地下水中常见有机污染物的原位治理技术现状

2009412009Vo1.4NO.l2,,,,,,,(l.,100190.2.,100039:3.,100195):,,,,,,,:...;.:X143:A:10071903(2oo9)01002209n,Jl30%,,,1520,51%,29%,75%,32%,1,113,400,30%,720,0,560,013],44%(VOCs),38%,28%402,1495%,7VOCs,6l4],,1827,64%33%,3o/ot3,51,,[8](eomprehensiveEnvironmentalResponse,Compensation,andLiabilityAet(CERLA)RevisedResoureeConservationandReeoveAet(RC))80,80,,,19.1!,,,,l3.21,:¹,;º,;»,,;¼19,,,,,(PRB),1.....2009Vbl.4NO.l2009:41,,,,,11],1120],,l2l]BTEX,(benzene)(toluene)(ethylbenzene)(xylene),,,,.3mg[22]:,,,1.1(AirSParging,AS),(volatileorganieComPonents,VOCs)(semivolatileorganiCcomponents,svOCs),,,(),,AS1982~199951%,(1),95%,,,,,,,,,l23],;,l24]5.0m;40,,70%,,40%,60%;,,,,(2)angl2s,3,,,,,,,,,,,1.2,,,,00,200,126],,,I920](1),02,,,02,.....20()9412009VO1.4No.l,,,,1984,,,320.05.11,(2),,,,NOa50,,Cunningham!,,,,.,,,Hutehins128],,4,,8,46,l2n,,,BTEX,,,12829],,,,,30t1,,,50%,,I32],,,,,21.3,,(AHs),,,,PAHsHs,,(ONAPL),lalss0.010922]ZhuI33],,,,,2.1PAHs,,.....2009,1.4NO.l:200941Mueller[34l,,PAs,99%,98%Gibert1351PAHsBTEX:6,(,)19,93%,1.5,80%,,95%,,,,,,,,,,22,,,(Phytoremediation),,,Widdowson136,,s(ONAL)7,As,ONAPL3,19982001(PCE)(CA)(CE)151.80.35137]:,/,CE,,1381,l39]3.,,,,1401,,Meearty141]TCE(5001200g/L),7,3.4mglL,85%,Shenl250%10%40%,TCE2%,56%,:,,Hrapovie1431TCE,,2500mgTCE,,CE,,3.2(l),,19966,.....20()9412009Vo1.4No.l,(TCE)TCE15002000g/L,30em(1.7g/L)451,TCE,I6l,,,,pH,,,,I;!,,,,,l4S](2),,,Wang149!Tl100nm,,Om,TCE(CBs)10100,,,,:¹,.º,,.»,,,,Cheng1501,TCE,O,//,,,,Mcnabls,,Low,,5052.HS,,15314BOOCOO,,00COO1111,5mgl22],00COO1544,5pR,COO80%1551,,;(ORC),,OOICOO0.320.75,5,,,,,,16,,,,,,,,.....20091.4No.12009:41,.,56]]].p,,[57]]],15,9L...58]]],59,60,[6l]]],,0,296220,.,62]]],HA,.,HA...,:,,,;,,,,,,,,,,,,,,!,![l]NOLANBT,RUDDYBC,HITTKJ,etal.RiskofnitrateingroundwatersoftheunitedstatesanationalPersPeetive[J].EnvironmentalSeienee&Teehnology,1997,31(8):22292236.[2]KOREIMANNC,GRAI,HJ,WINKLERG,etal.GroundwatermonitoringineuroPe.EuroPeanToPieCentreonInlandWters,EuroPeanEnvironmentalAgeney,1996.[3].[J].,2007,2(4):1618.[4]SQUILLACEPJ,SCOTTJC,MORANMJ,etal.VOCs,Pestieides,nitrate,andtheirmixturesingroundwaterusedfordrinkingwaterintheunitedstates[J]EnvironmentalSeienee&Technology,2002,36(9):1923~1930.5],.[J],2006,20(4):899[6,,.[J].,2005,14(l):l5...,2l,5.37.8].J].2007,7.2023.[9]MACKAYDM,CHERRYJA.Groundwatereontamination:PumPandtreatremediation[Jl.EnvironmentalSeience&Technology,1989,23(6):630~636.[10]MARI,INTA,KEMPTONJH.Insitustabilizationofmetaleontaminatedgroundwaterbyhydrousferrieoxide:AnexPerimentalandmodelinginvestigation[J].EnvironmentalSeienee&Teehnology,2000,34(15):3229~3234.11],.J].,2002,29(6):45~47.12],.[J].,2007,33(3):2625.13].[J].:,2007,28(Bo7):16123......2(X)94120091.4NO.l141,,..,2006,28(6):45257.151,,.[J].,2006,22(5):1.16BURMEIERH.Generaloverview[J].EvaluationofdemonstIatedandeme9teehnologiesforthetreanentofeontaminatedlandandgroundwater(Phase111)1998speeialsessionaonentwallsandpeeablereactivebers.[17MULLIGANCN,YONGRN,GIBBSBF.Remediationteehnologiesformetaleontaminated50115andgroundwater:AnevaluationJ].EngineeringGeology,2001,60(l):193207.18],,.[J].,2005,27(2):252819],,.Jl.,2007,27(7):1168~1173.20],,.J].,2004,27(4):17~19.[211,.[J].,19%,16(4):418~424.[22]GB57492006[OL].2006.23,,.[J].,2007,14(6):214-221.[24],,.[J].,2007,28(4):75760[25]YANGX,BECKMANND,FIORENZAS,etal.FieldstudyofpulsedairsPargingforremediationofPetroleumhydrocarboneontaminated5011andgroundwaterJ].EnvironmentalSeienee&Technology2005,39(18):7279~7286.26],,.J].,2007,27(4):622628.[27]CUNNINGHAMJA,RAHMEH,HOPKINSGD,etal.Enh:eedinsitubioremediationofbtexeontaminatedgroundwaterbyeombinedinjeetionofnitrateandsulfateJ].EnvironmentalScienee&Technology,2001,35(8):16631670.28HUTCHINSSR,MILLERDE,THOMASA.CombinedIaboratoryieldStudyontheuseofnitrateforinSitUbiorGm6distionOf8fueCOntsminstGdaquiferJ.EnvironmentalSeienee&ehnology,1998,32(12):1832~1840.29]nEsIGNE.Insitubtexbiotransformationunderenhaneednitrateandsulfateredueingeonditions[J.EnvironmentalSeienee&Teehnolo1997,31(2836.30,.[J].,1999,15(9):5557.[J].,1996,15(4):36~41.321,.[J].,1998,11(l):I6.[33]zHuL,eHENB,TA0s,etal.InteractionsoforganieeontaminantswithmineraladsorbedsurfaetantsJ].EnvironmentalSeienee&Teehnology,2003,37(17):4001~4006.[34]MUELLERJG,LANTZSE,ROSSD,etal.StrategyusingbioreaetorsandsPeeiallyseleetedmieroorganismsforbioremediationofgroundwatereontaminatedwithcreosoteandPentachloroPhenol[J].EnvironmentalSeienee&Teehnology,1993,27(4):691698.[35]GIBERTO,FERGUSONAS,KALINRM,etal.Performanceofasequentialreaetivebarrierforbioremediationofeoaltareontaminatedgroundwater[J].EnvironmentalSeienee&Teehnology,2007,41(19):6795~6801.[36]WIDDOWSONMA,SHEARERS,ANDERSENRG,etal.RemediationofPolycyclicaromatiehydroeathoneomPoundsingroundwaterusingPoPlartrees[J.EnvironmentalSeienee&Teehnology,2005,39(6):15981605.[37]MORANMJ,ZOGORSKIJS,SQUILLACEPJ.Chlorinatedsolventsingroundwateroftheunitedstates[J].EnvironmentalSeience&Teelmology,2007,41(1):781.f38]STURCHIONC,CLAUSENJL,HERATYLJ,et.....20091.4No.l2009:41al.ChlorineisotoPeinvestigationofnaturalattenuationoftriehloroethe