电Fenton法处理难降解有机废水的应用

2.8(,02)..........1(Advancedoxidationprocesses,AOPs),OHFentonOHFenton,H:,-rentonHZOZreZ+,HZO:,(,),FentonFentonH:Fe2+,H20:Fe2+OHOH(2.8),,,,,FentonH202,H20:,H:Fe2+,,11Fenion2Fenton2080,Fenton:HsiaY,,Fe2+H20:,Fenton,H2pH,pHH2HuangYaohui,re,+HZoZ,COD80%,COD030:FenionBrillasEIlq,RH:2,4D,2,4D90%,-Fenton,2,4DBrillas11,,pH=3,Fe2+H202,Tio:,-Fenton;,HsiaYllq,,RRVC,0:Fe3+,RVCFe2+H2,Fenion,5SChou1131,Fenton,FeZ(504)3Fe(OH)3Fe2+,FentonFenton4,:EFH20:EF--FeoxFSREFFereEFFeoxFSREFFere,FenionEFH20:H2,,HZo:,H:Fe2+,45H:Fenton,Fenton,,-Fenion,3Fenton,,OH,,,,,,,,::OH~4eZH++0::H++ZeH:(),FeFe3+A13+,,,,Fe2+,://\,(Fenion),,,,NaC10,,,,,Fenton,4Fenton(EF)Fenton:H20Fenion,Fenton;(Fez+),H,Fenton,,:4.1,,,,AOPsllnEdelahillNEF,romin,93%CODEF,COD93%llnGnivarch1181EF,80%,,OH,,,,EF,46200(24102)...........:l,4.2.,(%)(10%)(10%)100(X),7xlt,10%,,,EFEF,80%coDwang1211EF14,o.36Are,lmmpHj,360min,70%TOC,100%Kusvuran,EF12054.3,,Msw(),,,,EF,LinEFSBR,EFSBR,,4.4,,EFzuchengwupPb02NiCrTi,:Fe;,100%E.roekedlsnoi,,5kwh/k9CODGnidSarccPTi,,OH;N,EF,HZO:Alvare:GallegosH:,O:,H20:;,,,HDOJ.S.:,H,,H20,SS.ChouEFAOPSCOD50%,examine),,65%COD,2,Fenton,EF80%CODA.Mehemet!,EF125mL1.0nunoljL(PNP)(),COD95%EnricBriUas,0.050moNaZSO4pH3.040,ro30Llm(),61%;,6,100mEFPCP()(CTMP)475Fenion,Fenton,,-Fenton,:(l)Fenion30,,,Fenton,-Fenion,,,HO,;(2)Fenion,;(3)Fenton,0:H:,,Fe2+:[l],,.Fenion..2X,(2):5962l2],,.Fenton..2,29(6):2833[3F.JavierTivas,FemandoBeltrn,01,Gimeno,Fatimavalho.Fentonlikeoxidationofndfillaehate.JournalofFentonlikeoxidationenvironmentseieneeandhealth.Zo03,35(2):371-379[4],,,...2(X)2,29(3):135137l5],.Fenton4.,2x,5(10):5659.[61Ventura,JacquetG,andBermondA,etalleetro-checalnerationoftheFentonlx.eApplicationtoatraZinededationlJ].WaterResearch,2(X)2,(36):517522.[7],,.Fenion[J].,2(X,5(10):5659.[8]A.Ventrura,GJacquet,A.Bermond,etal.EleetroehemiealGenerationoftheFenton,sReant:APPlieationtoAtrazineDegradation.WaterRes.2(X)2,36:35173522[9]BrillasE,CalPeJ,CasadoJ.Mineralizationof2,4DbyadvaneedeleetroehemiealoxidationprocessesWaterRes,2,34(8):22562262[10]GogatePR,PanditABA,ReviewofImperativeTeehnologiesforWastewaterTreatmentl;OxidationTeehnologiesatAmbientConditions.AdvaneesinEnvironmentalResearch,2,8(3):501we551[11BrillasE,MurE,SauledaR.AnilinedeadationundereleetroehemiealandphotoeatalytieconditionsJAdyoxidTeehnol,1999,4(1):10011412]Fiaoy,NdK.HonofehlolDInzeneandPhenolinaPaekedbedflowreaetorwithelectro-nerateFenton,sreagent.J.Appl.Eleetrochest,1993,23(9):943946[13]ShanshanChou,YaoHuiHuang,ShenNane,HawHawHuang,Chihpin.TreatmentOfHighStrengthHexaneontainingWastewaterbyEleetrO-FentonMethod.WaterRes.1998,33:751759114],,,.Fenion..2X,24(12):91315]EB,B.Be,15eS,etaLDhecalDestruetionofCholoroPhenoxyHethieidesbyAnodieoxidationandEleetroFentonUsingABorondopedDiamondEleetrode.EleetroehemiealAeta.2X,49:487se4496[16]M.C.Edelahi,N.oturan,M.A.oturan,etal.DegradationofDiuronbytheEleetroFentonProeess.EnviroChemtt.2(X,l:23323617]GKaiehouh,N.lurall,M.,ntonReaetionsA.oturan,etal.DedationoftheHethieideEnviro.Chem.tt.2(X,2:3133(54)48...........,GAX,5,,,,,:l]P].,,zLZoo529987:2:2(X)5510,:2(X)5927.l2],.,2007,26(2):3539[3],7o,:,1995.[4],,.,2,3(2):147ol5],,,,.,200,28(6),468.[6],,.,2005,33(2)5053.1,..............(48)18E.Guivarch,5.Trevin,C.LAHI,etal.DedationofAzoDyesinWaterEleeFentonProeess.Enviro.Chem.tt.2(X)3,l:38ee4419A.Ventrura,GJaequet,A.Bermond,etal.EleetroeheealGenerationOftheFenton5Reagent:ApplieationtoAtrazineDedation.WaterRes22,36:35173522[20]..:,2XX).6[21]A.M.Wang,J.H.Qu,J.Ru,etal.MineralizationofAnAzoDyeAeidRed14byEleetroFenton5ReagentUsingAnAetivatedCarbonFilberCathode.DyesandPigrnents.2(X)5,65:227-233[22]E.Kusvuran,5.Irmak,H.Yavuz,etal.ComparisonoftheTreatmentMethodsEffieieneyforDeeolonizationandMineralizationofReaetiveBlaeksAzoDye.J.HazardousMaterials.2(X)5,B119:109-116[23]5.H.Un,C.C.Chang.Treatmentofn11achateEleetroFentonOxidationandSequeneingBatehReaetorMethod.2X),34:4243-4249[24]ZuehengW,MinghuaZ,DahuiW.Synergetie54effeetsofanodieeathodieeleetrocatalysisforPhenoldeadationinthepreseneeofiron(11)[J].Chemosphere,2(X)2,(48):10891096.25FoekedeyE,UerdeAV.CouPlingofanodieandeathodiereaetionforPhenoleleetroidationUsingthreedimensionaleleetrodesWaterResearch,2(X)2,(36):4169175.[261AlvarezGallegos^PleteherD.TheremovalOflowlevelorganiesviahydrogenperoxideformedinaretieulatedvitreousearboneathodeeell.Partl.TlleEleetrosynthesisofhydrogenperoxideinueousaeidiesolutions[J].Eleetroehim.Aeta.1998,():853-861[27]DoJS,YehWC.PairedeleetrooxidativedeadationofphenolwithinsitueleetrogenratedhydronpeoxideandhyPoehlorite[.Appl.Eleet,he,1996,(26):673678.[28]M.A.oturan,J.Peiroten,PChartrin,A.JAeher.ComPleteDestruetionofPnitroPhenolinAqUeousMediumbyEleetroFentonMethod.Environ.Sei.Teehnol.20(X),34:34743479[29]E.Brillas,J.Casado.AnilineDegradationPeroeoagulationProcessesUsingAFlowReactionChemosphere.EleetroFentonandWastewaterTreatmentZ(X)2,47:241248