04 其它多元醇及含活性氢低聚物

4()4.1-(hybridpolymer)()BayerMaterialScienceDesmophen4-14-1BayerDesmophen%%mgKOH/g(23)mPa·sA160SN60±11.6±0.34±22800±5001.00A160X60±11.6±0.34±21800±5000.98A165BA/X65±11.7±0.34±24300±5001.00A170BA70±11.8±0.213±23750±10001.02A265BA65±12.0±0.3152300±5001.06A365BA/X65±12.9±0.47.5±2.53000±5001.04A450BA/X50±21.0±0.24±24±1Pa·s1.01A450BA50±21.0±0.24±24.5±1Pa·s1.01A450MPA/X50±21.0±0.24±25±1Pa·s1.01A565X65±12.6±0.35±21000±3001.03A575X75±12.8±0.25±23500±5001.06A665BA70±13.2±0.47.5±2.58500±15001.05A665BA/X65±13.0±0.46.5±2.52400±5001.03A870BA70±12.95±0.157.5±.53500±7001.03BAMPAXSN100VOC()LyondellAcryflow(AA)1,3-(AP1.0)AcryflowAcryflowA1402()12(HEMA)144mgKOH/g225%113LyondellAcryflow4-24-2-1LyondellAcryflowA90A140M100P60*P90P120()/(mgKOH/g)901401056090125()6398846090125()6234015349006234301074.47.04.52.45.66.0220025002400220029002600600060005900470070005700(Mw/Mn)2.62.42.52.12.42.2Tg()/55525-52-44-40/%707080100100100/(g/mL)1.0301.0371.0101.021.0501.050(APHA)254020303060()/Pa·s5.7889~103035AAAAAP1.0AP1.0AP1.0AP1.0()/343431~16393~121251mgKOH/gP6020044-2-1AcryflowA90TgVOCA140TgVOCM100TgVOCP60P90P120P9010080300mPa·s100UVP12010080300mPa·s100UVAcryflowLyondell(ResinManagementConceptRMc)4-14-1AcryflowPlaccelEPAPlaccelDC()HDI4-34-3PlaccelmgKOH/gmgKOH/g(25)mPa·s()TgEPA225047~532400~630502/EtAc(1/1)35EPA586027~3211300~2100601/MIBK(1/1)12DC200985~9522700~370070226DC201675~8521200~180070213.5DC22099~152400~80050291084.2-4.2.1(hydroxyl-terminatedpolybutadiene)HTPBHTPB2~2.61,4-/1,4-/1,2-20/60/20HTPB0.890.92g/cm3HTPB4-44-64-4HTPB/(mmol/g)0.40~0.530.54~0.640.65~0.700.71~0.950.95~2.00/%0.100.100.100.100.15/%0.050.050.080.100.10(40)/Pa·s159.56.55.54.5(VPO)2500~50002000~43001800~35001600~33001500~30004-5IIIIIIIV/(mmol/g)1.00.65~0.800.45~0.600.5~0.7(Mn)20002300~35003500~45002200~4000VPO(30)/mPa·s250080002000020000/(mg/kg)500500500500H2O2/(mg/kg)5005005005004-6(mmol/g)1.000.80~1.000.65~0.800.55~0.65Mn23002300~28002800~35003500~4500(40)/Pa·s3.05.06.09.0/%0.100.100.100.10(H2O2)/%0.050.050.050.05Atofina(ElfAtoChem)PolybdR-45HTR-20LMAtofinaSartomerCrayValleySartomerCrayValleyHTPBSartomer4-74-94-7AtofinaPolybdPolybd(Mn)mgKOH/gmmol/gPa·sTgMw/Mn(23)R-20LM12001011.81.4~2.5-702.00.9132.4~2.6R-45HTLO2800480.855-752.50.9012.4~2.6R-45M2800410.734.3-762.20.8992.2~2.41,4-/1,4/1,2-20/60/2099.90.0530AtofinaPolybdR-45MPolybdR-45HTLO50400g/100g10050g/100mL10g/100mLCrayValleyPolybdR-45HTLO99.5%0.1%(30)40006000mPa·s0.73~0.93mmol/gPolybdR-20LMHTPB420g/100g109PolybdR-45PolybdR-45MPolybdR-20LMPolybdR-45M4-8SartomerKrasolKrasol1,4-/1,4/1,2-Tg(Mn)mmol/g(25)Pa·sMw/MnLBH200012.5/22.5/65-3321000.91131.35LBH20404.0-3322491.79161.851.2LBH300012.5/22.5/65-4030000.64201.35LBH500012.5/22.5/65-450.500038291.35LBH1000018/17/65-50100000.1935(50)1.1LBH-P200012.5/22.5/65-3021000.91131.35LBH-P300012.5/22.5/65-4132000.64201.35LBH-P500012.5/22.5/65-4253000.38291.35LBHLBH-PLBH2040HTPBLBHHTPB99.5%0.04%(20)0.94-9SartomerPolybdPolybd1,4-/1,4-/1,2-(Mn)mmol/g(30)Pa·sTgMw/MnLF-115/46/3922910.875.0-672.9LF-212/35/5320290.895.25-572.67LF-39/27/6424740.95.75-481.7LF-516/45/3927560.85.50-692.52LF-613/36/5132540.756.0-571.84LF-710/27/6332350.77.25-501.599.5%0.04%0.9HTPBH2O2HTPBRIMCASEHTPBSartomerCrayValley4.2.2SartomerKrasolHLBH-P300097%98%1.931mgKOH/g0.56mmol/g310065Pa·s/257Pa·s/500.03%Tg464.2.3(epoxidizedhydroxylterminated110polybutadieneresin)HTPBCAS129288-65-9AlewisAtofinaSartomerCrayValleyPolybd600EPolybd605E4-104-10SartomerPolybd(Mn)mmol/gmmol/g(30)Pa·sTg/Mw/Mn600E13501.72.27-704.0460605E14501.743.522-704.53000.05(23)1.01CrayValley600E1.8610Pa·s410470605E25Pa·s2803204.2.4--HTBN-(polybutadiene-acrylonitrilecopolymerglycol)HTBN-HTBNa/b0.85/0.15n5565-4-114-124-11HTBNIIIIIIIV2000200020002500(40)/Pa.s20.025.030.015.0/(mmol/g)0.500.450.40.55-0.7/%102.0152.020±2.05.0±2.0/%0.050.050.050.05(H2O2)/%0.050.050.050.054-12HTBNIIIIIIV/%101.5152.0202.0202.53000270025002500VPO/(mmol/g)0.50.450.400.40(70)/Pa·s20(40)1525/%0.050.050.050.05H2O2%0.050.050.050.05HTBNHTBNHTBNHTBN111HTBN4.2.5HTBSHTBS4-134-13(Mn)(40)Pa.smmol/g%mg/kg2500120.60~0.70.105002000160.70~0.8018500HTBS4.2.6-SAALyondellSAALyondell-34-144-14Lyondell-SAA-100SAA-101SAA-103/70/3060/4080/20(Mn)150012003200(Mw)300025008400/(mgKOH/g)210255125/%6.47.73.8/(g/mol)267220448(Tg)/625778(APHA,30%)4040401.0551.0941.05SAASAASAA4.31124.3.1CastoroilRicinusoilCAS(CAS)8001-79-435%57%703090%(Ricinoleicacid9--12-)103%4%(Oleicacid)3%4%(Linoleicacid)0.5%1%()3452.7(20)0.9500.965g/mL(20)1.4751.4851810313229160mgKOH/g(163mgKOH/g)4.9%176186mgKOH/g8290mgKOH/g5.0mgKOH/g5.0mgKOH/g()12mgKOH/g0.21.0%()200220()11(Uric)4.3.2(soybeanoil)2030(oleicacidC18:1)4558(linoleicacidC18:2)410(linolenicacidC18:3)1131998UrethaneSoySystemsCo.(USSC)Soyoyl(4-15)2054-15USSCSoyoylSoyoylR137SoyoylF672/(mgKOH/g)212130/%3.50.5/(mgKOH/g)6.55.5/mPa·s300030004.3.3Maskimi(MaskimiPolyolSDNBHD)(naturaloilpolyolNOP)MaskimiNOP2.53.0NOP/4-16MaskimimgKOH/gmPa·sg/mL%pHMaskimiolPKSU32370~3801600~18001.0218~9MaskimiolPK317315~330250~3500.900.308~9MaskimiolPK230215~245100~1500.900.108~9MaskimiolPK350340~360900