镍催化剂上丙酮加氢制异丙醇的研究-王耀斌

8I19943Vol.8No.lJOURNALOFSHNGHAIUNIVERSI,,YOFENGINEERINGSCIENCEM.1994(200335)Ni--A,.,.:O,,,1606.52min,214%.,2).LlLl.1(C.P)(98%)(A.R):6201,400,12~20%.1.1.2();102G();();();10%.LZNiA1203.,pH,.:993l21:L3(.8xl.75mm,4cm,0.5.,INA12O3(Inm)40~600.45~0.(g/ml)60~800.28~0.1880~l0()0.18~0.150.830.80.4,11,30.3310--3mof/min,(3:2)10.11x103mof/min.,5%,1.5%,,.COMCZA.L4,(4).:(l),;(2),,;(3),;(4)NiA12O3,,,.LSL5.12,680O,3:1,118.2min,.285120,,110120,,110.,,.100%,1..239L2451,OP11:52,60~800.3952,no,410min,,.3,,2()))1200011000loooo8555(%)))9622295.5559099988.7.448,,.(3:l),.,3:1.1:5,110,360800,3952,3:1(),,4.,,,,.()))3:lll3.5:lll4:III4.5:lll5:lll(%)))60.66665.69.55571.33372.99942(m))),.666751.000511666377.333(%)))28.,,39.77751.44465552.1½,(),.2.LI,110,60800.23893:1,,5.50.23899HHH:tttHZx,,xlo,,01/innnmol/innnngh/.0111%%%111500021.9995.63337.2999721.3330.136666,5.666111100014.2223.61114.7333475.0.21044462.0008880009lll2.27773.0333379.2220.32899969.5556660006.444156662..1333323.5550.46822285.2225550005.4441.29991.7999237.1110.55633394.3334440004.2220.98881.3999147.8880.71633395.6663330003222073331.0777122.5550.93099996.22260.39379HHHZtttHZx,,x0333mol/minnnmol/minnnmin111g.h/molll%%%222500042.99911144414.333751.0000.11488860.888111800027.555710009222511.6660.17911164222111500021.9995.63337.333387.3330.22511169.0001111000142223.61114.777347.5550.34686.111888000,.1112.27773.000247.4440.542000,3.4446660006.4441.63332.222146.2220.77166696.3334440004.2220.98881.444118.4441.18044496.8l:,110,60800.3937,3:1,,6.56,,2,2,0.559.h/mol,.2.2,,,110,3:1,167.smin,,0.5,4060,6080,80100,T,3.,60100,.908070600.10.30.50.70.91.0rh/mof2:x:w(Cot)0.3930:W(C.t).0.2389.1002.3,:rKpp:(mm)3015ZoPkpa)4W(C.t)0.2615Uƒ7050:(mol/mingCat.)K(mol/mingeat.P:):eat2.3.12.3.1.1,,:rK,P,110,6080,0.261590.39509,,.3Kpa,p10,8Zo.SKpa,,,0.259h/mol.y(),45,,P,y%,.:r=K,InrinP,,J7,101520P(kPa)SW(C.t),0.3950:46n,1.0851.09.:r=K?.,MiA1203,1.09.2.3.1.2,,:rK:8\\\4,r”ŽUnJ,,971060800.261590.39509,,P,:7281.7KPa,.,0.259h/mol,7.,,,:rK(PH:409x10)pH:409x10Pa,,4.09K10.,wC.t)0.2619.49.710.0inP.7W(C.t)0.3950:ap,2409x10NiA12O31.07.2.12,NiA12O3:r=K(p:40,x,o)K8.K:2.82x1012mol/mingeatPaZ:r2.82x,0pH:40,x,o),10%,.7p:tttrxl333rrrp,:::ggggg9.h/molll%%%mol/nUngCatttttKPaaa0002615550.255571.22271222.955581777666666673336.73335.000077.333333333397773.97775.533372777000.3950000.255580.5559.0555.822281.77777777778.6667.6664.855577.33366666669.3338333-.999972777:PspP:rrrx10333P::090Kx10,22201/mmgCat.))).);(Pa)))(mo/mgeat.P.bbb999.14442.08x103.slxlo{25888.29991.x10...{3.51x10{31222666.73331.52x10{3..027000.0555I5210j40910{1:3gCN3.1.,,,,,,fffff,f~;l.111.1.,J,,,}.CCCu:160006.522221.444.,..12110,3:1,,NA1203:r22,224.09x10),,.,,(PH:4.09xlo).3.3,,0,,.3.4,.15NiA12O,,,,..:1974..:1973..,19,2:112~116.:FeM/A2,.1985,2:49~57..1986,4:23218DL.Nelson,BP.WebbAeetoneVo!.1.J1.rJ(1(2(4.J.J””6..(52)52811..1,93.7(3):17~22[21G.Br.dtkettrop.FZAnCem.1987,3273~2913]Koo.,he.Ox.UonTeChqueinDk9WarTauneot.fRG1979(DrinkwaPilotproctR.POrtnAAdvaneedTaentT.ehnology)DECREASINGTHECONTAMINATIONCAUSEDBYCHLORINATIONFORWATERDISINFECTIONWITHTHEFLOCCULATIONMETHODhAbstrdTheoPtimumfloculationmethodwithFeeChlorideasflocculantbeforeehlorinationhabCenintroduccdinthisPaPerwhieheanducetheeonminationeausedbyehlorinationfoewaterdisinfeetion.TheeontentsofTrihalogenmathane(THM)andorganieehlorineeompounds(AOCI)formedercb]orinatio.hanrcduccdby4050%and45%,respcctively,eomparedwiththeckforinaonaerfloulationwithdirectehlorination.Keywor:FloeeulationChlorinationTrihalogenmethaneAdsotionorganieehlorine(47)ASTUDYOFTHEHYDROGENATIONOFACETONETOFORMISOPROPANOLONTHENiCATALYSTangYaoblnYaRongbG.shzheDeAbtractThekinetiecharaeteristiesofthehydrognationofacetonetheNiCatalysthavebeenstudiedwithakinetiesequationofthetheeonditionoftheeatalystProduetionandthehydrogenatio.sdinthisae1o.Keywords:NiekelCatalystAeetoneIsopr.panolataosPheriePressurebyactionwasobined,andofacetonehavebeendiHydrogenation