纺织品涂层整理剂的生态问题和解决方法(1)

200025.,(、、),.,:(1)(、、、--、、);(2)(、、、);(3)(、、、);(4),().;;;:TQ610.4+99:A:1004－0439(2009)03－0001－05TheecologyproblemsofcoatingagentoftextilesanditsresolutionZHANGXiao-qin,ZHANGJieShanghaiDyestuffsCo.,Ltd.,Shanghai200025,ChinaAbstract：Textilecoatingisanimportantfinishtechnology.Theecologydemandsofcoatingagentwasstatedandtheecologyproblemsofcoatingagent(polyacrylate,polyurethaneandpolyvinylchloride)wereanalyzed,andtheresolutionandtheirsubstituteswerepointedout.Atthesametime,theecologyproblemsofadditivesinthecoatingagentsanditsresolutionwereintroduced.Thesubstituteswerepointedout,respectively:(1)flamere－tardant(swellingtypeofbicycliccagetypephosphatederivative,organicboricbase,novelsiliconbase,boric-ni－trogensynergisticflameretardantsystem,andboric-siliconsynergisticflameretardantsystem,complexofor－ganiccompoundandinorganicnitrogensalt,andnitrogenderivativeofalkylphosphoricacid);(2)waterproofinga－gent(modifiedsiliconepolyemulsion,acrylicfluorocarbonesterresin,fluorostain-removingagentwithhydrophilicchain,weakcationicfluoridedispersion);(3)bactericide(inorganiccompound,quaternaryammoniumsalt,carbami－dine,naturalcompound;(4)crosslinkingagentmustbethosewhichwouldnotcontainorreleaseformaldehyde,orlowformaldehydecrosslinkingagenttoaccordwiththestandardcouldbeused.Keywords：textiles;coatingagent;ecologyproblem;resolution2008-11-10(1942-),,,,,、、.,,,,,,.,,,Eco-LabelOeko-TexStandard100,,、,.,、TEXTILEAUXILIARIESVol．26No．3Mar．20092632009326.,,、、、、、、、、[1],.,,30%,50%,,.1,8[1]:(1),;(2),、、、、、、、;(3);(4);(5);(6)24()2430mg/kg(Oeko-TexStan－dard10020mg/kg);(7);(8),、、、、、.84:(1);(2);(3);(4),.2,2,,.,(PA)(PU).,、、、,、、,,.、、,,、,、、,,.,、、、、,.2.1,、N,N-(DMF)、(MEK)、(TOL)、(IPA),.,PBA,,,;WP-01,、,.,.,,,,.,:(1),、、,;(2),、、,,,、,,,,,、、、、、、.,,[2];(3)100%,(),,,,,,,.,,:(a)23,,,;(b),,、、.,;(c),,,,.,,,、、,、,,.-,-,,,,.[3]2.2,,.,,.,,、、、、,、,,.,()(),,.2,4-2,6-(TDI)、4,4′-(MDI)、1,6-(HDI),4,6,6--2-(IPDI)、1,5-(NDI)4,4′-(H12MDI),TDIMDI.2,4-4,4′-,,,70%~80%,,.,TDIMDI,,,,.[4]TDIMDI:2.3、,,,,,,,.200510,H&M、、.[5],.2.4,,、,,,.2.4.1,Eco-Label0.1%()0.1%(),Oeko-TexStandard100、,,(2,3-326)(TRIS)、()(TEPA)(PBB).,,,(THPC)、、N-(ProvatexCP)、(PBDPE)、(OBDPE).[4](DBDPE),,3%.,,.,.(1)、、、,1--4--2,6,7-[2,2,2](PEPA),1、23,2:(2)、、,(2,3-)FR-B,,、、、.(3)、、,,:(4)--,,,.(5),BozzettoIgnisalSPN.(6),LvanovoTezagranC、L、P.6,,,、、、、、,.,(Zr)(Nb),.2.4.2,.[4],;,O/W,(APEO),;,,(PFOS),,,200612,2001;(PFOA)PFOS.,(EPA),PFOA,WTOPFOA.,、APEO、PFOSPFOA,WackerFinishWS60E,,;PFOSPFOA,、ScotchguardPM-492NuvaN2114liq.、N4118liq..[6]2.4.3,、、.,20031Oeko-TexStandard100,43.,2,4,4′--2′-(THDE)、2-(4′-)(TBI)、α-(BCA)、2-(3′,5′-)-4--6-、1,2--3-(DBCP).[4]:(1),、、,IrgaguardB7000,;(2),DC-5700,;(3),AveciaReputex20,,ClariantSanitizedT96-04;(4),、.2.4.4,.,M-90,,.,,().3,,,、,,、.:[1].“”[J].,2004(5):84-88.[2],,.[C]//().2007:356-360.[3].[J].,2006(9):12-13.[4].[C]//.2006:31-38.[5]H&MCo..(、、)[Z].2005.[6].[C]//().2007:35-41.EMEERRL!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!GERMANYEMITAGROUPHKINT′LCO.LTD:852-30658374:852-30656487:86-760-86326581/86326561:86-760-86694790:13702393264:13924937901:13702535893:13702364183:86-20-8232470286-20-82326103:86-20-82328692、pH(10%SOL)RL-46.0-7.0、、、、、、、RL-256.5-7.5、、、、、、、RL-2066.0-7.0、、、、、、、RL-2184.0-5.0、、、、、、RL-2684.0-5.0、、、、、、RL-3064.0-5.0、、、、、、、、RL-3094.0-5.0、、、、、、、、RL-3074.0-5.0、、、、、、、、RL-3084.0-5.0、、、、、、、、5