新型分子筛催化剂的研究进展

:1002-1124(2006)02-0027-03(,116000):,:;;:TQ424.25:AAdvancesinmolecularsievecatalystsWANGHui-zhi(DalianBohaiLaboratory,Dalian116000,China)Abstract:Advancesincharactere,synthesistechnology,application,theoreticalresearchanddevelopmentdirec2tionofmolecularsievecatalystsmaterialwerereviewedinthispaper,andtheirprospectofapplicationwerediscussed.Keywords:molecularsieve;catalystsmaterial;application2090,,,[1]1,,SiO2Al2O3,:MXOAlO3YSiO2ZH2O(M:KNaCaMg)1930PanlingSiO4:2006-01-05:(1973-),,,1996AlO4O/(Al+Si)=2()[2](X),(A),(XY),(ZSM-5)(Silicalite)X1883Eichhorn[3]1925WeigelSteinheff,H2O,1945Barrer,X,,195419571959AXY[2],,1[J]1,1994,8(1):82-871[3]HansJGriesseretal1Polymerinternational,1992,27:10921[4]ZhangMC,KangET,Neohkg,etal1Adhesionenhancementofthernallyevaporatedaluminumtosurfaceggraftcopolymerizedpoly(tetrafluoroethylene)film[J]1JournalAdhesionScienceTechnology,1999,13(7):819-8351[5],1[J]1,1990,(5):5701[6]ChenXD,SunRH,HUYJ,etal1[J]1JRadiatResRadiatProces,1998,16(4):209-2121[7],,1CH4/O2[J]1,2000,18(1):25-291[8],,1PTFE[J]1,2004,23(1):59-611[9],,1[J]1,2004,38(2):190-1941[10]c1z1liu,etal1[J]1MaterialsChemistryandPhysics,2004,85:340-3461Sum125No12ChemicalEngineer20062©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[4]6070,Mobil,betaZSM,20100,ZSM-5,1977Flanigen,Silicalite1978Fluocilde-Silicalite,1979BibbyNH4OHZSM-11Sil2icalite-210,,1982UCC()WilsonFlani2gen20AlPO4SAPO4,,FeCrTi,Flanigen,TiO41983(Cacoxenite),(1420!)Fe-OAl-OP-O[5]1986PO4-Cn(n=112)TiO4BO390,,[5],:(1);(2)H2OH2SNH3,;(3),;(4)(),;(5),,,,,,2,2.14(),,,(100300),,Al(OH)3,,,,,2.2,500600,NaOH,AXY,,,,(34d),,[6]2.32.3.1Ti-HMS,,MCM-41HMSMSU,,,,,,M41S,HMS:(1);(2),,[7]2.3.2,MCM-41Beck82:20062©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:,2.4nm,-,66nm[8]2.3.3,2080,,,,,,,,,,1993ArafatYZSM-5,,X,AAlPO4ANAGISSAPO-5SilicaliteMCM-41MCM-48[9]2.3.4ZnCl2ZnCl2HMSZnCl2MCM-41XRDHMSMCM-41,FT-IR,ZnCl2,ZnCl2,,,ZnCl2,,,[10]3,200900m2g-1,50%,,,1945Barrer,,[11]199440,,60,,AXY,,4,,,,,[1].[J].,1996,(1):471[2]1.[M].:,19901[3],.[M].:,19801[4].[M].:,19801[5],.[M].:,19871[6]J.Acobe.Molecularsievesprinciplesofsynthesisandidentification,AIME,NewYork,19921[7],.Ti-HMS[J].,2002(5)1[8],.[J].(),2002,(6)1[9],.[J].,2002,(6)1[10].ZnCl2[J].,2003,26(1)1[11],.[M].:,198319220062:©1994-2006ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.