1染料废水物理化学处理技术的现状与进展

:2003204216:(1976-),,,2001,(,400044):Fenton.:;;:X703:A:100123644(2003)0620025205TechnicalProgressinDyeWastewaterTreatmentLIANGZhi2rong(SchoolofResourcesandEnvironmentalScience,ChongqingUniversity,Chongqing400044,China)Abstract:Thepaperreviewsthetechnicalprogressindyewastewatertreatmentbyphysicalandchemicalmethod,includingadsorp2tion,membranefiltration,coagulation,oxidativereagent,ionexchange,fentonreagent,photocatalyticoxidation,wetoxidation,andelectrochemistry,andthenpointsoutitsdevelopmenttrends.Keywords:Dyewastewater;physicalandchemicalmethod;treatmenttechnology1,,,,,[1],,,.2211,[2],,pH[3,4]21111,,COD,BOD[4][3]ZnCl220pH=4115140mg/g,pH,pH,Kannan[5],95%,,,20%,Raghavacharya[6],,,10%15%,,,21112.[7]522003226,,,[8],,,,pHDogan[9],,pH,Meshk[10],,LangmuirFreundlichAlqo2dah[11],(two-resistancemasstransfer)[12]21113,,[13][14],H2O295%,[15]21114Netpradit[16],,,90%,Ramakrishna[17]90%,49%Stephen[18]2122,,,Rajeshwari[19],1787%,LangmuirFreundlich,pH=61319188mg/g[20],,,212,,,pHAkbari[21](NF)80,8100%,,,011g/L497%,014Mpa01230128m3/m2d,pH[22].Katarzyna[23](UF),012Mp,,3311,,,[24],,(PAC)(PFS)[25](PAN)(DCD),Chu[26]88%,[27],,Fe3+,Fe(OH)3,COD60%[28](CCS)6G97%,[29],-,MG,85%[30]PSAFC,COD,,312O3,O3,,(UV)622003226Shu[31]O3/UV,UVO3.[32],I,O3,O37107mg/L,80wO3,90%,48%O3O3,,[33]Wu[34]O3O3,KZG,,90%,O3,UVO3,O3COD313,[35]PVAF,186mg/g80%,BanghamSilke[36]S6328aMP62,,,,,,314FentonFentonH2O2FeSO4,,UVFenton,pH3,H2O2Fe2+Shyh-Fang[37]FentonCOD,COD,,95%1[Fe2+]=014mmol/L,[H2O2]=0144mmol/L,[]=012mmol/L,160minTOC100%,UVFe2+H2O2[38].[39],Fenton,[Fe2+]=5mmol/L,[H2O2]=50mmol/L,[]=150mg/L,4,2.Lin[40]Fenton,,,,[41].315,TiO2,TiO2[42]4BS,,,;(TiO2-Fe2O3,TiO2-WO3)TiO2,,Tang[43],TiO2,,Langmuir-Hinshelwood,,TiO2,316,(WAO),,[44],(CWAO),H2O2(WPO)TOCCOD80%,90%,H2O2pH,[45](CWO),A1Cu,:A1CuH2O2317,[46],95%COD40%70%,[47],90%,COD72200322610%,pH.[48],,;,[49],99%,COD7814%9712%.,,,,.,COD[50,51],Grsesa[52],,,Xueming[53],Ti/BTi/Sb2O5-Sn2O2,pH,=100A/m2,5110%9012%,8191719Kwh/m3,COD4021120mg/L893mg/L:[1],1[J]1,2000,20(1):142181[2]SlokarYM,LeMarechalAM1Methodsofdecolorationoftextilewastewaters[J].DyesandPigments,1998,37(4):3352356.[3],,.Zeta[J]1,1994,14(2):252311[4],.[M].:,2002.16621711[5]KannanN,SundaramMM1Kineticsandmechanismofremovalofmethylenebluebyadsorptiononvariouscarbonsuacomparativestudy[J]1DyesandPigments,2001,51(1):252401[6]RaghavacharyaC1Colourremova1fromindustrialeffluents2comp2ara2tivereviewofavailab1etechnologies[J]1Chem1Eng1Wor1d,1997,32(7):532541[7],1[J]1,1995,8(2):732771[8],,1[J].,1998,14(4):729.[9]DoganM,AlkanM1Adsorptionkineticsofmethylvioletontoperlite[J]1Chemosphere,2003,50(4):5172528.[10]MeshkoV,MarkovskaL,MinchevaM,etal1Adsorptionofbasicdyesongranularactivatedcarbonandnaturalzeolite[J]1Wat1Res1,2001,35(14):335723366.[11]Al-QodahZ1Adsorptionofdyesusingshaleoilash[J]1Wat1Res.,2000,34(17):429524303.[12]SudamKP,BayKM1Adsorptionofstyrylpyridiniumdyesonsili2cagel[J]1Journalofcolloidandinterfacescience,1996,182(2):47324771[13],1-[J]1,1997,17(3):362371[14],,1[J]1,2000,10(3):132161[15],,,.--[J]1,2000,21(3):622711[16]NetpraditS,ThiravetyanP,TowprayoonS1Applicationofwastemetalhydroxidesludgeforadsorptionofazoreactivedyes[J].Wat1Res1,2003,37(4):76327721[17]RamakrishnaKR,ViraraghavanT1Useofslagfordyeremoval[J]1WasteManagement,1997,17(8):48324881[18]StephenJA,QuanG,RonanM,etal1Comparisonofoptimisedis2othermmodelsforbasicdyeadsorptionbykudzu[J]1BioresourceTechnology,2003,88(2):14321521[19]SivarajR,NamasivayamC,KadirveluK1OrangepeelasanadsorbentintheremovalofAcidviolet17(aciddye)fromaqueoussolutions[J]1WasteManagement,2001,21(1):10521101[20]RobinsonT,ChandranB,NigamWaterP1Removalofdyesfromasynthetictextiledyeeffluentbybiosorptiononapplepomaceandwheatstraw[J]1Wat1Res.,2002,36(11):2824228301[21]AkbariA,RemigyJC,AptelP1Treatmentoftextiledyeeffluentus2ingapolyamidebasednanofiltrationmembrane[J].ChemicalEngi2neeringandProcessing,2002,41(7):60126091[22]AkbariA,DesclauxS,RemigyJC,etal1Treatmentoftextiledyeef2fluentsusinganewphotograftednanofiltrationmembrane[J].Desali2nation,2002,149(1):10121071[23]KatarzynaMN,MalgorzataKK,TomaszW1Salteffectondyesepa2rationbyhydrophilicmembranes[J]1Desalination,1996,108(13):22122291[24],,,.[J]1,1999,19(4):282461[25],,,.[J]1(),1999,32(3):14021451[26]ChuW1Dyeremovalfromtextiledyewastewaterusingrecycledalumsludge[J]1Wat1Res1,2001,35(13):3147231521[27].[J]1(),2002,18(3):542571[28],1[J]1,2001,18(3):13321361[29],,,.[J]1,1990,11(5):252291[30],1PSAFC[J]1,2001,21(6):202231[31]ShuHung2Yee,HuangChing2Rong1DegradationofcommercialazodyeinwaterusingozonationandUVenhancedozonationprocess[J]1Chemosphere,1995,31(8):3813238251[32],,1822003226[J]1,1999,15(11):1241[33]InceNH,TezcanlG1Reactivedyestuffdegradationbycombinedsonolysisandozonation[J]1DyesandPigments,2001,49(3):14521531[34]WuJiang2Ning,WangTing2Wei1Ozonationofaqueousazodyeinasemi2batchreactor[J]1Wat1Res.,2001,35(4):1093210991[35],1PVAF[J]1,1997,12(4):9213.[36]KarcherS,KornmllerA,JekelM1Anionexchangeresinsforremovalofreactivedyesfromtextilewastewaters[J]1Wat1Res.,2002,36(19):4717247241[37]KangSh