增黏树脂与弹性体SBS的相容性以及与热熔压敏胶性能的关系

CHINAADHESIVES2(X218228Vol.18No.2,Feb.25BS,(,210037):(HMP),SBS(//),,,100110,HMPSA.12cm;100,HMAHMAHMA;w()210%(S),HMA()HMP;w())210%,HMPSA10X)mpa.s,():;;SBS;;;:TQ436.3:436.4:A:I(X2849(2()02002850(HMPSA),,,,,lHMPSAl(),:I,,,;CS,,t.,HMPSA,SBs(//)HMA,1.1SBS792,,;(40ro),,;(10roro76),,;(10(S),,;C,(Cloow),,;,,2BLD2005,:2(X)8-0826;:200816:(1983),,,:Email:linzhoni93g.11om182SBS29;NDJ1,;(),(GB!T48522002);360,;SYP4202I,1730cm,C=O,1ros1237cm,C0C,();165OCm,CC;970cm,()1.3HMPSA,N:;,,;,SBS,SBS,;,,,.4,GB48522002,;,GB48511984,;,HG36601999,;1800,GB27921981,;,GB15332--1994,;(FTeeIR),(KBr)22.,FTlFTee1Rl,FTIR;2869-2970em,2927293lCm,CH:,1369~1384cm,14571465em,CH3,16001sooCm,,,,SBS,2.2HMPSA,,()4050,,,,,,2.2.1.HMPSAHMPSA11,,HMA;,,SBSHMA,HMPSA,80115,HMPSA;,,SBS,11l1HMSATab.1EffecofsoneningintoftackinginonHMAsinitialtack/Icm20001010201.802.8010.00508500950015204XK)3(X)2)1(0Icm1FFig.1FTIRspectrogramofdifferenttackifyingresinsHMPSA18002,2,1121;,(l),x()x,y0()y1800230182l2HMSA3J.HMSAFig.2EffectofniintofkinHMAslingFig.3EtofsofteniintoftackifyingresinonHMAsltivi~2,80,3Tab.2ParameterehOfGaussianationforI80oIingsngthThb.3ParameterehartofGaussianequationformeItingviscosity472.438612.202132.20x109.6108.9x107.1091.509.715.148.707.70A7.95.2A31.875.35exp2(xx),}(l)(l)2,:(108.9,100.6)2,HMPSA;,HMPSAHMPSA;,HMPSA,lroHMPSA,2.2.2HMPSAHMPSA3,3,112(2),HMPSA3xl03xexp2(x)1,1(2)3,,HMPSAHMPSA;,HMPSA,x107.1;,HMPSA,looHMPSAHMPSA,,100lro23HMPSA,,,HMPSA18004HMPSA54,,HMPSA()HMPSA;()HMPSA,,o1n,U„J,,„,ƒ.”„O3436384()424446485052545658()l4HMPSAFig.4EffectofdifferenttackifyingresinonHMAslingsrrenh182SBS~(100S),HMPSAHMPSA3()/5HMpSAFig.SEectofdifferenttackifyingresinonHMPSAsmeltingviseosity()46HMPSA;HMPSA,w()6,w())50HMPSA5,HMPSA,,w()44;()HMPSA,,w())46(SBS210%),HMPSAHMPSA44HMSATab.4Effeetoftaekiing,sinonHMAsinitialraekandholdingtaek)l/cmIcmIcm361.73231.103.1.53150421303514.206.583.461.9148.(X)!.491l.0()7.583.575022148(X)l,3911.7510.8.68542.32481.3719.3710.(X)9.68582.9!8.2.4848.10.11.4,HMPSA,HMPSAHMPSAHMPSA;,HMPSA,HMPSA,,HMPSA;,HMPSA;,,HMPSA,,,100lro;SBS210%,HMPSA;()HMPSA;()HMPSA;()HMPSAHMPSA0JO,,,1ƒ.5]6].[Jl.,2007,28(6):112,16.,.M].:,2.JACOBLE,SWIGGERSE.Hotmeltpressuresensitiveadhesiveeomposition:US,6384138Pl.2(X)20507DEKEYZERNRM,ST()NERCA.HotmeltPressuresensitivesitioningadhesive:US,6465557P.2(X)2-1015.,,.[J].,2(X(l):118121.YANGHOICHANG,SAUNNYOUNG,KANGMINJEONG,et.NearsueemorPhologyeffeetontackbehaviorofly(styrenebutadienebstyrene)tribloekcolymerlosinfilmsJ}.POlymer,2X,47(:3889-3895.,,.[J].,2007,14(6):554.,.Jl.,2(X)5,14(l):3234.KUM00KAY.Analysisofrosinandmodi6edrosinestersinadhesivesbymatrixassistedlaserdesotioionizationtimeofflightmassspeetromet(MALDITOFMS)Jl.ForensieSeieneeInternational,2(X)8,176(2):111120.,,.CSIJ].,2008,26(l):2730KIMDAEJUN,KIMHYUN00NG,YOOHGOANHEE.Effeetofsubstrateandtaekifieronpeelstrengthof515(styreneisoprenestyrene)basedHMPSAs[J].InternationalJournalofAdhesion&Adhesives.2(X)5,25(4):1lJ.....J,...1..Jl,jr...r.Lr..Lf.,J.1..J1..JR”Or..Lr..Lr.L1..J,...0l....r..Lfwe32182121288295.VUIC.PIVRIKASA,HUANGCHUN,e.AstudyofehargensrtinanovelelecluminescentIy(Phenylenevinylenenuorenylenevinylene)b-eonjugatedpolymer[J].organicEleenies,2(X)7,8(l):813.ComPatibilitybetweentaekifyingresinsandelastomerSBSaswellastheirrelationtoHMPSAPerformaneeYu,LINx(SchoolofChemiealEngineering,NanjingForestUniversity,Nanjing21(X)37,China)Aract:Hotmeltpressuresensitiveadhesive(HMPSA)whiehhashighproPortioninindustrialapplieation15akindofthesolventseeadhesive.Therosinresins,teneresinandpetroleumresinwerethreetypesofeom-montackifyingresininindustry.TherearediffereneesineompatibilitybetweentackifyingresinsandthermoplastieelastomerSBS(styrene-butadiene--styreneblockeopolymer).TherelationbetweenthestrueturaldiffereneeOftaeki-fyingresinsandperfonnaneeweremainlystudiedandeomParedfromindustangle,anditsgeneralrulewasexPlored.TheresearchresultsshowedthattheHMPSAhadlowermeltingviseosityandhigherpeelingstrengthwhenthesofteningintoftackifyingresinwasbetweenl(X)and110,temralitytheinitialtackwasbetween1emand2em.Theordersofpeelistrengthwasfromlertosmall:HMPSAwithteeneresinHMPSAwithrosinresinHMPSAwithtroleumresinwhenthesofteningintoftaekifyingresinwasl(X).Whenthemassaetionoftackifyingresinswas210%inelastomerSBS,theeolnbinationPropertyofHMPSAwithPetroleumresinwasrerthanwithrosinresinorwithteneresinThemeltiviscosityofHMPSAwaslowerthan10Patheholdingtackwasinereased(namelytheeohesionwasreinfoed)whenmassfraetionoftaekifyingresinswasmorethan21.K,o:tackifyingresin;elastomer;SBS;eomPatibility;strueture;HMPSA,,,,(),,UV,,,()OVOCO(NordsonCrotion),EFD752H.,;,OVDOVDCO()otex()2,()()