldering–lasermarkability/weldability–glowwiretest„Lifecycleconsiderations–Reprocessingofproductionwaste–Recyclingofusedmaterials–Endoflife–environmentalproperties–TotalcostsSlide3PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionPhosphinateFlameRetardants„PropertiesofPhosphinates„HightemperaturePolyamides–Leadfreesoldering„Polyamide6and66–Glowwiretest–Electricalproperties–RecyclingStudy„Polyester(PBT)„Epoxyresins„ConclusionSlide4PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionClariant‘sNewPhosphinatePlantSlide5PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionPhosphinates,anewclassofFRSystems„Registrationiscompletedincompliancewith–ELINCSinventory(Europe)–TSCA(USA)–IECSC(China)–ENCS(Japan)–DSL(Canada)–ECL(Korea)–HNSO(NewZealand)–AICS(Australia)Slide6PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionPhosphinatesasFlameRetardants„Thermallystableupto350°C„Mineral-likecharacteristicsofmetalphosphinateFRsystem„decomposestosolidphosphates„nomigrationandblooming„virtuallynoemissionsPR1R2OOn_Mn+Slide7PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionToxicologicFindingsforthePhosphinate„Sensitizationnon-sensitizing(Gunieapig)„Mutagenity–Ames-Testnotmutagenic–Genotoxicityinvivonoexperimentalindications„Toxicity–DaphniaEC50100mg/l(48h,daphniamagna)–FishLC50100mg/l(96h,zebrafish)–BacteriaEC50=1968mg/l(3h,activatedsludge)–AlgaeNOEC180mg/l(scendenemussubspicatus)Slide8PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionPolyestersPhosphinateBasedFlameRetardants–AgrowingnumberofapplicationsOthersPolyamidesPrintedWiringBoardsPR1R2OOn_Mn+Slide9PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionFRPolyamideswithPhosphinates„Coloribility„CTI600V„goodmechanicalproperties„lowdensityofcompounds„goodflowproperties„hightemperaturestability„LasermarkingandlaserweldingpossibleSlide10PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionPA-HTRecipesforComparison„CompoundingonLeistritzZSE27HP–44D„PA6T/66„30%Glassfibres„Withoutflameretardants„WithBr-PS/ATO/PTFEUL94V-0„WithExolitOP1230UL94V-0Slide11PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-ConclusionMechanicalPropertiesinPA-HT™Tensile(dryasmoulded)E-Modulus[MPa]Tensilestrength[N/mm²]Elongationatbreak[%]WithoutFRExolitOP1230Br-PS1150010500125002001501402,52,01,5Slide12PublicDevelopmentFlameRetardantsATPG24.11.2006Phosphinates,theFlameRetardantsforPolymersinElectronicsDr.S.Hörold-PropertiesofPhosphinates-HTPolyamidesLeadfreesoldering-Polyamide6and66GlowwiretestElectricalpropertiesRecyclingStudy-Polyester(PBT)-Epoxyresins-Conclusion™Impact(dryasmoulded)Impactstre