二氧化钛纳米管的制备-改性及应用-王俏

2015345CHEMICALINDUSTRYANDENGINEERINGPROGRESS1311150090TB383A10006613201505131107DOI10.16085/j.issn.1000-6613.2015.05.022PreparationmodificationandapplicationoftitaniumdioxidenanotubesWANGQiaoWANGWeiCUIFuyiSHAOPenghuiHEJiaojieSchoolofMunicipalandEnvironmentalEngineeringHarbinInstituteofTechnologyHarbin150090HeilongjiangChinaAbstractTitaniumdioxidenanotubeshavebeenintensivelyconcernedandstudiedinrecentyearsduetotheirspecialmorphologyandhighlyorderedproperty.Thispaperreviewedrecentadvancesintitaniumdioxidenanotubes.Threekindsofpreparationmethodswerediscussedincludingtemplatesynthesiselectrochemicalanodizationandhydrothermalsynthesis.Onthisbasisitdescribedthemodificationmethodsoftitaniumdioxidenanotubesindetailincludingdopingandcompositing.Theapplicationsoftitaniumdioxidenanotubesandcompositesinthefieldofenvironmentandenergywereintroducedbriefly.Finallythefuturestudiesontheformationmechanismmorphologycontrolandmodificationoftitaniumdioxidenanotubeswereproposed.Keywordspowdertechnology;nanomaterials;preparation;modification;compositesTiO2[1–2][3]TiO2TiO2[4]TiO2TiO2TiO2TiO2[5][e-mail]2015341312TiO21TiO2TiO23[46]1.1TiO21AAO[7][6]-TiO2Hoyer[7]400mVTiO2AAOTiO22TiO2Jung[8]-30--10500nm89nmTiO2[6]1.2HFTiO2[9]Gong[10]0.5%3.5%HF2565nm[11]TiO2[12]TiO2TiO24;TiO2[13]TiO2[14][15-16]Schmuki[16]120V40VTiO2TiO2TiO21.3TiO2TiO2[17][6]Kasuga[18]TiO211020hTiO2TiONa[19]TiO2[4][20]TiO2TiO2[11][21]AAO140TiO21.43TiO231[22]513132TiO2TiO2TiO2[23-24][5]2.1TiO2TiO2[5]2.1.1TiO2TiO2-xAxATiO2TiO2TiO2[25]2001Asahi[26]TiO2TiO2TiO2TiO2TiO2TiO22.1.2TiO2TiO2[5][27]TiO2TiO2Schmuki[28]TiO2TiO21TiO2[22]10500nm100nm100μm10500nm220nm2015341314TiO2TiO22.1.31Shi[29]TiO2TiO2Su[30]1/12mol/L+1.0%+0.5%20VTiO2TiO22TiO2-TiO2TiO2[31][32]TiO2[33]TiO2TiO22.2TiO2[5]2.2.1TiO2TiO2TiO2TiO2TiO2SchottkySchottkyTiO2Schottky[34][35]TiO2TiO2TiO2[36]TiO2-TiO2[5]TiO2NTiO2Schmuki[36]TiO2Ti4+Ti3+2.2.21.53VTiO2[5][37]/TiO2TiO240.74%PNTiO2PN[5]TiO2TiO20.01mol/L500W1.82%2.2.3TiO2CdSPbS51315CdSeWO3ZnO[38]TiO2Grimes[39]TiO2CdSTiO22.53eVCdSTiO2TiO2TiO23TiO23.13.1.1TiO2TiO2TiO2TiO2Xie[40]TiO2ABPATiO2BPA80.1%TiO251.1%TiO2TiO2Schmuki[41]TiO23.1.2TiO2TiO2[42]TiO2[5]Grimes[43]TiO20.05L/LTiO2[44][44]TiO23.23.2.1Fujishima[45]TiO2TiO2TiO2[46]Mor[47]224nmTiO2960μmol/(h·W)6.8%TiO2TiO23.2.2TiO2TiO2TiO2TiO21991Gratzel[48]TiO27%TiO2TiO2Zhang[49]0.45%Paulose[50]220μmTiO26.89%6μmTiO262%4TiO2TiO2[22]20153413161TiO2TiO2TiO22TiO2TiO2TiO23TiO2TiO2TiO2TiO2[1]YoonJJungSKimJ.PhotocatalyticeffectsfortheTiO2-coatedphosphormaterials[J].MaterialsChemistryandPhysics20111253342-346.[2].[D].2012.[3]LiXFZhaoYJiaoQZetal.Preparationofone-dimensionaltitanatenanomaterialsusingdifferenttitaniasources[J].ActaPhysico-ChimicaSinica20112781996-2000.[4].TiO2[J].200524142-46.[5].[J].2012285861-872.[6].[J].200718-13.[7]HoyerP.Formationofatitaniumdioxidenanotubearray[J].Langmuir1996121411-1413.[8]JungJHKobayashiHvanBommelKJCetal.Creationofnovelhelicalribbonanddouble-layerednanotubeTiO2structuresusinganorganogeltemplate[J].ChemistryMaterials2002141445-1447.[9].[J].20112751017-1025.[10]GongDGrimesCAVargheseOKetal.Titaniumoxidenanotubearrayspreparedbyanodicoxidation[J].JournalofMaterialsResearch200116123331-3334.[11].TiO2[J].20113092003-2012.[12].[J].201142113270-3276[13].TiO2[J].20123292176-2181.[14]MacakJMTsuchiyaHGhicovAetal.TiO2nanotubesSelf-organizedelectrochemicalformationpropertiesandapplications[J].CurrentOpinioninSoildStateandMaterialsScience2007113-18.[15].TiO2[J].200820121868-1879.[16]AlbuSPKimDSchmukiP.GrowthofalignedTiO2bamboo-typenanotubesandhighlyorderednanolace[J].AngewandteChemieInternationalEdition2008120101942-1945.[17]ZhangXWPanJHDuAJetal.Combinationofone-dimensionalTiO2nanowirephotocatalyticoxidationwithmicrofiltrationforwatertreatment[J].WaterResearch2009431179-1186.[18]KasugaTHiramatsuMHosonAetal.Formationoftitaniumoxidenanotube[J].Langmuir199814123160-3163.[19].[J].2005342287-290.[20].-[J].201341183-88.[21].TiO2[J].200930137-42.[22]LeeKMazareASchmukiP.One-dimensionaltitaniumdioxidenanomaterialsNanotubes[J].ChemicalReviews20141149385-9454.[23]ShenYQWangDPYeS.SynthesisandcharacterizationofTiO2nanotubearrayswithAgnanoparticles[J].JournaoftheChineseCeramicSociety2014423402-408.[24]WangWLuCNiYetal.Preparationandcharacterizationofvisible-light-drivenN-F-Tatri-dopedTiO2photocatalysts[J].AppliedSurfaceScience2012258228696-8703.[25].[J].20102971235-1240.[26]AsahiRMonkawaTOhwakiTetal.Visible-lightphotocatalysisinnitrogen-dopedtitaniumoxides[J].Science20012935528269-271.[27].CuTiO2[J].2010265875-878.[28]MacakJMTsuchiyaHSchmukiPetal.TiO2nanotubesSelf-organizedelectrochemicalformationpropertiesandapplications[J].SolidStateandMaterials2007113-18.[29]ShiJianLiJunCaiYunfa.FabricationofC,N-codopedTiO2nanotubephotocatalystswithvisiblelightresponse[J].ActaPhysico-ChimicaSinica20082471283-1286.[30]SuYalingZhangXingwangZhouMinghuaetal.PreparationofhighefficientphotoelectrodeofN-F-codopedTiO2nanotubes[J].JournalofPhotochemistryandPhotobiologyAChemistry2008194152-160.[31]LiXCh