乙腈后续产品加工利用综述

(,,255068),:TQ22616:A:1009-9859(2008)03-0226-052,3%,99%,,1,,,ppb,,AB2-,,,,,,,,,,1998,315410kt,410kt113kt,2000710kt,10kt2,200799412kt,,3%,2918kt/a9,699%,11/kta-13192150198614114718:2008-06-19;:2008-07-23:(1966-),,1988,,:0533-3576149,2008,36(3):226230QILUPETROCHEMICALTECHNOLOGY2273,,,31131111(1),B1B1[1][2]:;-,,,,,,9317%,81%86%12151105,LonzaHoffmannLarochcRhoneRoulenc,AndersagB1[3]B12500t/a,500600tB1110112,500600t/a;,600700t/a(2),,,,ForonBrillS-R,,,500700t/a[3](3);;;,,,,,,31112[4],,,(),,,,,4080,HCl,,HCl,,Lonza250t/a,300400t/a31113,,,,,2008499%816/t312,,,31228,100kt,90%200011kt/a,,,,2-2--5-312112-(1)2-6:,(),,,,175,,7614%2-Lonza,2-[5],01001mol/L01963mol/L,1115MPa,1h1802h216MPa018MPa,4h,011MPa,9712%,2-8212%,9916%719%(2)2-2-2--3,5,6-2--6-4--3,4,5--2-,2-2-2--5-2-2--5-,2-2--5-15%,,2001200kt,1500t,2-20048,2-(9919%)316/t[6][79]2-,2-2-,,2-;,;2-HIV,2-,2-2-,2-,199550t,,,,2-2-5,5kt/a2-1kt/a,312122--5-2--5-,2--5-(CCMP),,,,(1)2--5-2--5-:3-3-[10],[13],,,236229--5-,ReillyPOCl30HCONMe2,4004h,32%2--5-Viljoon,1-,,(2)2--5-2--5-,,,200310118/kg,200712350/kgCC2MP,CCMP,CCMP,,:,;CCMP,CCMP,2--5-,CC2MPN-H1--2,2-(),,,2--5-2--5-,,,,,313,,:,31311Knapsack,,,,,,,31312US4981670[11],,,1/61/8,,Mo-Bi-Fe,300550010690114MPa120s,:,;,,;,,;,,,,314,H,31230:,Monsanto[12],110130,,,,,,:,;,;,,100%2001,,315(C9H7N),,,,,,,,,,,,,,,,,,,[13],,(10min),,48%54%4,,,:(1),,,(2),,,(3),,111,1998,27(5):367370211,2005,12(6):46473,11,1996,(4):47494,11,2003,32(6):26275HardtPeter1Processforthecatalyticproductionof2-substitutedpyridines1USPatAppl,US4212978119806,,12-2-1,2002,16(4):4364407LeiticsL,ShimanskayaMV1Vapor-phaseoxidationofmethylpyridinestopyridinecarboxaldehyde1KhimGeteroSoedim,1967,3:5075118SinghBC,NayakPL,PoutMK1Kineticsofoxidationofa-picolinebycerium()inaceticacid1IndianJChem,1974,12(4):421422(233)362333,1a,,,,4,,,()111,1993,23(6):252721,,2006(4):61623,11:,1992169DISCUSSIONSONCORROSIONANDPROTECTIONOFNAPHTHATANKERZhaoZhiqiang(Storage&TransportationComplexofQiluBranchCo1,SINOPEC,Zibo,Shandong,255411)AbstractCorrosionofnaphthatankerismainlycausedbywater,saltandsulfur.Thispapereducesthemainchemicalcompoundsandcorrespondingchemicalreactionsaccordingtothechemicalcompositionsandtheircontentsintherust,andputforwardscorrespondingmeas2urestopreventnaphthatankersfrombeingcorroded.Keywordsnaphtha,tanker,corrosionprotection(230)9GlubokovskikhLK,KanII,SuvorovBV1Oxidativereactionsof2,6-lutidineodfusedvanadiumpentoxide1SerKhim,1980,(5):51541011,2000,20(2):1611Dio,Susan1HCNfromcrudeaceto1USPatAppl,US49816701199112Williams,EricL1Processforthepreparationofthioacet2amide1USPatAppl,US52849741199413,,11,2007,37(6):413416OVERVIEWOFPROCESSINGANDUTILIZATIONOFACETONITRILEDOWNSTREAMPRODUCTSGongXiaoyan(NitrilonComplexofQiluBranchCo1,SINOPEC,Zibo,Shandong,255040)AbstractBrieflypresentstheproductionandapplicationofacetonitrile,overviewsthepropertiesandapplicationprospectsofitsdownstreamproductswhichhavegoodmarketandprofits.Keywordsacetonitrile,malononitrile,acetamidinehydrochloride,pyridine,hydrocyanicacid31