硫酸钙晶须在涂料中的应用综述

———————————————————2013－08－210、。、。1、、3。、、、、、[1]。1。、、、、、、、、、pH、。、、、、。22.12。、、、448000。TQ630.4B1007-9548201311-0018-02ReviewoftheApplicationofCalciumSulfateWhiskerinCoatingsHUANGMing-jie,ZHANGXiao-ying,SHEJing-li(LeixinGypsumProductCo.,Ltd.,JingmenHubei448000,China)Abstract:Applicationofcalciumsulfatewhiskerincoatingsisjuststarted.Calciumsulfatewhiskeranditspreparationprincipleanditsapplicationstatusincoatingsweremainlyintroduced.Keywords:calciumsulfatewhisker;coatings;applicationstatus1CaSO4/g·cm-30.1~0.4/μm1.0~4.01.585/℃1450/℃1000/GPa/GPa22℃/×10-620.5178.0＜120024~263~4≥301611201311MPFMPFReview18、5[2]。2.2[3-4]。。2%。。33．1、、、、。[5]。[6]75℃、3.5h、NCO6.0%~7.5%、0.5%5%25%30%。20%7.2MPa500%。3.2、、。1970、、。800~1200℃10min700℃。“911”。8~50mm、3~7mm3mm0.5~2.5h[7]。、、、、、、、、。。1450℃1800℃2h0.75%、。3.3VOC、、、、。[8-9]。、[10]。[11]350℃0、。3.4[12]60.5%42.5%。0.5%~2.5%、。3.5[13]2%~3%98%90℃98%85℃99.9%0.3℃/min1~3cm。4、、、、、、、、、26ReviewMPF1611201311MPF1919。[1].CaSO4[J].2005142:38-41.[2].[J].200941812-14.[3].[J].2004185:498-501.[4].[J].19981:10-13.[5].[J]．2002520-23．[6].[J].2009238-41.[7].[J].19983:22-23.[8].[J].20114111:48-52.[9].[J].2008363:78-82.[10].[J].2007225:54-56.[11].[J].20124:289-293.[12].[J].201212:63-66.[13].:CN200510047776X[P].2006-07-26.◆[13].[J].20062251-4.[14]MaZL,ZhaoWG,LiuYF,etal.Intumescentpolyurethanecoatingswithreducedflammabilitybasedonspirocyclicphosphate-containingpolyols[J].JournalofAppliedPolymerScience,1997,66(3):471-475.[15]El-wahabHA,El-fattahMA,El-khalinNA,etal.Syn－thesisandperformanceofflameretardantadditivesbasedoncyclodiphosph(V)azaneofsulfaguanidine,1,3-di-[N/-2-pyrimidinylsulfanilamide]-2,2,2.4,4,4-hexachlorocy－clodiphosph(V)azaneand1,3-di-[N/-2-pyrimidinylsulfanil－amide]-2,4-di[aminoaceticacid]-2,4-dichlorocy－clodiphosph(V)azaneincorporatedintopolyurethanevarnish[J].ProgressinOrganicCoatings,2012,74(3):615-621.[16].-[D].2009.[17].[D].2011.[18].CN1322786A[P].2001-11-21.[19].-CN101608060A[P].2009-12-23.[20].CN102559022A[P].2012-07-11.[21]P.CN102405245[P].2012-04-04.[22].CN102675860A[P].2012-09-19.[23]Tony,ChizenShawn.Flameretardantcoatingusefulase.g.flooring,fireprotectionandrockreinforcingcoating,com－prisespolyureaelastomer,sprayprocessablegraphite,graphitestabilizeragent,andflameretardant:WO2010034109[P].2010-04-01.[24]D.CN102239205A[P].2011-11-09.[25]ShartelB,BeckU,BahrH,etal.Sub-micrometrecoatingsasaninfraredmirror:anewroutetoflameretardancy[J].FireandMaterials,2012,36(8):671-677.[26]SchartelB,KuhnG,MixR,etal.Surfacecontrolledfirere－tardancyofpolymersusingplasmapolymerisation[J].Macro－molecularMaterialsandEngineering,2002,287(9):579-582.[27]LauferG,KirklandC,MorganAB,etal.Intumescentmulti－layernanocoating,madewithrenewablepolyelectrolytes,forflame-retardantcotton[J].Biomacromolecules,2012,13(9):2843-2848.[28]LuSY,HamertonI.Recentdevelopmentsinthechemistryofhalogen-freeflameretardantpolymers[J].ProgressinPolymerScience,2002,27(8):1661-1712.[29]GhoshSK.Functionalcoatingsbypolymermicroencapsula－tion[M].Weinheim:WileyBlackwell,2006:1-28.[30].[J].20111227163-166.[31].[J].201242731-34.◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆◆1611201311MPFMPFReview26