高性能热塑性树脂基复合材料的研究进展

1、陈平于祺孙明陆春(,116012),,,;;;AdvancesinHighPerformanceFRTPCompositesChenPingYuQiSunMingLuChun(DepartmentofPolymerScienceandMaterial,DalianUniversityofTechnology,Dalian,116012)ABSTRACTInrecentyears,fiberreinforcedthermoplasticcompositematerialshasbecomeanewfamilymemberofcompositeswithhighperformanceandlowcostmaterials.Thispapermainlyintroducesthedevelopmentofhighperformancethermoplasticandreinforcedfiber,theimpregnatingprocessandformingtechniquesofthethermoplasticresinreinforcedwiththecontinuousfiber.。

2、Atlast,thedevelopingtrendofthethermoplasticcompositesisalsointroduced.KEYWORDSthermoplasticresin;highperformance,fiberreinforced;composites150,90,,(FRTP)(FRP),:(1);(2);(3);(4);(5);(6)FRTP70,,,P,10,25%,[1],,,FRTP2FRTPFRTP,FRTP;2.1FRTP,FRTP,,Tg177e,,70MPa,2GPa,100MPa3GPa[2],ICIDuPont(PEEK)(334~380e,240~260e);Hoe-chest(PEK);Phillips(PPS)2No125220056FIBERCOMPOSITESJun1,2005,(PES)(PEK),(PES-C)(PEK-C);/##0,(PPESK)(PPE-KK)[3-7]1,,,,,,,,1Tg(e)(GPa)(MPa)(%)PEKK1564.501024PEEK1443.7910311HTX2052.488613PAS。

3、-22153.281018PPS853.91803PEI2172.9610460PES2602.41767PAI2833.3013525PES-C2603.2893PEK-C2283.51033.3PPESK2841.4190.711.22.2,,,,FRTP,,:E)C)S)D)E),90%E),S),,22()E-C-S-(GPa)3.443.314.583.4(GPa)81.3)86.869(%)4.84.85.7)(10-1PK)5.46.32.80.5(gPcm3)2.552.562.52.2(WPmk)0.87)))(kJPkg#K)0.8250.7870.7370.96,,)))X,,X),PAN,6B1,PAN,,PAN,P3[8-10]3(%)(MPa)(GPa)T3001.72900230T700S2.14900230T800H1.95490294T1000G2.26370294M50J0.84120475M55J0.84020540M60J0.73920588IM4001.54510295IM6002.05690285UM401.24900380UM550.740。

4、20540UM680.53300650(UHTPE)(PTAA)(PBO)UHTPE2:53,,UHTPE150e,PTAA70PTAA100~200GPa2~4GPa0.97~1.47gPcm3PTAA,PBO(Poly-p-phenylenebenzobisthiazole),21,(Zylon)PBO,Kevlar()2,,Kevlar,PBO,,44(NPtex)(GPa)(%)(gPcm3)(%)(e)zylonHM3.72802.51.560.6650zylonAS3.71803.51.5426501.951092.41.454.55500.4717221.384.5400UHTPE3.571703.50.970150(PBI)0.285.6301.401.55503FRTP,,FRTP,,,,,,,5:(1)[11~14];(2)[15~17];(3)[18~20];(4)[21~28];(5)[29~34]3.1,,,,,,,,,,,,,,,,[13](,)(),,,30%~60%[14]PEEK,,2.2,,,,,,[16]542005ABS,[17],,,,,PES。

5、-CPEK-C,[18],T700F-12PPESK,[19],,;,,,2.3,,,,,,,,,[19],,,,,,;,[20]PEEK,,,AS4CPPEEKT300P5405,T300P5405,GIC1560JPm2,CAI285MPa,,,,,,,,,2.4,,,,,,,:(1),;(2),;(3)mm,20L;(4),,,10mPa#s,;(5),,,,,;(6)[21]PPS,,;[22]PPS(PPSP);[23]PPS,,,,,,,,,Augstin[25]5mPmin60%;BASF[24]PEKPEEKPEEKKPES2.5,NASAPBTPET(LCP),,,,2:55(10Lm),,Wulthorst[31-33],;[34],,,,,,,,3FRTPFRTP,,,,,;,3.1FRTP,,,,CFRTP3.2FRTP,,,,,,3.3,,,,,,,,3.4,,,(),,(IR)(MW)(RF),,(),;,(),,();,,4FRTP,:(1),;(2),;(3),;(4)FRTP,,,,562005,,FRTP,,1.,1997,2:27~312L.A.C。

6、arlasson,ThermoplasticCompositeMaremials,19913,,.,2002,4(16):11~154,Allanshay,.93109180.25,Allanshay,.93109179.96,,.,2003,4:461~4677,,.,2001,15(2):244~2488SERAFINITT.Hightemperaturepolymermatrixcomposites.NoyesDataCorporation,19879MEADORMA.40thSAMPESymp.1995,26810CHANGEJCI.42ndSAMPESymp.1997,43511Tai-Shungchung.,Summit,HowardFurst.U.S.Pat4,588,53812EdwinK.Binnersley,willianH.Kracper.U.S.Pat4,640,86113,.,2000,28(5):15~1714,.,1995(1):9~1515GoodmanK.E.andLoss,A.C.J.Thermoplasticcomp,1990,3,3416,.,2。

7、001,12(12):1415~141817,.,2001,21(2):44~4718,,.,2004,21(1):119,,.,CN04100050246.620,.P,2000,2:5~821,.,1996,6:40~4422,.,1996,12(4):59~6223,.P,1997,2:35~3624,.,1995,12(4):44~4825ATexier,RMDavis.polymer,1993,34(4):898~90626AMVodermay,JCKaergerandGHinrichsen.CompositeMahufactur-ing,1993,4(3),123~13227DFHISCOCKandDMBiGG.polymercomposite,1989,10(3):14528JamesE.O.Connor,Bartlesville.U.S.Pat4,680,22429RAWessling,LDYatsandDKTolbert.U.S.Pat4,426,47030RamasamyA,WangYoujiang.PolymerComposites,1996,17(3):492~。

8、52231,.,1997,11(2):69~7232WulthorstB,TetxlaffG.TechnischeTextilien,1992,Marz,3533KaldenhoffRandWulfhorst.TechnischeTextilien,1993,Mai,3634RerE.Textile,1996(2)35,.P,1997,4:5~7(上接第30页)VEGF,1mm,VEGF,4,(VEGF)(),4(Perm-inch)VEGF0.0002VEGF0.00050.00090.00160.007820.00157413VEGF,(),VEGF(FRP),FRP,,VEGFFRPVEGF414VEGF,80VEGF,415VEGF,VEGF,,,,FRP,()1..:,19962.(1),:.2001,103.VEGF.,2002,2:70~724.,:.19995.,:.19956.,:.20017.,:.20018.5656,.19912:57。