高分子材料表面改性新技术

高分子材料表面改性新技术孙晓宁,王成群(,710048):综述了近年来高分子材料表面改性新技术)))等离子体技术表面改性高分子材料的最新进展运用等离子体技术改变高分子材料的表面性质的方法主要有三类:等离子体处理等离子体聚合和等离子体接枝聚合等离子体技术正以其优越性在高聚物材料表面改性方面得到越来越广泛的应用:等离子体;表面改性;高分子材料:TQ316.6:A:1003-3467(2007)06-0003-04NewTechnologyofPolymerMaterialsSurfaceModificationSUNXiao-ning,WANGCheng-qun(XicanPolytechnicUniversity,Xican710048,China)Abstract:Recentprogressofnewtechnologyofpolymermaterialssurfacemodification,namedplasmatechnologyisreviewed.Therearethreewaysusingplasmatechnologytomodifythesurfacepropertiesofpolymermaterials,whichareplasmasurfacetreatmen,tplasmapolymerizationandplasmagraftcopolymer-ization.Plasmatechnologyhasbeenappliedinpolymermaterialsurfacemodificationmoreandmoreex-tensively.Keywords:plasma;surfacemodification;polymermaterials,,,/0,/0,,,;;(),,;,,,,;,1,,,,,,,:2007-03-15:(2005KW-21):(1964-),,,,,:13572517223#3#6:Guruvenket[1],,ATR-FTIR,,Lai[2]X-(XPS)(SEM),,,,;,CO[3],,,10,,,:¹,;º,;»,Li[4],,,,(Cl/C=0.01)(Cl/C=0.03),,,,,HeO2ArH2,[5],,NH2COOHOHSipehia[6]NH2COOHOH,,(D,L-),NH2,,pH,,,Chu[7],(HuVEC)(RbM-VEC),(Fn)HuVECRbMVEC(Fn)2,:;;;;(CVD),,,,[8-9],;,,,WeiSF6O2,,,CFCCCO,50%[10]#4#HENANCHEMICALINDUSTRY200724,,Jama[11]6(PA6)50Lm,30%,Delattre[12](PPTh),PPThC/S4B1,,PPTh50!,,CF4CH2F2,,Hochart[13](CF4C6F14CF4/H2)(PAN),63b115b,H2Terlingen[14],,,,,,3,:¹:;º:;»:,;¼:,,[15],N-(NIPAAm),,32e,(N-)(PNIPAAm)[16],/,,,,20%~30%,Choi[17],,,,IRXPS,ChoiDPPH,,[18]39.5kJ/mo,l,Gupta[19-20],,Gupta[20],,,,,;,Huh[21],PET-A(QC)PET-A(PET-A-C)(PET-A-QC),,48%~58%,Sun[22],,126b64.8b,,,#5#6:4,,,;,,;,:[1]GuruvenketS,MohanRaoG,ManojKomath,eta.lPlasmasurfacemodificationofpolystyreneandpolyethylene[J].AppliedSurfaceScience,2004,236:278-284.[2]LaiJN,SunderlandB,XueJM,eta.lStudyonhydroph-ilicityofpolymersurfacesimprovedbyplasmatreatment[J].AppliedSurfaceScience,2006,252:3375-3379.[3]刘际伟,高晓敏,冯敏.聚四氟乙烯射频等离子体表面改性研究[J].表面技术,2004,33(1):65-71.[4]LiR,ChenJR.Studiesonwettabilityofmedicalpoly(v-inylchloride)byremoteargonplasma[J].AppliedSur-faceScience,2006,252:5076-5082.[5]任杰,杨爽.生物医用材料)))聚乳酸的表面改性研究进展[J].北京生物医学工程,2004,23(4):299-302.[6]SipehiaR.Theenhancedattachmentandgrowthofendo-thelialcellsonanhydrousammoniagaseousplasmamod-ifiedsurfacesofpolystyreneandpoly(tetrafluoroethylene)[J].Biomat.Art.CellsArt.Org.,1990,18(3):437-443.[7]ChuCF,ZnA,LiszkowskiM,eta.lEnhancedgrowthofanimalandhumanendothelialcellsonbiodegradablepo-lymers[J].Biochim.Biophys.Acta,1999,1472(3):479-485.[8]HamerliP,WeigelT,GrothT,eta.lSurfacepropertiesofandcelladhesionontoallylamine-plasma-coatedpoly-ethylenterephtalatmembranes[J].Biomaterials,2003,24:3989-3999.[9]YiCH,LeeYH,YeomGY.Thestudyofatmosphericpressureplasmaforsurfacecleaning[J].SurfaceandCoatingsTechnology,2003,171:237-240.[10]肖梅,凌一鸣.低温等离子体在材料表面改性中的应用[J].东南大学学报(自然科学版),2001,31(1):114-118.[11]JamaSC,LeBrasM,eta.lNewapproachtoflamere-tardancyusingplasmaassistedsurfacepolymerizationtechniques[J].PolymerDegradationStability,1999,66:153-155.[12]DelattreJL,dA'gostinoR,FracassiF.Plasma-polymer-izedthiophenefilmsforenhancedrubber-steelbonding[J].AppliedSurfaceScience,2006,252:3912-3919.[13]HochartF,Levalois-MitjavilleJ,RogerDJ.Plasmasurfacetreatmentofpoly(acrylonitrile)filmsbyfluoro-carboncompounds[J].AppliedSurfaceScience,1999,142(1-4):574-578.[14]TerlingenGA.Introductionoffunctionalgroupsonpoly-ethylenesurfacebyacarbondioxideplasmatreatment[J].AppliedSurfaceScience,1995,57(8):969-982.[15]黄健,王晓琳,陈秀珍,等.高分子微滤膜等离子体处理接枝N-异丙基丙烯酰胺[J].高分子材料科学与工程,2003,19(4):48-51.[16]许海燕,孔桦,杨子彬,等.利用等离子体表面接枝技术提高医用聚氨酯血液相容性的研究[J].中国生物医学工程学报,2003,22(6):533-536.[17]ChoiHS,KimYS,ZhangY.Plasma-inducedgraftco-polymerizationofacrylicacidontothepolyurethanesurface[J].SurfaceandCoatingsTechnology,2004,182:55-64.[18]InagakiN,TasakaS,GotoY.Surfacemodificationofpoly(tetrafluoro-ethylene)filmbyplasmagraftpolymeriza-tionofsodiumvinylsulfonate[J].JournalofAppliedPo-lymerScience,1997,66:77-84.[19]GuptaB,HilbornJG,BissonI,eta.lPlasma-inducedgraftpolymerizationofacrylicacidontopoly(ethyleneterephthalate)films[J].JournalofAppliedPolymerSc-ience,2001,81:2993-3001.[20]GuptaB,PlummeraC,BissonI,eta.lPlasma-inducedgraftpolymerizationofacrylicacidontopoly(ethyleneterephthalate)films:characterizationandhumansmoothmusclecellgrowthongraftedfilms[J].Biomaterials,2002,23:863-871.[21]HuhMW,KangIK,LeeDH,eta.lSurfacecharacter-izationandantibacterialactivityofchitosan-graftedpo-ly(ethyleneterephthalate)preparedbyplasmaglowdis-charge[J].JournalofAppliedPolymerScience,2001,81:2769-2778.[22]SunHX,ZhangL,ChaiH,eta.lSurfacemodificationofpoly(tetrafluoro-ethylene)filmsviaplasmatreatmentandgraftcopolymerizationofacrylicacid[J].Desalina-tion,2006,192:271-279.#6#HENANCHEMICALINDUSTRY200724