MBR工艺在废水处理中的研究与应用进展

20151642306·123·MBR*(150040)[](MBR)MBRMBR[]MBR[]X703[]A[]1007-1865(2015)16-0123-02ProcessinResearchandApplicationofMBRinWastewaterTreatmentLiangQianwei,ChengGuoling*,KongWeipeng,LiYongfeng(SchoolofForestryNortheastForestryUniversity,Harbin150040,China)Abstract:Membranebioreactor(MBR)isakindofnewandhighlyefficientwastewatertreatmenttechnology,whichproducedbycombiningofmembranetechnologyandbiologicalsewagetreatmenttechnologyandapplicationofMBRindomesticsewage,industrialwastewaterandwaterreusehasbeenincreasinglyobvious.Themaintypes,thecharacteristics,membranematerialsandcomponenttypesofMBRareintroduced,andtheresearchstatusofMBRtechnologyathomeandabroadisanalyzed,theproblemsofprocessintheapplicationarefocusedonandsomesuggestionsandmeasuresofcontrollingmembranefoulingareputforward,andthegooddevelopmentprospectisforecasted.Keywords:MBRwastewatertreatmentmembranefoulingresearchstatus(MembranebioreactorMBR)MBR[1,2]MBRMBR[3-5]1MBR1.1MBRMBRMBR(HRT)(SRT)1.2MBR11MBRTab.1ClassificationofMBR1.31.3.1MBR[6,7](1)MBR(2)MBR(3)(4)(5)(6)1.3.2MBR[8,9](1)30%~50%(2)(3)(4)522.11966Dorr-Oliver1969Smith[10]MBR2070MBR2070MBR2080MBRMBR1983~198713MBR198590MBR[11-14]2090MBRMBRMBRMansfield[15]MBR10%[16]MBR2011913.6m3/d204020.4m3/d[17]MBR2.2MBR[]2015-06-02[](E201354)[](1991-)*201516·124·[18]MBRMBR19921994MBR863MBRMBR[3,19-21]MBR201350MBR230/MBR2015MBR500/2MBR2MBRTab.2SomeMBRengineeringinChina/(m3·d-1)450002006600002007310002006200002009250002006100020052000200750020122MBR33.13.1.1[22]MBR3.1.2(1)(EPS)EPSEPS[23](2)(SMP)SMP(3)MBRSRT3.2(1)(2)(3)[24](4)[25]3.3MBRMBR(1)(2)MBR(3)MBR4MBRMBR[1][J]200531(5)7-1026[2]MBR[J]201440(6)90-92[3]-[J]200828(3)416-432[4]LiJYuDSZhangPYComparisonbetweenMBRandA/Oprocessestreatingsalinewastewater[J]DesalinationandWaterTreatment201351(19-21)3821-3825[5]ZhangHFImpactofsolublemicrobialproductsandextracellularpolymericsubstancesonfiltrationresistanceinamembranebioreactor[J]EnvironmentalEngineeringScience200926(6)1115-1122[6][J]200525(1)10-13[7]MBR[J]200414(2)34-38[8]JangDHwangYShinHetalEffectsofsalinityonthecharacteristicsofbiomassandmembranefoulinginmembranebioreactors[J]BioresourTechnol2013141(1)50-56[9]MelinTJeffersonDBixioDetalMembranebioreactortechnologyforwastewatertreatmentandreuse[J]Desalination2006187(1/2/3)271-282[10]SmithCVGregorioDDTalcottRMTheuseofultrafiltrationMembraneforactivatedsludgeseparation[C]Proc24rdIndWasteConfPurdueUniversityAnnArborScienceUSA19691300-1310[11]LiXYWangXMModelingofmembranefoulinginasubmergedmembranebioreactor[J]Desalination2006278(1)151-161[12]NoorSabrinaAhmadMutamimZainuraZainonNoorMohdAriffinAbuHassanMembranebioreactorApplicationsandlimitationsintreatinghighstrengthindustrialwastewater[J]ChemicalEngineeringJournal2013225109-119[13]JinLeNgHowYongOngSayLeongPerformanceandfoulingcharacteristicsofdifferentpore-sizedsubmergedceramicmembranebioreactors(SCMBR)[J]WaterScienceandTechnology200959(11)2213-2218[14]TorOveLeiknesHeidiBoltMartinEngmannAssessmentofmembranereactordesignintheperformanceofahybridbiofilmmembranebioreactor(BF-MBR)[J]Eurombrane200620(10)24-28(79)20151642306·79·2003004005006007000.000.050.100.150.200.250.300.350.400.450.5023456780.100.120.140.160.180.20AbsorbanceNumberofDAR/CoTsPcbilayers(a)(b)(c)(d)AbsorbanceWavelength/nm380nm2DAR/CoTsPcUV-VisTab.2DAR/CoTsPcmultilayerUV-Visabsorptionspectra2.32.3.1I-pHpHpH2.5~6.0I-pH1.56543210-50-100-150-200-250-300E/mV-LogC3Tab.3Thestandardworkingcurveofthepotentialresponse334.7×10-6~0.1mol/L58.8mV/decade3.5×10-6mol/L2.3.2(pH=4.60.1mol/L)1.5%-6058.8mV/decade58.0mV/decade101.4%3(0.1mol/L)4.7×10-6~0.1mol/L3.5×10-6mol/L58.8mV/decade[1]NishiharaHAsaiHKramakiJChemSocFaradayTrans1991871771[2]WrightonMSScience198623132[3]MurrayRWEwingAGDurstRAAnalChem198759379A[4]EspenscheidMWGhatak-RoyARBIIIRetalJChemSocFaradayTrans1986821051[5]StoeckerPWYacynychAMSelectiveElectrodeRev199012137[6]FujihiraMTopicsinOrganicElectrochemistry(FryAJBrittonWEEds)PlenumNewYorkandLondonP1986255[7]MerzATopicsinCurrentChemistryinElectrochemistry(ESteckhamEd)BerlinSpringer-Verlag199015249[8]DegrandCRomeAnnChim1985751[9]GortonLJChemSocFaradayTransI198682124[10]LunteCEHeinemannWRTopicsinCurrentChemistryinElectrochemistrryII(ESteckhamEd)BerlinSpringer-Verlag19851431[11]DongSWangYElectroanalysis1989199(124)[15]PMSuttonMembranebioreactorforindustrialwastewatertreatmentapplicabilityandselectionofoptimalsystemconfiguration[J]WaterEnvironFound20063222-3248[16]PBerrubeMembranebioreactortheoryandapplicationstowastewaterreuse[J]SustainabilitySciEng2009(2)255-292[17]WYangNCicekJIlgStateoftheartofmembranebioreactorsworldwideresearchandcommercialapplicationinnorthAmerica[J]JMembrSci2006(270)201-211[18][J]199117(5)39-44[19][J]201542(2)67-7075[20]MBR[J]201441(12)168-170[21][J]201231(12)2791-2796[22]-[J]201435(2)643-650[23][J]200928(8)1473-14771484[24]AHL-QS[J]201433(5)1300-1305[25]-[J]201332(2)453-459