常用催化剂及配体

钯催化剂:编号中文名简写结构式分子量CAS备库数量备注1醋酸钯Pd(OAc)2224.53375-31-3100g2氯化钯PdCl21777647-10-1100g3四三苯基磷钯Pd(PPh3)41155.614221-01-325g易变质4[1,1'-双(二苯基磷)二茂铁]二氯化钯Pd(dppf)Cl2731.7172287-26-4100g经常以氯仿或二氯络活物存在5双三苯基磷二氯化钯Pd(PPh3)2Cl2701.913965-03-2100g6三（二亚苄基丙酮）二钯pd2(dba)3915.751364-51-3100gBuchwald-Hartwig最常用催化剂7烯丙基氯化钯(II)二聚体[PdCl（ally）2]363.812012-95-210g8[1,1'-双(二苯基膦基)二茂铁]二氯化钯Pd(dppp)Cl2731.772287-26-425g9乙酰丙酮钯Pd(acac)2304.614024-61-410g聚合反应应用较多配体:中文名简写结构式分子量CAS备库数量备注1三苯基膦PPh3262.30603-35-0250g22-双环己基膦-2',4',6'-三异丙基联苯XPhos476.7564483-18-725gBuchwald-Hartwig最常用配体32-双环己基膦-2',6'-二甲氧基联苯SPhos410.53657408-07-625g42-二环己基磷-2',6'-二异丙氧基-1,1'-联苯RuPhos466.4787618-22-825g54,5-双二苯基膦-9,9-二甲基氧杂蒽XantPhos578.62161265-03-825g61,1'-双(二苯基膦)二茂铁Dppf554.412150-46-8100g71,1'-联二萘酚BINOL28618531-99-2100g8(±)-2,2'-双-(二苯膦基)-1,1'-联萘,BINAP622.698327-87-8100g9三环己基膦Pcy3280.42622-14-2100g怕氧化