多相催化臭氧化水处理技术研究进展游洋洋

*游洋洋1，3卢学强1，2许丹宇2，3张涛1，2石岩2，3杨昂1，31．3003872.3001913.300191。、、。。DOI10.13205/j．hjgc．201401010ＲEVIEWONHETEＲOGENEOUSCATALYTICOZONATIONINWATEＲTＲEATMENTYouYangyang13LuXueqiang12XuDanyu23ZhangTao12ShiYan23YangAng131.SchoolofEnvironmentalandChemicalEngineeringTianjinPolytechnicUniversityTianjin300387China2.TianjinAcademyofEnvironmentalSciencesTianjin300191China3.TianjinUnitedEnvironmentalEngineeringDesignCompanyLimitedTianjin300191ChinaAbstractIntheresearchandpracticeofwatertreatmenttheheterogeneouscatalyticozonationtechnologyisanewadvancedoxidationprocesswhichhasdrawngreatattentions．Metaloxidenanometermetaloxidemetalhydroxidearecommonlyusedascatalystwhileactivatedaluminaactivecarbonandceramichoneycombsarepopularizedasthecatalystcarrier．Thecatalystandcatalystcarrierofheterogeneouscatalyticozonationinwatertreatmentaresummarizedandreviewed．Theprospectoftheheterogeneouscatalyticozonationandsomecommonproblemsarealsodiscussed．Keywordsheterogeneouscatalyticozonationcatalystcarrierwatertreatment*51208358BCZDSF00700。2013－03－28、、。·OH1。2。3-4。。5-7。。、8。。。9-13。73WaterPollutionControl。1Fe、Cu、Ni、Al、Mn、CoCe、。1.1金属氧化物Zeng14SnO2SnO2。SnO2。SnO2。Liu15MnCl2Na2SiO3。51%TOC21%。。。12h90%。Martins16Mn-Ce-O70/30Fe-Mn-O。。Faria17Mn-OCo-OCe-OCe-Mn-OCe-Co-O。。CeMn、Co。1.2金属氢氧化物和羟基化物Xu18p-CNB。1.527。0mg/L500mg/L59%99%。5。。Zhang19FeOOHNOM。、UV254DOCNOM。Zhang20α-FeOOH、β-FeOOH、γ-FeOOHε-FeOOHα-FeOOHMeO—HMeO—H·H·OO3·OH。O3O3·OH。Qi21γ-Al2O3γ-AlOOHMIB98.4%27.5%。MIB。γ-AlOOHMIBMIB。γ-Al2O3。1.3纳米金属氧化物、。Anandan22Bi2CuO4。1.84×10－3s－1Bi2O32.03×10－3s－1CuO2.72×10－3s－1Bi2CuO43.76×10－3s－1。Pugazhenthiran23Bi2O3Au-Bi2O3-10AO-10。Bi2O3Au-Bi2O3AO-101.73.530min47%AO-10Au-Bi2O3。83EnvironmentalEngineering。、。2。。。、。2.1活性氧化铝γ-Al2O3。。Ｒosal24Al2O3MnOx/Al2O3。MnOx/Al2O310－6MnOx/SBA153.0×10－6。Ｒosal25Al2O3MnO2/Al2O337。。Pocostales26γ-Al2O3Co3O4/Al2O3、17α-。TOCCODCo3O4/Al2O3。。Chen27DMP。DMPTOCTiO2/Al2O3。。400℃。Sreethawong28FeNO33Al2O3Fe2O3/Al2O3。Al2O3Fe2O3/Al2O3CODFe2O3/Al2O3。Fe2O3、Fe2O3/Al2O3。Tong29Fe3O4/CoO/Al2O3。24-24-DP、。24-DP2.567×10－4s－1Fe3O4-CoO/Al2O31.840×10－3s－1。2.2活性炭、、。。。Beltran30DCF。120minTOC40%TOC95%。－－。Wang31Ｒu。42hTOC75%Ｒu。Ｒu/AC。Li32Ce/ACDMP。0.2%Ce/AC。60minCe/ACTOC68%48%93WaterPollutionControl22%。Ce/ACDMP2.57.5。Orge33-34。。Akhtar35Fe2O3/CeO2SMX。SMX。Fe2O3/CeO2pH=3.5SMXpH=7.5。SMXFe2O3/CeO2SMX。2.3蜂窝陶瓷、、。Zhao36。。、。278K328K、TOC、。Zhao37MnMn。Li38Mn/Co。TOCCOD。pH80min。。Utrill39/3%。pH·OH。。。Byun40－。TOC。3、、、。。1。。2、。、。3。。4。1AndreozziＲCaprioVInsolaAetal．AdvancedoxidationprocessesAOPforwaterpurificationandrecoveryJ．CatalysisToday19995351-59.2TabriziMTFGlasserDHildebrandtD．Wastewatertreatmentofreactivedyestuffsbyozonationinasemi-batchreactorJ．ChemicalEngineeringJournal2011166662-668.3BaiCPXiongXYGongWQetal．ＲemovalofrhodamineBbyozone-basedadvancedoxidationprocessJ．Desalination201127884-90.04EnvironmentalEngineering4ArriagaFMOtsuTOyamaTetal．PhotooxidationoftheantidepressantdrugFluoxetineProzacinaqueousmediabyhybridcatalytic/ozonationprocessesJ．Waterresearch2011452782-2794.5WangHCChangSHHungPCetal．Usingcatalyticozonationandbiofiltrationtodecreasetheformationofdisinfectionby-productsJ．Desalination2009249929-935.6LiDPQuJH．TheprogressofcatalytictechnologiesinwaterpurificationAreviewJ．JournalofEnvironmentalSciences200921713-719.7LiXKZhangQYTangLLetal．Catalyticozonationofp-chlorobenzoicacidbyactivatedcarbonandnickelsupportedactivatedcarbonpreparedfrompetroleumcokeJ．JournalofHazardousMaterials2009163115-120.8KhanMHJungJY．OzonationcatalyzedbyhomogeneousandheterogeneouscatalystsfordegradationofDEHPinaqueousphaseJ．Chemosphere200872690-696.9．－J．201028536-38.10WangHCChangSHHungPCetal．SynergisticeffectoftransitionmetaloxidesandozoneonPCDD/FdestructionJ．JournalofHazardousMaterials20091641452-1459.11LiottalFGruttadauriaM．HeterogeneouscatalyticdegradationofphenolicsubstratesCatalystsactivityJ．JournalofHazardousMaterials2009162588-606.12CarbajoMBeltraFJGimenoOetal．OzonationofphenolicwastewatersinthepresenceofaperovskitetypecatalystJ．AppliedCatalysisBEnvironmental200774203-210.13．－ＲOJ．20123051-4.14ZengYFLiuZL．DecolorizationofmolassesfermentationwastewaterbySnO2-catalyzedozonationJ．JournalofHazardousMaterials2009162682-687.15LiuYShenJMChenZLetal．DegradationofpchloronitrobenzeneindrinkingwaterbymanganesesilicatecatalyzedozonationJ．Desalination2011279219-224.16MartinＲCQuinta-ferreiraＲM．PhenolicwastewatersdepurationandbiodegradabilityenhancementbyozoneoveractivecatalystsJ．Desalination201127090-97.17FariaPCCMonteiroDCMPereierMFＲ．CeriummanganeseandcobaltoxidesascatalystsfortheozonationJ．Chemosphere200974818-824.18XuZZChenZLetal．Catalyticefficiencyandstabilityofcobalthydroxidefordecompositionofozoneandp-chloronitrobenzeneinwaterJ．CatalysisCommunications2009101221-1225.19ZhangTLuJFComparativeM．Studyofozonationandsyntheticgoethite-catalyzedozonationofindividualNOMfractionsisolatedandfractionatedfromafilteredriverwaterJ．Waterresearch2008421563-1570.20ZhangTLiCJMaJetal．Surfacehydroxylgroupsofsyntheticα-FeOOHinpromoting·OHgenerationfromaqueousozonePropertyandactivityrelationshipJ．AppliedCatalysisBEnvironmental2008821/2131-137.21