变性淀粉在工业水处理技术中的应用范庆松

2009年10月　　　　　　　　　　　　　　　　　云南化工　　　　　　　　　　　　　　　　　　Oct.2009　第36卷第5期　　　　　　　　　　　　YunnanChemicalTechnology　　　　　　　　　　　　　　Vol.36,No.5　范庆松,田　丰,殷冬媛(,100011):2009-07-17　　　　:2009-09-30:(2008-KZ-D02)。:(1979-),,,,。　:　,、。:　;;:　TQ314.1　　:　A　　:　1004-275X(2009)05-0052-04　　,,、、,,,,,。,,,,,。1　2070,、、、,、、,,。,,,。,,,。,、、、。、、。1.1　,,-,pH,,,,,,。(、)。[1]-,,Hg2+。,、,。,,,Zeta,2×10-6Zeta,。1.2　,,,,。,、。、、、、,,,。、。[2],,:0.2%,pH7～10,24。1.3　,、、,。,、,,。,,。[3-8],。,,,,。(PAM),,。1.4　、、pH,。、,,,、。,,,,COD、BOD;,,。,、,,,,。、,。Cald-wellC.C[6],(0.02～0.050);[7,8],3--2-、,,、,、。2　、、,。,,。、、、、。2.1　、。、,、。、,。Chan[9-11]、[9-11],,Langmuir。Xu[12-15]Pb(Ⅱ)、Cu(Ⅱ)、Cr(Ⅵ)、Zn(Ⅱ),,。2.2　,。、、。·53·　2009年第5期　　　　　　　　　　　　范庆松等:变性淀粉在工业水处理技术中的应用KimLim[16]POCl3,DS0.02～0.08,,,。[17]Cr(Ⅲ)、Al(Ⅲ),。[18],、,4mmol/g。Kweon[19],,,,Langmuir。2.3　Cr(Ⅵ),。Xu[20]Cr(Ⅵ),,,Langmuir。2.4　、,。Para[21]30%,。Khalil[22],,,。[23]Li[24]Cu(Ⅱ),Freundlich。2.5　。Zhang[25]Cu(Ⅱ)Pb(Ⅱ),,2h,Langmuir;60%,LangmuirPb(Ⅱ)2.09mmol/g,Cu(Ⅱ)2.12mmol/g。Khalil[26],,。[27]Cr(Ⅲ)Cd(Ⅱ)pH,。3　,,,。,,,,,。,。,,,、、。,,。:[1]　,.APS-Na2S2O3[J].,1994,11(2):48-51.[2]　,,.[J].,2000,(4):47-48.[3]　,,[J]..2009,1(33):127-135.[4]　,,.[J]..2000,1:3-15.[5]　,,,.[J]..2007,5(22):111-114.[6]　CaldwellCG.Methodofmakingpapercontainingstarchderiv-bativeshavingbothanionicandcationicgroupsandtheproductproducedthereby.NationalstarchandchemicalCorporation,NewYork,USP3,459,63.1969-8-5:3-5.[7]　.[J].,1996,29(2):265-272.[8]　.[J].,1996,9(3):468-474.[9]　ChanWC.Removalandrecoveryofgalliumionfromsolutionbyinsolubleamphotericstarches[J].JournalofAppliedPolymerScience,1993,50:1733-1738.[10]　ChanWC.Indiumionremovelandrecoverybymeansofwater-insolubleamphotericstarches[J].DieAngewandteMakro-molekulareChemie,1993,213:81-92.[11]　ChanWC.Removalofheavymetalionswithwater-insolubleamphotericsodiumtertiaryaminesulfonatestarches[J].Journal·54·云南化工　　　　　　　　　　　　　　　　　2009年第5期　ofPolymerResearch,1994,1(2):221-226.[12]　XuSM,FengS,PengGetal.RemovalofPb(II)bycrosslinkedamphotericstarchcontainingthecarboxymethylgroup[J].Carbohydratepolymers,2005,60:301-305.[13]　XuSM,FengS,YueF,etal.AdsorptionofCu(II)Ionsfromanaqueoussolutionbycrosslinkedamphotericstarch[J].Jour-nalofappliedpolymerscience,2004,92:728-732.[14]　XuSM,ZhangSF,LuRW,etal.Studyonadsorptionbe-haviorbetweenCr(VI)andcrosslinkedamphotericstarch[J].Journalofappliedpolymerscience,2003,89:263-267.[15]　CaoLQ,XuSM,FengS,etal.AdsorptionofZn(Ⅱ)Ionontocrosslinkedamphotericstarchinaqueoussolutions[J].JournalofPolymerResearch,2004,11:105-108.[16]　KimBS,LimST.Removalofheavymetalionsfromwaterbycross-linkedcarboxymethylcornstarch[J].Carbohydratepol-ymer,1999,39:217-223.[17]　,,.[J].,2000,26(4):222-227.[18]　,,,.[J].,2001,17(5):341-345.[19]　KweonDK,ChoiJK,KimEK,etal.Adsorptionofdivalentmetalionsbysuccinylatedandoxidizedcornstarches.Carbo-hydratePolymers,2001,46(2):171-177.[20]　XuSM,WeiJ,FengS,etal.Astudyintheadsorptionbe-haviorsofCr(Ⅵ)oncrosslinkedcationicstarches[J].JPolymRes,2004,11:211-215.[21]　ParaA.Complexationofmetalionswithdioximeofdialdehydestarch[J].CarbohydratePolymers,2004,57:277-283.[22]　KhalilMI,Abdel-HalimMG.Preparationofsomestarch-basedneutralchelatingagents[J].CarbohydrateResearch,2000,324:189-199.[23]　,,.[J].,2004,23(2):193-197.[24]　LiYJ,XiangB,NiYM.RemovalofCu(II)fromaqueoussolutionsbychelatingstarchderivatives[J].JournalofAppliedPolymerScience,2004,92:3881-3885.[25]　ZhangLM,ChenDQ.Aninvestigationofadsorptionoflead(Ⅱ)andcopper(Ⅱ)ionsbywater-insolublestarchgraftco-polymers[J].ColloidsandsurfacesA:physicochemicalandengineeringaspects,2002,205:231-236.[26]　KhalilMI,Abdel-HalimMG.Preparationofanionicstarchcontainingcarboxylgroupsanditsutilizationaschelatingagent[J].Starch/Sta¨rke,2001,53:35-41.[27]　,,.ISC[J].,2003,29(3):177-179.ApplicationofModifiedStarchinIndustrialWaterTreatmentFANQing-song,TIANFeng,YINDong-yuan(CentralResearchInstituteofChinaChemicalScienceandTechnology,Beijing100011,China)Abstract:　Theapplicationofmodifiedstarchinindustrialwatertreatmentisreviewedinthispaper.Differentkindsofwatertreatmentproductsbasedonthemodifiedstarch,theirpropertiesaswellascomparisonbetweenthemodifiedstarchandreplaceabletraditionalproductsarelisted.Keywords:　modifiedstarch;flocculatingagent;sorbent··2010《》、《》()、、《》610045000297《》[e-mail]　—638870376388679636-189《　》　2012045000297《》[e-mail]　—6388703763886796·55·　2009年第5期　　　　　　　　　　　　范庆松等:变性淀粉在工业水处理技术中的应用