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2013-07-031981—。18030083398E-mail379299412@qq.com。Fenton361001-、-、-、-、/-、。TU992B1009-0177201401-0025-05ApplicationofFentonReagentinOrganicWastewaterTreatmentSunYanhuiZhangQingJiChangqingZijinMiningandMetallurgyTechnologyCo.Ltd.Xiamen361001ChinaAbstractTheapplicationandmechanismoftraditionalFentonreagentinthefieldofwatertreatmentwereintroduced.SeveralFentonreagenttypesuchasPhoto-FentonElectro-FentonUltrasonic-FentonUltrasonic-FentonMicrowave-FentonAdsorption-FentonandFlocculation-Fentonreagentsweresummarized.Thecharacteristicsofeachmethodresearchandapplicationconditionsweredescribedindetail.TheresearchdirectionandthedevelopmentofFentonreagentswereprospected.KeywordsFentonreagentFenton-likereagentwastewatertreatmentapplicationFentonFenton12。、、、、FentonFentonFentonFenton。1FentonH2O2Fe2+H2O2OH·CO2H2OFe2++H2O→2Fe3++OH-+OH·1R—H+OH→·R·+H2O2R·+Fe→3+Fe2++products3、30Fenton。pH、、H2O2Fe2+3。H2O2Fe2+。H2O2Fe2+H2O2Fe2+。2FentonFentonFe2+/H2O2。。Chamarro4-9Fenton、、4-、24-、PAHs、、、—52—WATERPURIFICATIONTECHNOLOGYVol.33No.12014February25th201420143312529WaterPurificationTechnologyH2O2、Fe2+/H2O2CODCr。125mg/L99.5%CODCr67.9%70%CODCrDB32/1072—2007。H2O2Fe2+pHFenton。。3FentonFentonFentonFenton。FentonFenton-Fenton、-Fenton、-Fenton、-Fenton、/-Fenton。3.1-Fenton-Fenton10Fe2+H2O2Fe2+H2O2。-Fenton11-13HMXFenton。Fenton。。TiO2TiO2TiO2、。14TiO2300W-Fenton。CODCr50%75%。FeⅢFeⅢ。UV/Fenton。15UV/FeC2O43-3/H2O2。30~40mg/L99%Fenton94.6%UV/FeC2O43-379.9%。16、。-FentonFenton。。3.2-Fenton-FentonFentonFe2+H2O2Fenton。H2O2Fenton、、-H2O2Fenton17。-FentonH2O2H2O2。·OH、。-Fenton4-Fenton、、FSREF-Fere。2080-Fenton。H2O2Fe2+H2O2。Bermond18H2O2H2O2Fe2+Fenton。Do19-Fenton—62—.FentonVol.33No.12014H2O2。、H2O2。Alvarez-Gallegos20H2O2O2H2O2H2O2。21-FentonFenton-FentonCOD68%Fenton12%。-FentonFenton。-Fenton-Fenton。22-FentonCOD58%0.080.3623-FentonCOD87%。BOD5/CODCr0.30.5。24-Fenton、Fenton、-Fenton、-Fenton-FentonCOD60%0.8。-Fenton-Fenton-Fenton。-FentonH2O2H2O2Fe2+。H2O2Fenton-Fenton。3.3-Fentonultrasonic、、———。>5000K、>5×107Pa、、。。Fenton。-Fenton25COD、US/FentonFenton。-Fenton、Fenton26CODCr100mg/LGB8978—1996。27、Fenton、US-FentonX-3B5%45%90%BOD5/CODCrUS-Fenton。US-Fenton、pH、FeSO4H2O2X-3B。Fenton。Fenton。3.4-Fenton—72—WATERPURIFICATIONTECHNOLOGYVol.33No.12014February25th2014。-Fenton。28Fenton。29Fenton-。600W2910mL/L。3.5/-Fenton。Fenton。-Fenton。3031Fenton。32Fenton。Fenton。33-Fenton124-。COD17511mg/L605.2mg/L。COD96.5%、、、。FentonH2O230%1.5g/LH2O2Fe2+5~15pH6~8、0.5g/m3CODCr500mg/L50mg/L。42060Fenton、。、FentonFenton-Fenton、-Fenton、-Fenton、-Fenton、/-FentonFenton、。Fenton-Fenton、-Fenton、-Fenton-Fenton。、。H2O2FentonFenton、、。FentonFenton。1.FentonJ.200524351-54.2.FentonMC-LRJ.—82—.FentonVol.33No.1201420085221-24.3LinSH.LinCM.OperatingcharacteristicsandkineticstudiesofsurfactantwastewatertreatmentbyFentonoxidationJ.WaterRes.19993371735-1741.4ChamarroEMarcoAEsplugasS.UseofreagenttoimproveorganicchemicalbiodegradabnityJ.WaterRes.20013541047-105l.5.FentonPAHSJ.2008342-45.6.FentonJ.20067660-64.7.FentonJ.2010219-21.8.FentonJ.20052869-11.9.FentonJ.20066175-76.10EstherOliveros.Industrialwastewatertreatmentlargescaledevelopmentofalight-enhancedFentonreactionJ.ChemicalEngineeringandProcessing199736397-405.11.FentonJ.2004913-15.12.FentonHMXJ.2008220-23.13.UV-FentonJ.2008241358-61.14.-FentonJ.200316425-28.15.UV/FeC2O433/H2OJ.199932348-51.16JeanJacquesMehmetA.OTURAN.NewPhotochemicalandElectrochemicalMethodsfortheDegradationofPesticidesinAqueousmedia.EnvironmentalApplicationsJ.TurkJChem200125509-520.17Yao-HuiHShan-ShanCMing-GingPetal.Casestudyonthebioeffiuentofpetrochemicalwastewaterbyelectro-FentonmethodJ.Wat.Sci.Technol.19993910-11145-149.18VenturaAJacquetGBermondAetal.ElectrochemicalGenerationoftheFenton'sReagentApplicationtoTrazineDegradationJ.WaterResearch200236113517-3522.19DoJSYehWC.PairedeleetrooxidativedegradationofphenolwithinsituelectrogenratedhydrogenperoxideandhypoehloriteJ.J.Appl.Eleetroehem.199626673-678.20Alvarez-GallegosAPleteherD.Theremovaloflow-levelorganicsviahydrogenperoxideformedinareticulatedvitreouscarboncathodecellPart1.TheelectrosynthesisofhydrogenperoxideinaqueousacidicsolutionsJ.Electroehim.Aeta199844853-861.21.FentonJ.20081189107-108.22.FentonJ.201134163-65.23.-FentonJ.2008312192-195.24.-FentonD.2007.25.US/FentonJ.2007105893-95.26.、FentonJ.2006287508-511.27.-FentonD.2007.28.FentonJ.200533125-9.29.Fenton-J.200518422-25.30.FentonTHMFPJ.200410136-40.31.-FentonJ.200816210-12.32.FentonJ.200831382-85.33.-Fenton124-J.200828724-26.—92—WATERPURIFICATIONTECHNOLOGYVol.33No.12014February25th2014
本文标题:Fenton试剂在有机废水处理中的应用孙艳慧
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