GB13690-92+常用危险化学品的分类及标志附录A

1附录A常用危险化学品分类明细表（补充件）A1第1类爆炸品A1.1具有整体爆炸危险的物质和物品。表A1序号品名别名分子式（或结构式）主（次）危险性类别危险特性标志12,4,6-三硝基甲苯(干的或含水30％)trinitrotoluene梯恩梯茶色炸药CH3C6H2(NO2)3爆炸性（有毒）5.13,5.17,5.37,5.57,5.110,5.1201(26)22,4,6-三硝基苯甲硝胺2,4,6-trinitrophenyl-methylnitramine特屈儿(NO2)3C6H2N(NO2)CH25.13,5.31,5.38,5.57,5.95,5.11032,4,7-三硝基芴酮2,4,7-trinitrofluorenoneC6H3(NO2)COC6H(NO2)25.9,5.57,5.85,5.11042,4,6-三硝基苯胺2,4,6-trinitroaniline苦基胺NH2C6H2(NO2)3爆炸性5.13,5.57,5.110151,3,5-三硝基苯(干的或含水30％)1,3,5-trinitrobenzene均三硝基苯C6H3(NO2)35.13,5.5762,4,6-三硝基苯甲酸(干的或含水30％)2,4,6-trinitrobenzoicacid三硝基安息香酸C6H2(NO2)3COOH5.13,5.577三硝基苯甲醚trinitroanisole三硝基茴香醚苦味酸甲酯C6H2(OCH3)(NO2)35.13,5.23,5.57,5.11082,4,6-三硝基苯酚(干的或含水30％)2,4,6-trinitrophenol苦味酸(NO2)3C6H2OH爆炸性(有毒）5.13,5.57,5.94,5.1101(26)92,4,6-三硝基苯酚铵(干的或含水10％)2,4,6-ammoniumtri-nitrophenol苦味酸铵C6H2(NO2)3ONH4爆炸性5.13,5.32,5.36,5.57,5.711102,4,6-三硝基氯苯2,4,6-trinitrochlo-robenzene苦酰氯苦基氯C6H2Cl(NO2)35.13,5.5711三硝基萘trinitronaphthalene(NO2)C10H55.13,5.57,5.90212六硝基二苯胺（含水＜75%）hexanitrodiphenyl-amine二苦基胺、六硝炸药(NO2)3C6H2NHC6H2(NO2)3爆炸性（有毒）5.13,5.18,5.32,5.57,5.94,5.105,5.1121(26)132,3,4,6-四硝基苯胺2,3,4,6-tetranitro-anilineC6H(NO2)4NH2爆炸性5.13,5.57,5.110114环三次甲基三硝胺（含水≥15%或含钝感剂）cyclotrimethylene-trinitramine黑索金、旋风炸药C3H6N3(NO2)3爆炸性（有毒）5.13,5.57,5.1101(26)15季戊四醇四硝酸酯（含水≥25%或含钝感剂≥15%）pentaerythritetetra-anitrate泰安、喷梯尔C(CH2ONO2)45.13,5.32,5.57,5.11016高氯酸（浓度＞72%）perchloricacidHClO4·2H2O5.52,5.57,5.99,5.110,5.112,5.11517硝化甘油（含不挥发、不溶于水的钝感剂≥40%）nitroglycerin硝酸甘油酯硝化丙三醇甘油三硝酸酯C3H5(ONO2)3爆炸性5.21,5.57,5.110118硝化淀粉（干的或含水＜20%）nitrostarch[C6H7O2(ONO2)3]n5.13,5.57,5.5819硝化纤维素（干的或含水或乙醇≤25%或含增塑剂＜18%）nitrocellulose硝化棉C12H17(ONO2)3O7~C12H14(ONO2)6O75.13,5.21,5.32,5.37,5.57,5.11220雷酸汞（含水或水加乙醇≥20%）mercuryfulminate雷汞Hg(ONC)2爆炸性（有毒）5.32,5.37,5.57,5.58,5.1101(26)A2第2类压缩气体和液化气体A2.1易燃气体表A2序号品名别名分子式（或结构式）主（次）危险性类别危险特性标志1一氧化碳carbonmonoxideCO易燃气体（有毒）5.1,5.20,5.1032(20)32乙炔（溶于介质的）acetylene电石气C2H2易燃气体5.3,5.13,5.4323乙胺ethylamine一乙胺氨基乙烷C2H5NH25.7,5.13,5.95,5.1094乙烷（压缩的）ethaneC2H65.1,5.13,5乙烷（液化的）ethaneC2H65.1,5.136乙烯（压缩的）ethyleneC2H45.13,5.1027乙烯（液化的）ethyleneC2H45.13,5.1028二甲胺(无水)dimethylamineC2H7N易燃气体（有毒）5.13,5.99,5.1092(20)9（二）甲醚dimethylether甲醚CH3OCH3易燃气体5.1,5.13,5.102,5.109210二硼烷diborane乙硼烷B2H6易燃气体（有毒）5.11,5.17,5.37,5.67,5.105,5.1112(20)111,3-丁二烯(抑制了的)1,3-butadiene联乙烯CH2CHCHCH2易燃气体5.13,5.1092121-丁炔（抑制了的）1-butyne乙基乙炔C2H5CCH5.13,5.94131-丁烯1-buteneC4H85.1,5.13,5.109142-丁烯2-buteneC4H85.1,5.13,5.10915三甲胺(无水)trimethylamine(CH3)3N5.1,5.13,5.94,5.10316正丁烷butaneCH3CH2CH2CH35.1,5.13,5.10217异丁烷isobutaneC4H105.9,5.10218丙烷propaneCH3CH2CH35.1,5.13,5.102,5.10919丙烯propyleneCH2CHCH35.1,5.1320丙炔propyne甲基乙炔CH3CCH5.7,5.13,5.2021甲乙醚methylethylether乙甲醚甲氧基乙烷C2H5OCH35.6,5.7,5.1322甲烷（压缩的）methane沼气CH45.1,5.13423甲烷（液化的）methane沼气CH45.1,5.1324甲硫醇（液化的）methylmercaptan巯基甲烷CH3SH易燃气体（有毒）5.1,5.10,5.82,5.86,5.1112(20)25异丁烯isobutylene(CH3)2CCH2易燃气体（有毒）5.13,5.75,5.1092(20)26环丙烷（液化的）cyclopropaneCH2CH2CH2易燃气体5.1,5.13,5.102227环氧乙烷ethyleneoxideCH2CH2O5.1,5.13,5.9428氢（压缩的）hydrogen氢气H25.1,5.13,5.4329氢（液化的）hydrogen氢气H25.1,5.13,5.4330氯乙烯（抑制了的）vinylchloride乙烯基氯CH2CHCl易燃气体（有毒）5.1,5.13,5.1092(20)31溴乙烯（抑制了的）vinylbromide乙烯基溴CH2CHBr易燃气体5.1,5.10232硫化氢（液化的）hydrogensulfideH2S易燃气体（有毒）5.1,5.13,5.20,5.75,5.103,5.1112(20)A2.2不燃气体（包括助燃气体）表A3序号品名别名分子式（或结构式）主（次）危险性类别危险特性标志1一氧化二氮(压缩的)nitrousoxide氧化亚氮笑气N2O助燃气体（氧化性）5.20,5.102,5.1143(25)2一氧化二氮(液化的)nitrousoxide氧化亚氮笑气N2O5.20,5.102,5.1143一氯二氟甲烷chlorodifluoromethane致冷剂22CHClF2不燃气体5.20,5.7234一氯三氟甲烷monochlorotrifluorom-thane致冷剂13CClF35.205二氧化碳（压缩的）carbondioxide碳（酸）酐CO25.20,5.1036二氧化碳（液化的）carbondioxide碳（酸）酐CO25.20,5.1037六氟化硫sulfurhexafluorideSF6不燃气体5.2038六氟丙烯hexafluoropropylene全氟丙烯CF3CFCF25.2059压缩空气compresedair高压空气助燃气体5.20,5.55,5.59,5.11410空气（液化的）air5.20,5.55,5.59,5.11411氖（压缩的）neonNe不燃气体5.2012氖（液化的）neonNe13氙（压缩的）xenonXe14氙（液化的）xenonXe15氦（压缩的）heliumHe16氦（液化的）helium液氦He17氧（压缩的）oxygen氧气O2助燃气体5.5,5.20,5.59,5.11418氧（液化的）oxygen液氧O219氪（压缩的）kryptonKr不燃气体5.2020氪（液化的）kryptonKr21氮（压缩的）nitrogenN25.20,5.10322氮（液化的）nitrogen液氮N2A2.3有毒气体表A4序号品名别名分子式（或结构式）主（次）危险性类别危险特性标志1二氧化硫（液化的）sulfurdioxide亚硫酸酐SO2有毒气体5.75,5.94,5.107,5.11142二氧化氮（液化的）nitrogendioxide四氧化二氮过氧化氮NO2或N2O4有毒气体（腐蚀性）5.99,5.104,5.107,5.114,5.1154(27)3三氟化氮nitrogentrifluoride氟化氮NF3有毒气体5.49,5.71,5.90,5.99,5.110,5.11544三氟化硼borontrifluoride氟化硼BF35.20,5.75,5.85,5.95,5.103,5.110,65.1115三氯化硼borontrichlorideBCl3有毒气体（腐蚀性）5.71,5.84,5.99,5.97,5.104,5.110,5.1214(27)6四氟化硅silicontetrafluoride氟化硅SiF45.75,5.84,5.94,5.99,5.103,5.1057氟（压缩的）fluorineF25.65,5.75,5.84,5.98,5.104,5.105,5.1158氟化氢（无水）hydrogenfluorideHF5.75,5.95,5.98,5.105,5.111,5.1459氨（液化的，含氨＞50%）ammonia液氨NH3有毒气体5.1,5.13,5.20,5.75,5.94,5.107,5.111410氯（液化的）chlorine液氯Cl25.63,5.75,5.104,5.10711氯化氰（抑制的）cyanogenchloride氰化氯氯甲腈CNCl有毒气体5.75,5.84,5.97,5.101,5.105,5.111412氯甲烷methylchloride甲基氯CH3Cl有毒气体（易燃）5.13,5.66,5.77,5.1024(18)13氰化氢（无水,稳定的）hydrogencyanide氰氢酸（无水）HCN5.12,5.44,5.75,5.103,5.105,5.111,5.9414溴甲烷methylbromide甲基溴CH3Br有毒气体5.13,5.97,5.110,5.111,5.131415碳酰氯carbonylchloride光气COCl3有毒气体（腐蚀性）5.75,5.84,5.93,5.99,5.103,5.105,5.1114(27)16磷化氢phosphine磷化三氢膦PH3有毒气体（易燃）5.7,5.11,5.67,5.72,5.97,5.105,5.111,5.1174(18)A3第3类易燃液体A3