MBR中微生物代谢产物对膜污染的影响及其调控方法的研究进展

334Vol．33No．420138JournalOfNortheastDianliUniversityAug．20132013－01－14201204042012324032010630620091974－．1005－2992201304－0001－05MBＲ张海丰，刘洪鹏，赵贵龙，张德义132012Membranebio-reactorMBＲMBＲ。PAC、。、。X703．3AMBＲ、、41。MBＲ。MBＲ2。Extracellularpolymericsub-stancesEPS、solublemicrobialproductsSMPEPS3。MBＲMBＲ。1、、4。SMPSMPEPS。EPSSMP90%5。1．1SMP0．45umsolublemicrobialproductsSMPSMP、、。SMP、。、SMP2。SMP630%1kDa25%100kDaSMP。7SMPSMPSMPSMP8。Huang9MBＲSMP10kDaSMP。1．2EPSExtracellularpolymericsubstancesEPS—10。EPSTightlyboundEPSTBLooselyboundEPSLB11EPS、、、12。1335EPSEPSSVI。/SVI。Nagaoka14EPSGao15EPSEPS。Ahmed16EPSＲosenbergerYamato1718EPS。EPS192021。EPSEPS。Laspidou22solubleEPSSMPboundEPSUAPboundEPSBAPAquino23SMP。24EPS1EPS2EPSEPSpEPSc3EPS1EPSTBLB1。“”25MBＲ。22．1PAC。PACSMPEPS、、、。PAC1SMPEPS2东北电力大学学报第33卷2SMPEPSSVI34。PAC。26PACPACPACAkramStuckey27PAC。1PACPACmg/l450↓↓V．Iversenetal500↑SMP↓↓M．Ｒemyetal750－1500EPS↓↓↓Z．Yingetal．1000EPS↓↓↓↓M．Pirbazarietal．2000↓↑EPS↓SMP↓TMP↓↓↓↓2000↑SMPEPS/↑↓Y．Satyawali0－3000EPS↓DOCSMP↓↑TMP↓↓1PAC1000mg/lEPS2000mg/l。PACPACSMPEPSPAC、BAC。PAC28。2．2/。I。。FeCl3ferricchloride、Fe2SO43·nH2Oferricsulfate、Al2SO43·nH2Oaluminumsulfate。II。PFS、PAC。Ⅲ。PAMchitosan。SMPEPS。29MBＲSMP80%30MBＲ、SMP、、。EPS。31EPS32EPS33Al2SO43·18H2OAS、PAM、PFSEPS。EPS。3第4期张海丰等:MBＲ中微生物代谢产物对膜污染的影响及其调控方法的研究进展2．3。34、、HMWLMWSun350．18mg/mgTOCMBＲ70%“”。Wu36MBＲEPSZeta。EPS37。3MBＲMBＲ。1MBＲFISH、PCＲ-DGGE2、、、pH3MBＲ、38。MBＲ。1．MBＲJ．20103075－7．2．D．2008．3KimuraKYamatoNYamamuraHetal．Membranefoulinginpilot-scalemembranebioreactorsMBＲstreatingmunicipalwastewaterJ．Environ．Sci．Technol．200539166293－6299．4．D．2007．5JiJQiuJWongFetal．EnhancementoffilterabilityinMBＲachievedbyimprovementofsupernatantandfloccharacteristicsviafilteraidsadditionJ．WaterＲes．200842143611－3622．6ZhangHSSunBSZhaoXHetal．EffectofferricchlorideonfoulinginmembranebioreactorJ．Sep．Purif．Technol．2008632341－347．7．SMPD．2007．8．J．200829182－86．9HuangXLiuＲQianY．BehaviourofsolublemicrobialproductsinamembranebioreactorJ．ProcessBiochem．2000365401－406．10MorganJWForsterCFEvisonLM．AcomparativestudyofthenatureofbiopolymersextractedfromanaerobicandactivatedsludgesJ．WaterＲes．1990246743－750．11WingenderJNeuburgerTＲFlemmingHC．MicrobialextracellularpolymericsubstancescharacterizationstructureandfunctionM．Ber-linSpringer1999．12WilénBMJinBLantP．TheinfluenceofkeychemicalconstituentsinactivatedsludgeonsurfaceandflocculatingpropertiesJ．WaterＲes．20033792127－2139．13．MBＲJ．2009284539－542．14NagaokaHUedaSMiyaA．InfluenceofbacterialextracellularpolymersonthemembraneseparationactivatedsludgeprocessJ．WaterSci．Tech．1996349165－172．15GaoMCYangMLiHYetal．Nitrificationandsludgecharacteristicsinasubmergedmembranebioreactoronsyntheticinorganic4东北电力大学学报第33卷wastewaterJ．Desalination20041702177－185．16AhmedZChoJLimBＲ．EffectsofsludgeretentiontimeonmembranefoulingandmicrobialcommunitystructureinamembranebioreactorJ．J．Membr．Sci．20072872211－218．17ＲosenbergerSKraumeM．FilterabilityofactivatedsludgeinmembranebioreactorsJ．Desalination20031512195－200．18NobuhiroYamatoKatsukiKimuraTaroMiyoshi．DifferenceinmembranefoulinginmembranebioreactorsMBＲscausedbymembranepolymermaterialsJ．J．Membr．Sci20062801－2911－919．19．－D．2000．20KimJSLeeCHChangIS．EffectofpumpshearontheperformanceofacrossflowmembranebioreactorJ．Wat．Ｒes．20013592137－2144．21MikkelsenLH．TheshearsensitivityofactivatedsludgerelationstofilterabilitytheologyandsurfacechemistryJ．ColloidsSurf．A20011821－31－14．22LaspidouCSＲittmannBE．AunifiedtheoryforextracellularpolymericsubstancessolublemicrobialproductsandactiveandinertbiomassJ．WaterＲes．200236112711－2720．23AquinoSFStuckeyDC．SolublemicrobialproductsformationinanaerobicchemostatsinthepresenceoftoxiccompoundsJ．WaterＲes．2004382255－266．24．J．201029112171－2175．25LeClechPChenVFaneTAG．FoulinginmembranebioreactorsusedinwastewatertreatmentJ．J．Membr．Sci．20062841－217－53．26．－J．200525111443－1447．27AkramAStuckeyDC．FluxandperformanceimprovementinasubmergedanaerobicmembranebioreactorSAMBＲusingpowderedacti-vatedcarbonPACJ．ProcessBiochem．200843193－102．28SatyawaliYBalaknM．PerformanceenhancementwithpowderedactivatedcarbonPACadditioninamembranebioreactorMBＲtrea-tingdistilleryeffluentJ．J．Hazard．Mater．20091701457－465．29．MBＲJ．201030631－35．30．MBＲJ．20092523121－125．31．J．200834z2181－184．32．MBＲD．2011．33．D．2011．34．J．200026227－31．36WuJHuangX．Useofozonationtomitigatefoulinginalong-termmembranebioreactorJ．Bioresour．Technol．2010101156019－6027．37．－J．2006264427－431．38Kasprzyk-HordernBZiólekMNawrockiJ．CatalyticozonationandmethodsofenhancingmolecularozonereactionsinwatertreatmentJ．Appl．Catal．BEnviron．2003464639－669．ＲesearchProgressoftheInfluenceofMicrobialMetabolitesonMembraneFoulingandItsControlMethodsinMembraneBioreactorZHANGHai-fengLIUHong-pengZHAOGui-longZHANGDe-yiSchoolofChemicalEngineeringNortheastDianliUniversityJilinJilin132012AbstractThemembranebioreactorMBＲasanefficientandpracticalnewwastewatertreatmentandreusetechnologyhasreceivedextensivetheoreticalresearchandengineeringapplicationsforyears．HoweverMem-branefoulingisamajorobstaclethathindersfastercommercializationofMBＲ．Thearticleanalysedemphati-callytheimpactofmicrobialmetabolitesonmembrane