二氧化钛纳米管阵列的制备-性能及传感应用研究-杨丽霞

2009年第54卷第23期:3605~3611:3605~3611YangLX,LuoSL,CaiQY,etal.AreviewonTiO2nanotubearrays:Fabrication,properties,andsensingapplications.ChineseSciBull,doi:10.1007/s11434-009-0712-3:,,*,,410082;,410082*,E-mail:[e-mail]2009-03-02,2009-10-16(:2009CB421601)(:08JJ3113)(:521218019)F−(TiO2).,,pH.,.,.,[1~3].,.[4~6].,,..,.,,,.,,.,.,[7][8]-[9][4].,.,[4].,1000µm[10].1.12001Mor[4]2009年12月第54卷第23期3606.,,,5~25V,p5.,HNO3,H3BO3,H3PO4,H2SO4HSO4−,.15~140nm,200~1000nm[4,11~13].1[14]::(1),;(2)TiF62−,,(1(c));(3),..,F−.Grimes[4],F−0.05~0.3mol/L,.F−,.1,.(pH1),,,,500nm[4].pH,;,:pH4.54.4µm[4].,,[14].pH;pH,,,.,,[4].(ethyleneglycol,EG)[10],(formamide,FA)[15],N-(N-methylformamide,NMF)[15],(dimethylsulfoxide,DMSO)[16][17],1%~5%0.25%~0.6%NH4F.(FA),35V,48h70µm,180nm,24nm;0.25%NH4FEG60V,17h134µm,160nm,25nm[15].,(EG),15µm/h[18].0.3%NH4F2%H2OEG,70h,20,40,50,6065V,5,30,45,165106µm;21,4896h188,289360µm.,(1000µm)0.6%NH4F3.5%H2OEG60V1.0mm216h[10].1.2:(1)(3.2eV,3.4eV),,5%;(2),,.,,,,.,C,N,B[19~22]TiO23607,.,[20].N-TiO2,NTiO2,N(2p)TiO2,N(2p)O(2p),TiO2,[20].CdS,CdSe,Fe2O3TiO2[23~25]..Pt,Au,PdTiO2.20nmPt-AuTiO2,PtAu/TiO2[26],.TiO2PtAu,,,.TiO2,[27].C/TiO2,,TiO2.,C/TiO2.22.1,.,ppm~ppb,[28][29][30][31]..,.(),,.[32].[3].2(a):0.1mm(10mm×2mm)[33],.,300,76nm3(2(b))[34~36].,,,22nm76nm200.6.5µm,22~110nm,9~34nm[4].,30nm1000ppm8.7[36].2(a),1000ppm(b)[34]2009年12月第54卷第23期3608..TiO2,,.,,,[34].,,,,,:500ppm0.049V,0ppm2.046V[35].,(:),,.,[37].(22nm,13.5nm,400nm)10nm.24,1000ppm,1750.,.,TiO2,Pd,[37].PdPtPdPt.,PdPt[38].2.2[39][40].3300,400,500600,,600,95%11%100s,190s[39].,50,100,150,200,250300,3[39](a),(b)600,TiO2,SrTiO3Ga2O3[40].100,200ppm,,.2.3,,.PtAu,20nmPtAu(4(a),(b)).[41],0~1.8mmol/L,0.08366(µA·L)/(mmol·cm2),3s,4(c)..Pt36094(a)AuPtSEM;(b)AuPt-TEM;(c)GOx/Pt–Au/TiO2:1,0mmol/L;2,0.2mmol/L,3,0.4mmol/L(10mmol/LPBS(pH7.3)+0.1mol/LNaCl(−0.2Vvs.Ag/AgCl(3mol/LKCl));0.1~0.8mmol/L[42].,3nmPt/,.0.006∼1.5mmol/L,0.24(µA·L)/(mmol·cm2),5.7µmol/L[42].Xie[43],,.,2.0×10−4mmol/L.−0.4V(vs.SCE),pH6.845.5µA·L·mmol−1·cm−2,5.6s,2.0×10−3mmol/L.,(HRP).HRP[44,45].−0.7~0.0V,,.HRP,..,HRPH2O2.,HRP,.−600mV(vs.Ag/AgCl),pH6.7H2O210−5∼3×10−3mol/L[45].HRPAuH2O2[46].,H2O25×10−6∼4×10−4mol/L,32×10−6mol/L.,,.3,.5~25V,pH5F−15~140nm,200nm~1µm.2009年12月第54卷第23期3610pH4.5,KFNaHSO44.4µm.,(5%).(,N-,,),1~5%H2O0.1~0.6%NH4F.20~60V,50~150nm,5~1000µm.C,N,B.CdS,CsSeFe2O3,Pt,Au,Pd,TiO2,,..(300),.600.,.,..1GrimesCA,MorGK.TiO2NTArraysSynthesis,Properties,andApplications.Norwell,MA:Springer,20092JiangHD,KimSK,KimSJ.Effectofparticlesizeandphasecompositionoftitaniumdioxidenanopaticlesonthephotocatalyticproperties.JNanopartRes,2001,3:141—1473VargheseOK,YangXP,KendigJ,etal.Atranscutaneoushydrogensensor:Fromdesigntoapplication.SenseLett,2006,4:120—1284MorGK,VargheseOK,PauloseM,etal.Areviewonhighlyordered,verticallyorientedTiO2nanotubearrays:Fabrication,materialproperties,andsolarenergyapplications.SolEnergyMaterSolCells,2006,90:2011—20755OuHH,LoSL.Reviewoftitaniananotubessynthesizedviathehydrothermaltreatment:Fabrication,modification,andapplication.SepPurifTechnol,2007,58:179—1916SunL,LiJ,ZhuangHF,etal.Progressonfabrication,modificationandapplicationsoftitaniananotubeArrays.ChinJInorgchem,2007,23:1841—18507ChopraNG,LuykenRJ,CherreyK.etal.Boronnitridenanotubes.Science,1995,269:966—9678TenneR,MargulisL,GenutM,etal.Polyhedralandcylindricalstructuresoftungstendisulphide.Nature,1992,360:444—4469FujikawaS,TakakiR,KunitakeT.NanocopyingofindividualDNAstrandsandformationofthecorrespondingsurfacepatternofti-taniananotube.Langmuir,2005,21:8899—890410PauloseM,PrakasamHE,VargheseOK,etal.TiO2nanotubearraysof1000µmLengthbyanodizationoftitaniumfoil:phenolreddiffusion.JPhysChemC2007,111:14992—1499711GhicovA,TsuchiyaH,MacakJM,etal.Titaniumoxidenanotubespreparedinphosphateelectrolytes.ElectrochemCommun,2007,7:505—50912YangLX,CaiQY,YuY.Size-controllablefabricationofnoblemetalnanonetsusingaTiO2template.InorgChem,2006,45:9616—961813BauerS,KleberS,SchmukiP.TiO2nanotubes:TailoringthegeometryinH3PO4/HFelectrolytes.ElectrochemCommun,2006,8:1321—132514CaiQY,YangLX,YuY.Investigationsontheself-organizedgrowthofTiO2nanotubearraysbyanodicoxidization.ThinSolidFilm,2006,515:1802—180615PauloseM,ShankarK,YoriyaS,etal.Anodicgrowthofhighly-orderedTiO2nanotubearraysto134µminlength.JPhysChemB2006,110:16179—1618416SorachonY,MaggieP,VargheseOK,etal.FabricationofverticallyorientedTiO2nanotubearraysusingdimethylsulfoxideelectro-lytes.JPhysChemC,2007,111:13770—1377617TsuchiyaH,MacakJM,TaveiraL,etal.Self-organizedTiO2nanotubespreparedinammoniumfluoridecontainingaceticacidelec-trolytes.ElectrochemCommun,2005,7:576—58018PrakasamHE,ShankarK,PauloseM,etal.AnewbenchmarkforTiO2nanotubearraygrowthbyanodization.JPhysChemC,2007,111:7235—7241361119ParkJH,KimS,BardA.Novelcarbon-dopedTiO2nanotubearrayswithhighaspectratiosforefficientsolarwatersplitting.NanoLett,2006,6:24—2820VitielloRP,MacakJM,GhicovA.N-dopingofanodicTiO2nanotubesusingheattreatmentinammonia.ElectrochemCommun,2006,8:544—54821GhicovA,MacakJM,Tsuch