高级氧化技术处理制药废水研究进展马兴冠

20096586。802.860%C9.850%。1.7%2%。12。《》。1、《》6、、、、、。。--。、。[1]--BOD5、COD、NH3-NSS99%、98.5%、85%98%GB8978－1996[2]--MBRCOD800mg·L-194.5%～97.6%[3]ABR-A/O。COD10500～15000mg·L-1SO42-000～1500mg·L-1COD、SO42-98%92%GB8978-1996[4]BIOFORGB8978－1996。110168、、。。X787A1000-3770(2011)11-0005-0052011[e-mail]3711201111TECHNOLOGYOFWATERTREATMENTVol.37No.11Nov.,20115DOI:10.16796/j.cnki.1000-3770.2011.11.002。COD、。[5]--Fenton、、COD91.6%BOD99.2%0.250.35[6]-Fenton。、pH3、3VH2O210mmol·L-120mg·L-160min99%TOC60%。PGharbani[7]4--2-pH4--2-pH999.64%Akmehmet[8]、/、/3。/AliZElkarmi[9]2,4-2,4-220mg·L-1380mg·L-1。、pH35℃pH7。2AOPsAdvancedoxidationprocessesAOPsCO2H2O[10]。Fenton、、、、、、[11-12]。[13-15]、[16]、[17]、。2.1FentonFentonH2O2。、、。、。[18]FentonCOD74.5%BOD5/COD0.100.31[19]FentonCOD72%BOD5/COD0.45[20]FentonCOD71.40%。Fenton。SuRongjun[21]-FentonH2O2:FeSO4·H2O1:1FeSO4·7H2O7.8mmol·L-1pH3.0BOD5/COD0.150.24COD78.9%88.6%MeleroJA[22]Fe2O3/SBA-15。pH380℃200minTOC50%。FBRTOC60%0.20.3。371162.2OH-。。[23]TiRuO2。pH7.0550.0mA·cm-21.0cm120minCOD97.5%60.5%。。[24]20%COD62.6%92.1%BoroskiMarcela[25]-。12.50cm×2.50cm×0.10cm763A·m-2pH690minCOD91%86%UV/TiO2/H2O2pH3TiO20.25g·L-1H2O210mmol·L-14h。COD1753mg·L-1COD160mg·L-1COD50mg·L-1。2.3[26]1972TiO2。-OH-H2O·OH。·OH·OHCO2H2O[27]。TiO2、、、。。[28]TiO2。。500mg·L-12.5g·L-15h93.4%[29]ABRCOD823mg·L-156.8mg·L-193.1%[30]TiO2-SBRCOD87.66%BOD588.59%SS61.09%pH5.007.67。。。2.4、1[27]Tab.1Applicationofpharmaceuticalwastewatertreatmentbyphotocatalytieoxidationtechnologyinabroad/%SMXDIDM[31]TiO2TiO2UV/H2O2TiO2UV/H2O2/Fe2+-Fenton-Fenton/TOC80BOD5/COD0～0.42879050TOC79.9COD92.5BOD5/COD0-0.25DIDM(100)COD≥95%-Fenton33627。、、[32-33]。、、。。[34]COD、BOD、CODBOD[35]。100W60s80.9%H2O2Fe2+COD。。[36]、、COD96.2%96.4%。3、、。。、。、、。12。3、、、。[1],,,.--[J].,2009,35(4):63-65.[2],,,.--MBR[J].,2010,36(9):158-161.[3],,,.ABR-A/O[J].,2010,36(4):69-71.[4],,.BIOFOR[J].,2006,24(5):14-15,18.[5],,.--Fenton[J].,2008,26():112-114.[6],,,.-Fenton[J].,2010,4(1):57-62.[7]PGharbani,MKhosravi,SMTabatabaii,etal.Degradationoftraceaqueous4-chloro-2-nitrophenoloccurringinpharmaceuticalindus-trialwastewaterbyozone[J].IntJEnvironSciTech.,2010,7(2):377-384.[8]Akmehmet,Balcioglu,Merih,etal.Pre-treatmentofantibioticfor-mulationwastewaterbyO3,O3/H2O2,andO3/UVprocesses[J].Turk-ishJEngEnvSci.,2004(28):325-331.[9]AliZElkarmi,KhaledH.Abu-Elteen,etal.Biodegradationof2,4-dichlorophenoloriginatingfrompharmaceuticalindustries[J].AfricanJournalofBiotechnology,2009,8(11):2558-2564.[10],,.[J].,2011,37(1):14-19.[11],.[J].,2009,35(3):18-22.[12],,,.[J].,2002,18(5):33-35.[13],,.Fenton[J].,2010,4(5):1096-1100.[14].[J].,2010,4(12):2823-2826.[15],.[J].,2006,26(6):1-5.[16],,,.[J].,2003,19(6):56-58.[17],,.[J].,2004,20(10):26-29.[18],,.Fenton[J].,2010,30(9):25-27.[19],,.Fenton[J].,2010,36(4):79-81.[20],,,.Fenton[J].,2010,35(4):68-71.[21]SuRongjun,WangPeng,JiangLiming,etal.Studyontreatmentof37118acetylspiramycinpharmaceuti-calwastewaterbythephoto-Fentonoxidationprocess[C].EMEM2010,NortheastForestryUniversity,AdvancedMaterialsResearch,2010:512-515.[22]MeleroJA,MartínezF,BotasJA,etal.Heterogeneouscatalyticwetperoxideoxidationsystemsforthetreatmentofanindustrialpharmaceu-ticalwastewater[J].WaterResearch,2009,43(16):4010-4018.[23],,,.[J].,2011,24(1):79-84.[24],,,.[J].,2010,23(7):892-896.[25]BoroskiMarcela,Rodrigues,Garcia,etal.Combinedelectrocoag-ulationandTiO2photoassistedtreatmentappliedtowastewateref-fluentsfrompharmaceuticalandcosmeticindustries[J].JournalofHazardousMaterials,2009,162(1):448-454.[26]FujishimaA,HondaK.Electrochemicalphotoly-sisofwateratasemiconductorelectrode[J].Nature,1972,37:238-245.[27].[J].,2009,29(8):10-12.17.[28],,.[J].,2008,27(6):446-451.[29].[J].,2006,33(9):39-41.[30],,,.TiO2-SBR[J].,2008,28(7):1314-1319.[31]SirtoriC,ZapataA,OllerI,etal.Decontamin-ationindustrialphar-maceuticalwastewaterbycombiningsolarphoto-Fentonandbio-logicaltreatment[J].WaterResearch,2009,43(3):661-668.[32],.[J].,2006,26(6):1-5.[33],.[J].,2003,16(4):129-131,185.[34],,,.[J].,2010,27(8):28-29.[35].[J].,2003,23(1):44-46.[36]./[J].,2010,4(3):590-594.PROGRESSINSTUDIESONPHARMACEUTICALWASTEWATERTREATEDBYADVANCEDOXIDATIONTECHNOLOGYMaXingguan,WenJing,ChenChen,MingTieshan(MunicipalandEnvironmentalEngineeringCollege,ShenyangJianzhuUniversity,Shenyang110168,China)Abstract:Advancedoxidationtechnologyhadmanyadvantageslikehighefficiency,nosecondarypollution,andlowselectivityetc.Forpharmaceuticalwastewaterwithcharacteristicsofhighconcentrationandexcessivenon-biodegradation,pharmaceuticalwastewatertreatedbyadvancedoxidationtech-nologycanefficientlyincreaseorganicremovalrate.Atthesametime,ithadwideandpromisingdevelopmentforeground.Inordertowideusethistechnologyinactualprojectsforwastewatertreatment,thetheoryandcharacteristicsofadvancedoxidationprocesswereintroduced.Throughthere-searchandapplicationofthistechnologybothinChinaandabroadinrecentyears,itputforwardtotheproblemsneededtosolveinactualwastewatertreatmentengineering.Prospectofadvancedoxidationtechnologyinpharmaceuticalwastewatertreatmenthadbeenpredi