特种工程塑料及其应用

150,,(PPS)(PSF)(PI)(PAR)(LCP)(PEEK):PolyphenylenesulfidePPS.:,PPS,PPSPPS:;PPS2600.08%0.02%1.36/0.7%300-330PPS1(),,,,2,,,..2604001.6-1.90.15-0.25...PPS1.,,2.ABSPC100-150PPS.PPSFPPSPPS5/PPSPPSPPSPPSFortronPPS——PPSPPSFortronPPSPPSRytonPPSPPS1990PPS35%199460%212004PPS10%PPS-RytonPPSFortronPPSDICPPSPPSPPS70PPSPPSPPSPPSPPSPPS/——PPSPPSPPS8000/15%-20%PPS0%-40%PPS2005PPS10000/PPSPPSPPSPPS5PPS10%PPSPPSPPSPPSPPSPPSPPSPPS5000-8000/PPSPPSPolysalfonePSFPSUAPSFPSFPSF-100~150,160,190,,,,,,,,PSF0.05%PSFPSFPSFPASFPESPolyimide(PI)21protionsolver1N-2NASALewisPMRforinsitupolymerizationofmonomerreactants,RMR5--23-150060022693100MpaKapton170MpaUpilexS400Mpa34Gpa200Gpa500Gpa4Kapton809012050052×10-53×10-53×10-510-610-765×109rad9073.42.510-3100300KV/mm300KV/mm1017Ω/cm891012DMFDMAC,NMPTHE/300PMR3456LB781Kapton,UpilexApical2.3.2.4M17760000h50%30t4.5.6.7.8.///9.10.a-softerror11.TN-LCDSHN-LCDTFT-CD12.-6070Polyimide(PI)PIPI-PAIPEIPI290490PiPolyarylatePAR-70-+180443B130LiquidCrystalPolyesterLCP80LCPLCPabDuPontKevlar®LCPLCPLCP1.35-1.45g/cm³()/ASTM177Vectra®A430Rodrun®LC3000177243Zenite®6330Vetra®A130Novaccurate®E335G30Sumikasuper®E7000Rodrun®LC5000UenoLCP®1000243Xydar®-930Zenite®6130Vectra®C130UenoLCP®2000TitanLCP®LG431Novaccurate®E345G30Xydar®G-930Titan®LG431Zenite®7130Zenite®6130Vectra®E130iVectra®c1301.601.631.661.671.611.62/MPa135139145150165159/MPa172170174170221214Izod/J/m962991601232081761.82MPa/271275289263276255LCP1aLCPbcLCPUL94V-0dLCP200-300316eLCPLCP90%50%2aLCPbLCPcLCPPSF/PBT/PALCP1140140150/5-7Hr22603004103100100240DuPontEastmanSolvayTicona(Ticona),UnitikaLCP121355LCP15%LCP10LCPLinkControlProtocol()PPPPPPLCPLCPLCPLCP(PEEK)PEEKPEEKPEEKPEEKPEEKPEEK1343000PEEKPEEKPEEK2070ICIpeekPEEKPolyetherEtherKetonePEEK44‘-14333431630%250PIPPSPTFEPPO50PEEKPEEK20024MPa2501213MPaPEEKPEEKPEEK250PEEKPEEKPEEKPolyetheretherketone/PEEK•••••FDA••(PPS)(PSF),(PI),(PAR)(LCP5PEEKPEEKPEEKPEEKPEEKYPEEKFDAPEEK---116/-99.5/0.720.37,-1954,(327)1011101330000,3,4,2.12.2/2.12.3,,250,1.01.64/500.010.051/6,,,9095151960,,19604850-10,6,70PolytetrafluoroetyleneTeflonPTFEF4TeflonTeflonPTFEFEPPFAETFE:·PTFEPTFE260290-300·FEPFEP200·PFAPFAFEPPFA260·ETFEETFE15012300240~26030.05-0.15456“”calphalonfluororubber1948DuPont-2--1.3-50ThiokolN2O419582326246231262VITONA12463VITONB26TPAFLASVITONGLTKALREZ3MSolvay3FO2623262698%HNO32713%~15%26-4125030024626-41300×10026-41300×100246100%90~95246350164001104001101/2~1/31/223-11200250DuPontVitonA0.01%45232624637×10-6/224610-92610~20MPa150~350%3~4KN/m2315.0~25MPa200%~600%2~7MPa1502626200×24150×242326263023-11Tg026232465×1071×1071~320%30%~50%2461×1075×107200~2503001000~50005~1014067%7030%275149420160~170300—120200~300Km133×10-6Pa10-6mmHg643Km133×10-7Pa10-7mmHg26246200~25030023”N2O4“O”GVitonABEGLT—200204“”SHED1-40~150-40FFVFlexibleFuelVehicleFFV10%66%66%SP-20F615Fooooo“”PTFE.-CF2-CF2-CF2-CF2-CF2-CF2-CF2-CF2-CF2-CF2-.,(PFOA)1041039095327342CF2CF21913619157--346.94484.88kJmol1mol171.38kJ2603704201×10-44×10-39×10-226015--1962603000.1g100g10440803262171.38kJ•-190~26090R-134aR134aHFC134aHFC-134aSUVA134aGenetron134aKLEA134a1,1,1,2-tetrafluoroethane1,1,1,2--CH2FCF3R-134aHFCODSOzone-depletingSubstances——R-134aHFC-134aCFC-12R-12R1212F-12CFC-12Freon12R134aR12R134aR12R12R12R134aR12R-134a102.01atm-26.2101.1kPa407025kPa661.9/1atmkJ/kg216ODP0(GWP100yr)1300ASHRAEA1UCONRO-W-6602aMobilEALArctic32bCastrolIcematicSW100bcSt4030.712513429.4108.8R12R12R134aR134aR134a/——4232——4232000000000000000%%NDNDNDND1-12.7-3.1-36.24.3-27.1HFC-134appmppmNDNDND42070.73——0.37a——b——ND——0——3——5——300/30/13.6kg/400kg/800kg/R-134aR-134aEmkarateRL32HRL68HRL100HRL170HRL220HICEMATICSOLESTETFEETFEF-40ETFEF-40ETFEETFE-ETFE0.20mm2008ETFEETFE20ETFEETFEETFE25-35415-30ETFEB1DIN41020.15-0.35ETFE95%50%K2.0W/m2K0.77ETFEETFEETFEETFE